Validation Log
2025-12-15 02:40:11.025695
mwtab Python Library Version: 2.0.0
Source:        https://www.metabolomicsworkbench.org/rest/study/analysis_id/AN005974/mwtab/txt
Study ID:      ST003637
Analysis ID:   AN005974
File format:   txt
Status: Contains Validation Issues
Number of Issues: 13

Number of Warnings: 11

Number of Value Errors: 13

Number of Consistency Errors: 0

Number of Format Errors: 0

Issue Log:
Error: The value, "0.35 ml/min;", for the subsection, "FLOW_RATE", in the "CHROMATOGRAPHY" section should be a number or range (ex. "5-6") followed by a space with a unit (ex. "5 V") from the following list: ['mL/min', 'uL/min', 'μL/min']. Ignore this when more complicated descriptions are required.
Error: The value, "45∘C", for the subsection, "COLUMN_TEMPERATURE", in the "CHROMATOGRAPHY" section should be a number or range (ex. "5-6") followed by a space with a unit (ex. "5 V") from the following list: ['°C', 'C']. Ignore this when more complicated descriptions are required.
Warning: The "Molecular Weight" column at position 3 in the METABOLITES table, matches a standard column name, "mass". If this match was not in error, the column should be renamed to the standard name or a name that doesn't resemble the standard name.
Warning: The "Pubchem CID" column at position 7 in the METABOLITES table, matches a standard column name, "pubchem_id". If this match was not in error, the column should be renamed to the standard name or a name that doesn't resemble the standard name.
Warning: The "HMDB" column at position 5 in the METABOLITES table, matches a standard column name, "hmdb_id". If this match was not in error, the column should be renamed to the standard name or a name that doesn't resemble the standard name.
Warning: The "lipidmaps ID" column at position 6 in the METABOLITES table, matches a standard column name, "lm_id". If this match was not in error, the column should be renamed to the standard name or a name that doesn't resemble the standard name.
Warning: The "Metlin" column at position 10 in the METABOLITES table, matches a standard column name, "metlin_id". If this match was not in error, the column should be renamed to the standard name or a name that doesn't resemble the standard name.
Warning: The "CAS" column at position 8 in the METABOLITES table, matches a standard column name, "cas_number". If this match was not in error, the column should be renamed to the standard name or a name that doesn't resemble the standard name.
Warning: The "ChEBI" column at position 9 in the METABOLITES table, matches a standard column name, "chebi_id". If this match was not in error, the column should be renamed to the standard name or a name that doesn't resemble the standard name.
Warning: The "Ionization model" column at position 4 in the METABOLITES table, matches a standard column name, "ionization_mode". If this match was not in error, the column should be renamed to the standard name or a name that doesn't resemble the standard name.
Warning: The "Ionization model" column at position 4 in the METABOLITES table, matches a standard column name, "ionization_mode", and some of the values in the column do not match the expected type or format for that column. The non-matching values are:
0         [M-H]-
1         [M-H]-
2         [M-H]-
3         [M-H]-
4         [M-H]-
5         [M-H]-
6         [M-H]-
7         [M-H]-
8         [M-H]-
9         [M-H]-
10        [M-H]-
11        [M-H]-
12        [M-H]-
13        [M-H]-
14        [M-H]-
15        [M-H]-
16        [M-H]-
17        [M-H]-
18        [M-H]-
19        [M-H]-
20        [M-H]-
21        [M-H]-
22        [M-H]-
23        [M-H]-
24        [M-H]-
25        [M-H]-
26        [M-H]-
27        [M-H]-
28        [M-H]-
29        [M-H]-
30        [M-H]-
31        [M-H]-
32        [M-H]-
33        [M-H]-
34        [M-H]-
35        [M-H]-
36        [M-H]-
37        [M-H]-
38        [M-H]-
39        [M-H]-
40        [M-H]-
41     [M+COOH]-
42     [M+COOH]-
43     [M+COOH]-
44     [M+COOH]-
45     [M+COOH]-
46     [M+COOH]-
47     [M+COOH]-
48     [M+COOH]-
49     [M+COOH]-
50     [M+COOH]-
51     [M+COOH]-
52     [M+COOH]-
53     [M+COOH]-
54     [M+COOH]-
55     [M+COOH]-
56     [M+COOH]-
57     [M+COOH]-
58     [M+COOH]-
59     [M+COOH]-
60     [M+COOH]-
61     [M+COOH]-
62     [M+COOH]-
63     [M+COOH]-
64     [M+COOH]-
65     [M+COOH]-
66     [M+COOH]-
67     [M+COOH]-
68     [M+COOH]-
69     [M+COOH]-
70     [M+COOH]-
71     [M+COOH]-
72     [M+COOH]-
73     [M+COOH]-
74     [M+COOH]-
75     [M+COOH]-
76     [M+COOH]-
77     [M+COOH]-
78     [M+COOH]-
79     [M+COOH]-
80     [M+COOH]-
81     [M+COOH]-
82     [M+COOH]-
83     [M+COOH]-
84     [M+COOH]-
85     [M+COOH]-
86     [M+COOH]-
87     [M+COOH]-
88     [M+COOH]-
89     [M+COOH]-
90     [M+COOH]-
91     [M+COOH]-
92     [M+COOH]-
93     [M+COOH]-
94     [M+COOH]-
95     [M+COOH]-
96     [M+COOH]-
97     [M+COOH]-
98        [M-H]-
99        [M-H]-
100       [M-H]-
101       [M-H]-
102       [M-H]-
103       [M-H]-
104       [M-H]-
105       [M-H]-
106       [M-H]-
107       [M-H]-
108       [M-H]-
109       [M-H]-
110       [M-H]-
111       [M-H]-
112       [M-H]-
113       [M-H]-
114       [M-H]-
115       [M-H]-
116       [M-H]-
117       [M-H]-
118       [M-H]-
119       [M-H]-
120       [M-H]-
121       [M-H]-
122       [M-H]-
123       [M-H]-
124       [M-H]-
125       [M-H]-
126       [M-H]-
127       [M-H]-
128       [M-H]-
129       [M-H]-
130       [M-H]-
131       [M-H]-
132       [M-H]-
133       [M-H]-
134       [M-H]-
135       [M-H]-
136       [M-H]-
137       [M-H]-
138       [M-H]-
139       [M-H]-
140       [M-H]-
141       [M-H]-
142       [M-H]-
143       [M-H]-
144       [M-H]-
145       [M-H]-
146       [M-H]-
147       [M-H]-
148       [M-H]-
149       [M-H]-
150       [M-H]-
151       [M-H]-
152       [M-H]-
153       [M-H]-
154       [M-H]-
155       [M-H]-
156       [M-H]-
157       [M-H]-
158       [M-H]-
159       [M-H]-
160       [M-H]-
161       [M-H]-
162       [M-H]-
163       [M-H]-
164       [M-H]-
165       [M-H]-
166       [M-H]-
167       [M-H]-
168       [M-H]-
169       [M-H]-
170       [M-H]-
171       [M-H]-
172       [M-H]-
173       [M-H]-
174       [M-H]-
175       [M-H]-
176       [M-H]-
177       [M-H]-
178       [M-H]-
179       [M-H]-
180       [M-H]-
181       [M-H]-
182       [M-H]-
183       [M-H]-
184       [M-H]-
185       [M-H]-
186       [M-H]-
187       [M-H]-
188       [M-H]-
189       [M-H]-
190       [M-H]-
191       [M-H]-
192       [M-H]-
193       [M-H]-
194       [M-H]-
195       [M-H]-
196       [M-H]-
197       [M-H]-
198       [M-H]-
199       [M-H]-
200       [M-H]-
201       [M-H]-
202       [M-H]-
203       [M-H]-
204       [M-H]-
205       [M-H]-
206       [M-H]-
207       [M-H]-
208       [M-H]-
209       [M-H]-
210       [M-H]-
211       [M-H]-
212       [M-H]-
213       [M-H]-
214       [M-H]-
215       [M-H]-
216       [M-H]-
217       [M-H]-
218       [M-H]-
219       [M-H]-
220       [M-H]-
221       [M-H]-
222       [M-H]-
223       [M-H]-
224       [M-H]-
225       [M-H]-
226       [M-H]-
227       [M-H]-
228       [M-H]-
229       [M-H]-
230       [M-H]-
231       [M-H]-
232       [M-H]-
233       [M-H]-
234       [M-H]-
235       [M-H]-
236       [M-H]-
237       [M-H]-
238       [M-H]-
239       [M-H]-
240       [M-H]-
241       [M-H]-
242       [M-H]-
243       [M-H]-
244       [M-H]-
245       [M-H]-
246       [M-H]-
247       [M-H]-
248       [M-H]-
249       [M-H]-
250       [M-H]-
251       [M-H]-
252       [M-H]-
253       [M-H]-
254       [M-H]-
255       [M-H]-
256       [M-H]-
257       [M-H]-
258       [M-H]-
259       [M-H]-
260       [M-H]-
261       [M-H]-
262       [M-H]-
263       [M-H]-
264       [M-H]-
265       [M-H]-
266       [M-H]-
267       [M-H]-
268       [M-H]-
269       [M-H]-
270       [M-H]-
271       [M-H]-
272       [M-H]-
273       [M-H]-
274       [M-H]-
275       [M-H]-
276       [M-H]-
277       [M-H]-
278       [M-H]-
279       [M-H]-
280       [M-H]-
281       [M-H]-
282       [M-H]-
283       [M-H]-
284       [M-H]-
285       [M-H]-
286       [M-H]-
287       [M-H]-
288       [M-H]-
289       [M-H]-
290       [M-H]-
291       [M-H]-
292       [M-H]-
293       [M-H]-
294       [M-H]-
295       [M-H]-
296       [M-H]-
297       [M-H]-
298       [M-H]-
299       [M-H]-
300       [M-H]-
301       [M-H]-
302       [M-H]-
303       [M-H]-
304       [M-H]-
305       [M-H]-
306       [M-H]-
307       [M-H]-
308       [M-H]-
309       [M-H]-
310       [M-H]-
311       [M-H]-
312       [M-H]-
313       [M-H]-
314       [M-H]-
315       [M-H]-
316       [M-H]-
317       [M-H]-
318       [M-H]-
319       [M-H]-
320       [M-H]-
321       [M-H]-
322       [M-H]-
323       [M-H]-
324       [M-H]-
325       [M-H]-
326       [M-H]-
327       [M-H]-
328       [M-H]-
329       [M-H]-
330       [M-H]-
331       [M-H]-
332       [M-H]-
333       [M-H]-
334       [M-H]-
335       [M-H]-
336       [M-H]-
337       [M-H]-
338       [M-H]-
339       [M-H]-
340       [M-H]-
341       [M-H]-
342       [M-H]-
343       [M-H]-
344       [M-H]-
345       [M-H]-
346       [M-H]-
347       [M-H]-
348       [M-H]-
349       [M-H]-
350    [M+COOH]-
351    [M+COOH]-
352    [M+COOH]-
353    [M+COOH]-
354       [M-H]-
355       [M-H]-
356       [M-H]-
357       [M-H]-
358       [M-H]-
359       [M-H]-
360       [M-H]-
361       [M-H]-
362       [M-H]-
363       [M-H]-
364       [M-H]-
365       [M-H]-
366       [M-H]-
367       [M-H]-
368       [M-H]-
369       [M-H]-
370       [M-H]-
371    [M+COOH]-
372    [M+COOH]-
373    [M+COOH]-
374    [M+COOH]-
375    [M+COOH]-
376    [M+COOH]-
377    [M+COOH]-
378    [M+COOH]-
379    [M+COOH]-
380    [M+COOH]-
381    [M+COOH]-
382    [M+COOH]-
383    [M+COOH]-
384    [M+COOH]-
385    [M+COOH]-
386    [M+COOH]-
387    [M+COOH]-
388    [M+COOH]-
389    [M+COOH]-
390    [M+COOH]-
391    [M+COOH]-
392    [M+COOH]-
393    [M+COOH]-
394    [M+COOH]-
395    [M+COOH]-
396    [M+COOH]-
397    [M+COOH]-
398    [M+COOH]-
399    [M+COOH]-
400    [M+COOH]-
401    [M+COOH]-
402    [M+COOH]-
403    [M+COOH]-
404       [M-H]-
405       [M-H]-
406       [M-H]-
407       [M-H]-
408       [M-H]-
409       [M-H]-
410       [M-H]-
411       [M-H]-
412       [M-H]-
413       [M-H]-
414       [M-H]-
415       [M-H]-
416       [M-H]-
417       [M-H]-
418       [M-H]-
419       [M-H]-
420       [M-H]-
421       [M-H]-
422       [M-H]-
423       [M-H]-
424       [M-H]-
425       [M-H]-
426       [M-H]-
427       [M-H]-
428       [M-H]-
429       [M-H]-
430       [M-H]-
431       [M-H]-
432       [M-H]-
433       [M-H]-
434       [M-H]-
435       [M-H]-
436       [M-H]-
437       [M-H]-
438       [M-H]-
439       [M-H]-
440       [M-H]-
441       [M-H]-
442       [M-H]-
443       [M-H]-
444       [M-H]-
445       [M-H]-
446       [M-H]-
447       [M-H]-
448       [M-H]-
449       [M-H]-
450       [M-H]-
451       [M-H]-
452       [M-H]-
453       [M-H]-
454       [M-H]-
455       [M-H]-
456       [M-H]-
457       [M-H]-
458       [M-H]-
459       [M-H]-
460       [M-H]-
461       [M-H]-
462       [M-H]-
463       [M-H]-
464       [M-H]-
465       [M-H]-
466       [M-H]-
467       [M-H]-
468       [M-H]-
469       [M-H]-
470       [M-H]-
471       [M-H]-
472       [M-H]-
473       [M-H]-
474       [M-H]-
475       [M-H]-
476       [M-H]-
477       [M-H]-
478       [M-H]-
479       [M-H]-
480       [M-H]-
481       [M-H]-
482       [M-H]-
483       [M-H]-
484       [M-H]-
485       [M-H]-
486       [M-H]-
487       [M-H]-
488       [M-H]-
489       [M-H]-
490       [M-H]-
491       [M-H]-
492       [M-H]-
493       [M-H]-
494       [M-H]-
495       [M-H]-
496       [M-H]-
497       [M-H]-
498       [M-H]-
499       [M-H]-
500       [M-H]-
501       [M-H]-
502       [M-H]-
503       [M-H]-
504       [M-H]-
505       [M-H]-
506       [M-H]-
507       [M-H]-
508       [M-H]-
509       [M-H]-
510       [M-H]-
511       [M-H]-
512       [M-H]-
513       [M-H]-
514       [M-H]-
515       [M-H]-
516       [M-H]-
517       [M-H]-
518       [M-H]-
519       [M-H]-
520       [M-H]-
521       [M-H]-
522       [M-H]-
523       [M-H]-
524       [M-H]-
525       [M-H]-
526       [M-H]-
527       [M-H]-
528       [M-H]-
529       [M-H]-
530       [M-H]-
531       [M-H]-
532       [M-H]-
533       [M-H]-
534       [M-H]-
535       [M-H]-
536       [M-H]-
537       [M-H]-
538       [M-H]-
539       [M-H]-
540       [M-H]-
541       [M-H]-
542       [M-H]-
543       [M-H]-
544       [M-H]-
545       [M-H]-
546       [M-H]-
547       [M-H]-
548       [M-H]-
549       [M-H]-
550       [M-H]-
551       [M-H]-
552       [M-H]-
553       [M-H]-
554       [M-H]-
555       [M-H]-
556       [M-H]-
557       [M-H]-
558       [M-H]-
559       [M-H]-
560       [M-H]-
561       [M-H]-
562       [M-H]-
563       [M-H]-
564       [M-H]-
565       [M-H]-
566       [M-H]-
567       [M-H]-
568       [M-H]-
569       [M-H]-
570       [M-H]-
571       [M-H]-
572       [M-H]-
573       [M-H]-
574       [M-H]-
575       [M-H]-
576       [M-H]-
577       [M-H]-
578       [M-H]-
579       [M-H]-
580       [M-H]-
581       [M-H]-
582       [M-H]-
583       [M-H]-
584       [M-H]-
585       [M-H]-
586       [M-H]-
587       [M-H]-
588       [M-H]-
589       [M-H]-
590       [M-H]-
591       [M-H]-
592       [M-H]-
593       [M-H]-
594       [M-H]-
595       [M-H]-
596       [M-H]-
597       [M-H]-
598       [M-H]-
599       [M-H]-
600       [M-H]-
601       [M-H]-
602       [M-H]-
603       [M-H]-
604       [M-H]-
605       [M-H]-
606       [M-H]-
607       [M-H]-
608       [M-H]-
609       [M-H]-
610       [M-H]-
611       [M-H]-
612       [M-H]-
613       [M-H]-
614       [M-H]-
Warning: The "Metlin" column at position 10 in the METABOLITES table has all null values.
Warning: The "CAS" column at position 8 in the METABOLITES table may have incorrect values. 90% or more of the values are the same, but 10% or less are different.