Validation Log 2025-12-15 02:38:29.531749 mwtab Python Library Version: 2.0.0 Source: https://www.metabolomicsworkbench.org/rest/study/analysis_id/AN005937/mwtab/json Study ID: ST003612 Analysis ID: AN005937 File format: json Status: Contains Validation Issues Number of Issues: 17 Number of Warnings: 12 Number of Value Errors: 14 Number of Consistency Errors: 2 Number of Format Errors: 0 Issue Log: Error: The value, "nothing", in ["CHROMATOGRAPHY"]["FLOW_RATE"] should be a number or range (ex. "5-6") followed by a space with a unit (ex. "5 V") from the following list: ['mL/min', 'uL/min', 'μL/min']. Ignore this when more complicated descriptions are required. Error: The value, "300°C", in ["CHROMATOGRAPHY"]["COLUMN_TEMPERATURE"] should be a number or range (ex. "5-6") followed by a space with a unit (ex. "5 V") from the following list: ['°C', 'C']. Ignore this when more complicated descriptions are required. Error: The following metabolites in the, ["MS_METABOLITE_DATA"]["Data"] table were not found in the ["MS_METABOLITE_DATA"]["Metabolites"] table: "1_2_3_4-Butanetetrol_ 1-[2-(2-fluorophenyl)-2H-1_2_3-triazol-4-yl]-_ [1R-(1R*_2S*_3R*)]-" "(+)-1_2_3_4-Tetrahydroisoquinoline_ 1-benzyl-6_7-dimethoxy-" "1_4_6-Trimethyl-1_2_3_3a_4_7_8_8a-octahydro-4_7-ethanoazulene" "1H-1_2_3-Triazolo[4_5-c]quinoline-1-hexanoic acid" "2_4-Heptanedione_ 6-[[2-(2_3_8_8a-tetrahydro-5_8a-dimethyl-7-oxoimidazo[1_2-a]pyridin-1(7H)-yl)ethyl]imino]-" "2_4-Hexadienedioic acid" "2_6_10_14-Tetramethyl-7-(3-methylpent-4-enylidene) pentadecane" "2-Cyclohexen-1-one_ 3-[3-(4_4-dimethyl-4_5-dihydro-1_3-oxazol-2-yl)phenyl]" "2^-Deoxyribolactone" "2-(Ethylamino)ethanol_ N-pentafluoropropionyl_ O-trimethylsilyl" "3_10-Dioxa-2_11-disiladodeca-5_7-diene_ 2_2_11_11-tetramethyl-" "3_5-Cyclocholestan-19-al_ 6-hydroxy-_ (6.beta.)-" "3_5-Dimethyl-2-phenylpyridine" "5_14_23-Octadecatrien-14_15-diol" "5_6-Epoxyretinoic acid" "benzenamine_ 2_3_5_6-tetrafluoro-N_N-dimethyl-" "Benzonitrile_ 2-benzylthio-4-methoxy-" "Bis(trimethylsilyl) 3_6_9_12-tetraoxatetradecane-1_14-dioate" "Cholest-4-en-26-al_ 3-oxo-_ cyclic 26-(ethylene acetal)" "Cyclodocosane_ ethyl-" "Cyclohexene_ 3-butyl-3-methyl-1-trimethylsilyloxy-" "D-Arabino-Hexonic acid_ 3-deoxy-2_5_6-tris-O-(trimethylsilyl)-_ .gamma.-lactone" "Dodecane_ 1-(methoxymethoxy)-" "D-(+)-Ribono-1_4-lactone" "Gulonic acid_ .gamma.-lactone" "Heptacosane_ 1-chloro-" "Hexadeca-2_6_10_14-tetraen-1-ol_ 3_7_11_16-tetramethyl-" "Propionic acid_ 3-iodo-_ heptadecyl ester" "Tetrapentacontane_ 1_54-dibromo-" Error: The following metabolites in the ["MS_METABOLITE_DATA"]["Metabolites"] table were not found in the ["MS_METABOLITE_DATA"]["Data"] table: "1,2,3,4-Butanetetrol, 1-[2-(2-fluorophenyl)-2H-1,2,3-triazol-4-yl]-, [1R-(1R*,2S*,3R*)]-" "(+)-1,2,3,4-Tetrahydroisoquinoline, 1-benzyl-6,7-dimethoxy-" "1,4,6-Trimethyl-1,2,3,3a,4,7,8,8a-octahydro-4,7-ethanoazulene" "1H-1,2,3-Triazolo[4,5-c]quinoline-1-hexanoic acid" "2,4-Heptanedione, 6-[[2-(2,3,8,8a-tetrahydro-5,8a-dimethyl-7-oxoimidazo[1,2-a]pyridin-1(7H)-yl)ethyl]imino]-" "2,4-Hexadienedioic acid" "2,6,10,14-Tetramethyl-7-(3-methylpent-4-enylidene) pentadecane" "2-Cyclohexen-1-one, 3-[3-(4,4-dimethyl-4,5-dihydro-1,3-oxazol-2-yl)phenyl]" "2'-Deoxyribolactone" "2-(Ethylamino)ethanol, N-pentafluoropropionyl, O-trimethylsilyl" "3,10-Dioxa-2,11-disiladodeca-5,7-diene, 2,2,11,11-tetramethyl-" "3,5-Cyclocholestan-19-al, 6-hydroxy-, (6.beta.)-" "3,5-Dimethyl-2-phenylpyridine" "5,14,23-Octadecatrien-14,15-diol" "5,6-Epoxyretinoic acid" "benzenamine, 2,3,5,6-tetrafluoro-N,N-dimethyl-" "Benzonitrile, 2-benzylthio-4-methoxy-" "Bis(trimethylsilyl) 3,6,9,12-tetraoxatetradecane-1,14-dioate" "Cholest-4-en-26-al, 3-oxo-, cyclic 26-(ethylene acetal)" "Cyclodocosane, ethyl-" "Cyclohexene, 3-butyl-3-methyl-1-trimethylsilyloxy-" "D-Arabino-Hexonic acid, 3-deoxy-2,5,6-tris-O-(trimethylsilyl)-, .gamma.-lactone" "Dodecane, 1-(methoxymethoxy)-" "D-(+)-Ribono-1,4-lactone" "Gulonic acid, .gamma.-lactone" "Heptacosane, 1-chloro-" "Hexadeca-2,6,10,14-tetraen-1-ol, 3,7,11,16-tetramethyl-" "Propionic acid, 3-iodo-, heptadecyl ester" "Tetrapentacontane, 1,54-dibromo-" Warning: The "ri" column at position 7 in the ["MS_METABOLITE_DATA"]["Metabolites"] table, matches a standard column name, "retention_index". If this match was not in error, the column should be renamed to the standard name or a name that doesn't resemble the standard name. Warning: The "ri_type" column at position 8 in the ["MS_METABOLITE_DATA"]["Metabolites"] table, matches a standard column name, "retention_index_type". If this match was not in error, the column should be renamed to the standard name or a name that doesn't resemble the standard name. Warning: The standard column, "other_id", was found in the METABOLITES table as "other_id". If this column contains database IDs for standard databases such as KEGG, PubChem, HMDB, etc., it is recommended to make individual columns for these and not lump them together into a less descriptive "other_id" column. Error: Column(s) with no name were found in the ["MS_METABOLITE_DATA"]["Metabolites"] table. Warning: The "pubchem_id" column at position 2 in the ["MS_METABOLITE_DATA"]["Metabolites"] table has all null values. Warning: The "inchi_key" column at position 3 in the ["MS_METABOLITE_DATA"]["Metabolites"] table has all null values. Warning: The "kegg_id" column at position 4 in the ["MS_METABOLITE_DATA"]["Metabolites"] table has all null values. Warning: The "other_id" column at position 5 in the ["MS_METABOLITE_DATA"]["Metabolites"] table has all null values. Warning: The "other_id_type" column at position 6 in the ["MS_METABOLITE_DATA"]["Metabolites"] table has all null values. Warning: The "ri" column at position 7 in the ["MS_METABOLITE_DATA"]["Metabolites"] table has all null values. Warning: The "ri_type" column at position 8 in the ["MS_METABOLITE_DATA"]["Metabolites"] table has all null values. Warning: The "moverz_quant" column at position 9 in the ["MS_METABOLITE_DATA"]["Metabolites"] table has all null values. Warning: The "" column at position 10 in the ["MS_METABOLITE_DATA"]["Metabolites"] table has all null values.