Validation Log 2025-12-15 02:33:23.404481 mwtab Python Library Version: 2.0.0 Source: https://www.metabolomicsworkbench.org/rest/study/analysis_id/AN005822/mwtab/txt Study ID: ST003544 Analysis ID: AN005822 File format: txt Status: Contains Validation Issues Number of Issues: 15 Number of Warnings: 10 Number of Value Errors: 15 Number of Consistency Errors: 0 Number of Format Errors: 0 Issue Log: Error: An empty value or a null value was detected for the subsection, "TREATMENT_SUMMARY", in the "TREATMENT" section. A legitimate value should be provided for this required subsection. Error: An empty value or a null value was detected for the subsection, "FLOW_GRADIENT", in the "CHROMATOGRAPHY" section. A legitimate value should be provided for this required subsection. Error: The value for the subsection, "COLUMN_TEMPERATURE", in the "CHROMATOGRAPHY" section should be a number or range (ex. "5-6") followed by a space with a unit (ex. "5 V") from the following list: ['°C', 'C']. Ignore this when more complicated descriptions are required. Error: An empty value or a null value was detected for the subsection, "SOLVENT_A", in the "CHROMATOGRAPHY" section. A legitimate value should be provided for this required subsection. Error: An empty value or a null value was detected for the subsection, "SOLVENT_B", in the "CHROMATOGRAPHY" section. A legitimate value should be provided for this required subsection. Warning: SUBJECT_SAMPLE_FACTORS entry #1 has the following duplicate keys in its Additional sample data: "RAW_FILE_NAME(GC-QQQ file name)" "RAW_FILE_NAME(GC-QQQ file name)" Warning: SUBJECT_SAMPLE_FACTORS entry #2 has the following duplicate keys in its Additional sample data: "RAW_FILE_NAME(GC-QQQ file name)" "RAW_FILE_NAME(GC-QQQ file name)" Warning: SUBJECT_SAMPLE_FACTORS entry #3 has the following duplicate keys in its Additional sample data: "RAW_FILE_NAME(GC-QQQ file name)" "RAW_FILE_NAME(GC-QQQ file name)" Warning: SUBJECT_SAMPLE_FACTORS entry #4 has the following duplicate keys in its Additional sample data: "RAW_FILE_NAME(GC-QQQ file name)" "RAW_FILE_NAME(GC-QQQ file name)" Warning: SUBJECT_SAMPLE_FACTORS entry #5 has the following duplicate keys in its Additional sample data: "RAW_FILE_NAME(GC-QQQ file name)" "RAW_FILE_NAME(GC-QQQ file name)" Warning: SUBJECT_SAMPLE_FACTORS entry #6 has the following duplicate keys in its Additional sample data: "RAW_FILE_NAME(GC-QQQ file name)" "RAW_FILE_NAME(GC-QQQ file name)" Warning: SUBJECT_SAMPLE_FACTORS entry #7 has the following duplicate keys in its Additional sample data: "RAW_FILE_NAME(GC-QQQ file name)" "RAW_FILE_NAME(GC-QQQ file name)" Warning: SUBJECT_SAMPLE_FACTORS entry #8 has the following duplicate keys in its Additional sample data: "RAW_FILE_NAME(GC-QQQ file name)" "RAW_FILE_NAME(GC-QQQ file name)" Warning: SUBJECT_SAMPLE_FACTORS entry #9 has the following duplicate keys in its Additional sample data: "RAW_FILE_NAME(GC-QQQ file name)" "RAW_FILE_NAME(GC-QQQ file name)" Warning: SUBJECT_SAMPLE_FACTORS entry #10 has the following duplicate keys in its Additional sample data: "RAW_FILE_NAME(GC-QQQ file name)" "RAW_FILE_NAME(GC-QQQ file name)"