Validation Log 2025-12-15 02:42:02.908046 mwtab Python Library Version: 2.0.0 Source: https://www.metabolomicsworkbench.org/rest/study/analysis_id/AN006015/mwtab/txt Study ID: ST003662 Analysis ID: AN006015 File format: txt Status: Contains Validation Issues Number of Issues: 130 Number of Warnings: 126 Number of Value Errors: 128 Number of Consistency Errors: 0 Number of Format Errors: 1 Issue Log: Error: The value, "18-35", for the subsection, "AGE_OR_AGE_RANGE", in the "SUBJECT" section should be a number or range (ex. "5-6") followed by a space with a unit (ex. "5 V") from the following list: ['weeks', 'days', 'months', 'years']. Ignore this when more complicated descriptions are required. Error: The value, "Male and female", for the subsection, "GENDER", in the "SUBJECT" section should be one of "Male", "Female", "Male, Female", "Hermaphrodite", or "N/A". Ignore this when more complicated descriptions are required. Error: The value, "45", for the subsection, "COLUMN_TEMPERATURE", in the "CHROMATOGRAPHY" section should be a number or range (ex. "5-6") followed by a space with a unit (ex. "5 V") from the following list: ['°C', 'C']. Ignore this when more complicated descriptions are required. Error: Unknown or invalid section, "FACTORS". Warning: The "Monoisotopic_mass" column at position 7 in the METABOLITES table, matches a standard column name, "mass". If this match was not in error, the column should be renamed to the standard name or a name that doesn't resemble the standard name. Warning: The "ID_inchikey" column at position 11 in the METABOLITES table, matches a standard column name, "inchi_key". If this match was not in error, the column should be renamed to the standard name or a name that doesn't resemble the standard name. Warning: The "ID_inchi" column at position 10 in the METABOLITES table, matches a standard column name, "inchi". If this match was not in error, the column should be renamed to the standard name or a name that doesn't resemble the standard name. Warning: The "ID_smiles" column at position 15 in the METABOLITES table, matches a standard column name, "smiles". If this match was not in error, the column should be renamed to the standard name or a name that doesn't resemble the standard name. Warning: The "ID_HMDB_Name" column at position 2 in the METABOLITES table, matches a standard column name, "name". If this match was not in error, the column should be renamed to the standard name or a name that doesn't resemble the standard name. Warning: The "ID_iupac_name" column at position 13 in the METABOLITES table, matches a standard column name, "name". If this match was not in error, the column should be renamed to the standard name or a name that doesn't resemble the standard name. Warning: The "Product Adduct" column at position 5 in the METABOLITES table, matches a standard column name, "adduct". If this match was not in error, the column should be renamed to the standard name or a name that doesn't resemble the standard name. Warning: The "ID_KEGG" column at position 16 in the METABOLITES table, matches a standard column name, "kegg_id". If this match was not in error, the column should be renamed to the standard name or a name that doesn't resemble the standard name. Warning: The "ID_HMDB_Name" column at position 2 in the METABOLITES table, matches a standard column name, "hmdb_id". If this match was not in error, the column should be renamed to the standard name or a name that doesn't resemble the standard name. Warning: The "ID_HMDB" column at position 8 in the METABOLITES table, matches a standard column name, "hmdb_id". If this match was not in error, the column should be renamed to the standard name or a name that doesn't resemble the standard name. Warning: The "ID_HMDB_Name" column at position 2 in the METABOLITES table, matches a standard column name, "hmdb_id", and some of the values in the column do not match the expected type or format for that column. The non-matching values are: 0 2-Hydroxybutyric acid 1 3-Hydroxybutyric acid 2 Adenosine monophosphate 3 5'-Methylthioadenosine 4 Adenine 5 L-Alanine 6 Aminoadipic acid 7 Argininosuccinic acid 8 L-Asparagine 9 Butyrylcarnitine 10 Cadaverine 11 L-Carnitine 12 Citric acid 13 Cysteic Acid 14 Cytosine 15 gamma-Aminobutyric acid 16 D-Glucose 17 L-Glutamic acid 18 L-Glutamine 19 Glycine 20 Guanidoacetic acid 21 Guanine 22 L-Histidine 23 L-Homoserine 24 Inosine 25 myo-Inositol 26 L-Isoleucine 27 L-Leucine 28 Mannitol 29 N-Acetylserine 30 N-Methylhydantoin 31 NAD 32 Niacinamide 33 Ophthalmic Acid 34 Ornithine 35 Pantothenic acid 36 L-Phenylalanine 37 Phosphorylcholine 38 L-Proline 39 Pyruvic acid 40 S-Adenosylmethionine 41 Sedoheptulose 7-phosphate 42 Thiamine 43 L-Threonine 44 Uridine 5'-monophosphate 45 Uridine 46 Xanthine 47 NADP 48 1,5-Anhydrosorbitol 49 2-Phosphoglyceric acid 50 4-Hydroxyproline 53 3-Hydroxybutyrylcarnitine 55 Valerylcarnitine 56 Hydroxyvalerylcarnitine 57 Hexanoylcarnitine 59 Creatine 60 Creatinine 61 Cytidine 62 Deoxyuridine 63 Dopamine 64 Glutathione 66 Glycerophosphocholine 68 Hypoxanthine 69 L-Kynurenine 70 L-Lactic acid 72 Mannitol-1-phosphate 73 Mevalonic acid 74 N4-Acetylcytidine 75 Nicotine 76 Oxalic acid 77 Phosphocreatine 78 Pseudouridine 79 Spermidine 80 Spermine 81 Uracil 82 Urea 83 L-Acetylcarnitine 85 Tiglylcarnitine 86 Oxidized glutathione 87 Ureidosuccinic Acid 90 3'-AMP 91 Pyridoxine 92 3-Methylcytidine 93 dCMP Warning: The "ID_ChemSpider" column at position 14 in the METABOLITES table, matches a standard column name, "chemspider_id". If this match was not in error, the column should be renamed to the standard name or a name that doesn't resemble the standard name. Warning: The "ID_CAS" column at position 12 in the METABOLITES table, matches a standard column name, "cas_number". If this match was not in error, the column should be renamed to the standard name or a name that doesn't resemble the standard name. Warning: The "ID_ChEBI" column at position 9 in the METABOLITES table, matches a standard column name, "chebi_id". If this match was not in error, the column should be renamed to the standard name or a name that doesn't resemble the standard name. Warning: The "RT_mean_Analyte" column at position 4 in the METABOLITES table, matches a standard column name, "retention_time". If this match was not in error, the column should be renamed to the standard name or a name that doesn't resemble the standard name. Warning: The column, "ID_HMDB_Name", in the METABOLITES table was matched to multiple standard names, ['name', 'hmdb_id']. This is a good indication that the values in that column should be split into the appropriate individual columns. Warning: The "78_Before" column at position 244 in the MS_METABOLITE_DATA table has all null values. Warning: The "78_After" column at position 245 in the MS_METABOLITE_DATA table has all null values. Warning: The "79_Before" column at position 246 in the MS_METABOLITE_DATA table has all null values. Warning: The "79_After" column at position 247 in the MS_METABOLITE_DATA table has all null values. Warning: The "93_Before" column at position 248 in the MS_METABOLITE_DATA table has all null values. Warning: The "93_After" column at position 249 in the MS_METABOLITE_DATA table has all null values. Warning: The "245_Before" column at position 250 in the MS_METABOLITE_DATA table has all null values. Warning: The "245_After" column at position 251 in the MS_METABOLITE_DATA table has all null values. Warning: The "317_Before" column at position 252 in the MS_METABOLITE_DATA table has all null values. Warning: The "317_After" column at position 253 in the MS_METABOLITE_DATA table has all null values. Warning: The "318_Before" column at position 254 in the MS_METABOLITE_DATA table has all null values. Warning: The "318_After" column at position 255 in the MS_METABOLITE_DATA table has all null values. Warning: The "320_Before" column at position 256 in the MS_METABOLITE_DATA table has all null values. Warning: The "320_After" column at position 257 in the MS_METABOLITE_DATA table has all null values. Warning: The "322_Before" column at position 258 in the MS_METABOLITE_DATA table has all null values. Warning: The "322_After" column at position 259 in the MS_METABOLITE_DATA table has all null values. Warning: The "356_Before" column at position 260 in the MS_METABOLITE_DATA table has all null values. Warning: The "356_After" column at position 261 in the MS_METABOLITE_DATA table has all null values. Warning: The "377_Before" column at position 262 in the MS_METABOLITE_DATA table has all null values. Warning: The "377_After" column at position 263 in the MS_METABOLITE_DATA table has all null values. Warning: The "394_Before" column at position 264 in the MS_METABOLITE_DATA table has all null values. Warning: The "394_After" column at position 265 in the MS_METABOLITE_DATA table has all null values. Warning: The "408_Before" column at position 266 in the MS_METABOLITE_DATA table has all null values. Warning: The "408_After" column at position 267 in the MS_METABOLITE_DATA table has all null values. Warning: The "415_Before" column at position 268 in the MS_METABOLITE_DATA table has all null values. Warning: The "415_After" column at position 269 in the MS_METABOLITE_DATA table has all null values. Warning: The "600_Before" column at position 270 in the MS_METABOLITE_DATA table has all null values. Warning: The "600_After" column at position 271 in the MS_METABOLITE_DATA table has all null values. Warning: The "601_Before" column at position 272 in the MS_METABOLITE_DATA table has all null values. Warning: The "601_After" column at position 273 in the MS_METABOLITE_DATA table has all null values. Warning: The "602_Before" column at position 274 in the MS_METABOLITE_DATA table has all null values. Warning: The "602_After" column at position 275 in the MS_METABOLITE_DATA table has all null values. Warning: The "Blank_Extr_1" column at position 276 in the MS_METABOLITE_DATA table has all null values. Warning: The "Blank_Extr_2" column at position 277 in the MS_METABOLITE_DATA table has all null values. Warning: The "Blank_Extr_3" column at position 278 in the MS_METABOLITE_DATA table has all null values. Warning: The "Blank_ISTD_1" column at position 279 in the MS_METABOLITE_DATA table has all null values. Warning: The "Blank_ISTD_2" column at position 280 in the MS_METABOLITE_DATA table has all null values. Warning: The "Blank_ISTD_3" column at position 281 in the MS_METABOLITE_DATA table has all null values. Warning: The "Blank_Solvent_2" column at position 282 in the MS_METABOLITE_DATA table has all null values. Warning: The "Blank_Solvent_3" column at position 283 in the MS_METABOLITE_DATA table has all null values. Warning: The "Blank_Solvent_4" column at position 284 in the MS_METABOLITE_DATA table has all null values. Warning: The "blood_pool10_1" column at position 285 in the MS_METABOLITE_DATA table has all null values. Warning: The "blood_pool5_1" column at position 286 in the MS_METABOLITE_DATA table has all null values. Warning: The "blood_pool6_1" column at position 287 in the MS_METABOLITE_DATA table has all null values. Warning: The "blood_pool7_1" column at position 288 in the MS_METABOLITE_DATA table has all null values. Warning: The "blood_pool8_1" column at position 289 in the MS_METABOLITE_DATA table has all null values. Warning: The "blood_pool9_1" column at position 290 in the MS_METABOLITE_DATA table has all null values. Warning: The "blood_poolall_1" column at position 291 in the MS_METABOLITE_DATA table has all null values. Warning: The "ESTD_1_1" column at position 292 in the MS_METABOLITE_DATA table has all null values. Warning: The "ESTD_10_1" column at position 293 in the MS_METABOLITE_DATA table has all null values. Warning: The "ESTD_100_1" column at position 294 in the MS_METABOLITE_DATA table has all null values. Warning: The "ESTD_1000_1" column at position 295 in the MS_METABOLITE_DATA table has all null values. Warning: The "ESTD_10000_1" column at position 296 in the MS_METABOLITE_DATA table has all null values. Warning: The "ESTD_25_1" column at position 297 in the MS_METABOLITE_DATA table has all null values. Warning: The "ESTD_250_1" column at position 298 in the MS_METABOLITE_DATA table has all null values. Warning: The "ESTD_25000_1" column at position 299 in the MS_METABOLITE_DATA table has all null values. Warning: The "ESTD_5_1" column at position 300 in the MS_METABOLITE_DATA table has all null values. Warning: The "ESTD_50_1" column at position 301 in the MS_METABOLITE_DATA table has all null values. Warning: The "ESTD_500_1" column at position 302 in the MS_METABOLITE_DATA table has all null values. Warning: The "ESTD_5000_1" column at position 303 in the MS_METABOLITE_DATA table has all null values. Warning: The "ESTD_75_1" column at position 304 in the MS_METABOLITE_DATA table has all null values. Warning: The "ESTD_750_1" column at position 305 in the MS_METABOLITE_DATA table has all null values. Warning: The "plasma_SRM_1-1" column at position 306 in the MS_METABOLITE_DATA table has all null values. Warning: The "plasma_SRM_1-10" column at position 307 in the MS_METABOLITE_DATA table has all null values. Warning: The "plasma_SRM_1-11" column at position 308 in the MS_METABOLITE_DATA table has all null values. Warning: The "plasma_SRM_1-12" column at position 309 in the MS_METABOLITE_DATA table has all null values. Warning: The "plasma_SRM_1-2" column at position 310 in the MS_METABOLITE_DATA table has all null values. Warning: The "plasma_SRM_1-3" column at position 311 in the MS_METABOLITE_DATA table has all null values. Warning: The "plasma_SRM_1-5" column at position 312 in the MS_METABOLITE_DATA table has all null values. Warning: The "plasma_SRM_1-6" column at position 313 in the MS_METABOLITE_DATA table has all null values. Warning: The "plasma_SRM_1-7" column at position 314 in the MS_METABOLITE_DATA table has all null values. Warning: The "plasma_SRM_1-8" column at position 315 in the MS_METABOLITE_DATA table has all null values. Warning: The "plasma_SRM_1-9" column at position 316 in the MS_METABOLITE_DATA table has all null values. Warning: The "plasma_SRM_2-1" column at position 317 in the MS_METABOLITE_DATA table has all null values. Warning: The "plasma_SRM_2-10" column at position 318 in the MS_METABOLITE_DATA table has all null values. Warning: The "plasma_SRM_2-11" column at position 319 in the MS_METABOLITE_DATA table has all null values. Warning: The "plasma_SRM_2-12" column at position 320 in the MS_METABOLITE_DATA table has all null values. Warning: The "plasma_SRM_2-2" column at position 321 in the MS_METABOLITE_DATA table has all null values. Warning: The "plasma_SRM_2-3" column at position 322 in the MS_METABOLITE_DATA table has all null values. Warning: The "plasma_SRM_2-5" column at position 323 in the MS_METABOLITE_DATA table has all null values. Warning: The "plasma_SRM_2-6" column at position 324 in the MS_METABOLITE_DATA table has all null values. Warning: The "plasma_SRM_2-7" column at position 325 in the MS_METABOLITE_DATA table has all null values. Warning: The "plasma_SRM_2-8" column at position 326 in the MS_METABOLITE_DATA table has all null values. Warning: The "plasma_SRM_2-9" column at position 327 in the MS_METABOLITE_DATA table has all null values. Warning: The "plasma_SRM_3-1" column at position 328 in the MS_METABOLITE_DATA table has all null values. Warning: The "plasma_SRM_3-10" column at position 329 in the MS_METABOLITE_DATA table has all null values. Warning: The "plasma_SRM_3-11" column at position 330 in the MS_METABOLITE_DATA table has all null values. Warning: The "plasma_SRM_3-12" column at position 331 in the MS_METABOLITE_DATA table has all null values. Warning: The "plasma_SRM_3-2" column at position 332 in the MS_METABOLITE_DATA table has all null values. Warning: The "plasma_SRM_3-3" column at position 333 in the MS_METABOLITE_DATA table has all null values. Warning: The "plasma_SRM_3-5" column at position 334 in the MS_METABOLITE_DATA table has all null values. Warning: The "plasma_SRM_3-6" column at position 335 in the MS_METABOLITE_DATA table has all null values. Warning: The "plasma_SRM_3-7" column at position 336 in the MS_METABOLITE_DATA table has all null values. Warning: The "plasma_SRM_3-8" column at position 337 in the MS_METABOLITE_DATA table has all null values. Warning: The "plasma_SRM_3-9" column at position 338 in the MS_METABOLITE_DATA table has all null values. Warning: The "QC_ESTD1000nM_1" column at position 339 in the MS_METABOLITE_DATA table has all null values. Warning: The "QC_ESTD1000nM_10" column at position 340 in the MS_METABOLITE_DATA table has all null values. Warning: The "QC_ESTD1000nM_11" column at position 341 in the MS_METABOLITE_DATA table has all null values. Warning: The "QC_ESTD1000nM_12" column at position 342 in the MS_METABOLITE_DATA table has all null values. Warning: The "QC_ESTD1000nM_13" column at position 343 in the MS_METABOLITE_DATA table has all null values. Warning: The "QC_ESTD1000nM_14" column at position 344 in the MS_METABOLITE_DATA table has all null values. Warning: The "QC_ESTD1000nM_15" column at position 345 in the MS_METABOLITE_DATA table has all null values. Warning: The "QC_ESTD1000nM_2" column at position 346 in the MS_METABOLITE_DATA table has all null values. Warning: The "QC_ESTD1000nM_3" column at position 347 in the MS_METABOLITE_DATA table has all null values. Warning: The "QC_ESTD1000nM_4" column at position 348 in the MS_METABOLITE_DATA table has all null values. Warning: The "QC_ESTD1000nM_5" column at position 349 in the MS_METABOLITE_DATA table has all null values. Warning: The "QC_ESTD1000nM_6" column at position 350 in the MS_METABOLITE_DATA table has all null values. Warning: The "QC_ESTD1000nM_7" column at position 351 in the MS_METABOLITE_DATA table has all null values. Warning: The "QC_ESTD1000nM_8" column at position 352 in the MS_METABOLITE_DATA table has all null values. Warning: The "QC_ESTD1000nM_9" column at position 353 in the MS_METABOLITE_DATA table has all null values.