Validation Log 2025-12-15 02:42:24.040677 mwtab Python Library Version: 2.0.0 Source: https://www.metabolomicsworkbench.org/rest/study/analysis_id/AN006020/mwtab/json Study ID: ST003664 Analysis ID: AN006020 File format: json Status: Contains Validation Issues Number of Issues: 9 Number of Warnings: 7 Number of Value Errors: 9 Number of Consistency Errors: 0 Number of Format Errors: 0 Issue Log: Error: The value, "45℃", in ["CHROMATOGRAPHY"]["COLUMN_TEMPERATURE"] should be a number or range (ex. "5-6") followed by a space with a unit (ex. "5 V") from the following list: ['°C', 'C']. Ignore this when more complicated descriptions are required. Error: The value, "15℃", in ["CHROMATOGRAPHY"]["INJECTION_TEMPERATURE"] should be a number or range (ex. "5-6") followed by a space with a unit (ex. "5 V") from the following list: ['°C', 'C'] or "room temperature". Ignore this when more complicated descriptions are required. Warning: The "m/z" column at position 7 in the ["MS_METABOLITE_DATA"]["Metabolites"] table, matches a standard column name, "moverz_quant". If this match was not in error, the column should be renamed to the standard name or a name that doesn't resemble the standard name. Warning: The "Calc. MW" column at position 6 in the ["MS_METABOLITE_DATA"]["Metabolites"] table, matches a standard column name, "mass". If this match was not in error, the column should be renamed to the standard name or a name that doesn't resemble the standard name. Warning: The "Formula" column at position 4 in the ["MS_METABOLITE_DATA"]["Metabolites"] table, matches a standard column name, "formula", and some of the values in the column do not match the expected type or format for that column. The non-matching values are: 0 C21 H41 N O4 1 C22 H43 N O4 2 C23 H45 N O4 3 C23 H43 N O4 4 C25 H49 N O4 5 C25 H47 N O4 6 C18 H37 N O3 7 C18 H37 N O3 8 C25 H49 N O3 9 C41 H81 N O3 10 C34 H69 N O3 11 C34 H69 N O3 12 C20 H41 N O3 13 C40 H81 N O3 14 C40 H81 N O3 15 C41 H83 N O3 16 C41 H83 N O3 17 C42 H85 N O3 18 C42 H85 N O3 19 C42 H85 N O3 20 C42 H83 N O3 21 C42 H83 N O3 22 C44 H89 N O3 23 C36 H71 N O3 24 C37 H69 N O3 25 C42 H83 N O3 26 C27 H53 N O3 27 C28 H55 N O3 28 C30 H59 N O3 29 C38 H75 N O3 30 C29 H57 N O3 31 C29 H55 N O3 32 C29 H55 N O3 33 C31 H61 N O3 34 C25 H43 N O2 35 C23 H47 N O2 36 C33 H67 N O2 37 C33 H67 N O2 38 C34 H69 N O2 39 C36 H73 N O2 40 C38 H77 N O2 41 C40 H81 N O2 42 C42 H85 N O2 43 C42 H83 N O2 44 C34 H65 N O2 45 C34 H65 N O2 46 C36 H69 N O2 47 C38 H73 N O2 48 C38 H73 N O2 49 C40 H77 N O2 50 C41 H77 N O2 51 C42 H81 N O2 52 C42 H81 N O2 53 C42 H79 N O2 54 C42 H79 N O2 55 C42 H77 N O2 56 C44 H83 N O2 57 C34 H63 N O2 58 C42 H79 N O2 59 C42 H77 N O2 60 C35 H71 N O2 61 C37 H75 N O2 62 C24 H49 N O2 63 C43 H83 N O2 64 C39 H79 N O2 65 C26 H53 N O2 66 C23 H45 N O2 72 C48 H93 N O8 73 C48 H93 N O8 74 C48 H89 N O8 75 C49 H91 N O8 76 C48 H87 N O8 77 C48 H93 N O9 78 C46 H87 N O13 79 C46 H87 N O13 80 C46 H87 N O13 81 C52 H99 N O13 82 C52 H99 N O13 83 C54 H103 N O13 84 C54 H103 N O13 85 C54 H103 N O13 86 C54 H101 N O13 87 C54 H101 N O13 88 C54 H101 N O13 89 C24 H50 N O7 P 90 C24 H50 N O7 P 91 C26 H54 N O7 P 92 C26 H52 N O7 P 93 C26 H52 N O7 P 94 C28 H52 N O7 P 95 C28 H50 N O7 P 96 C30 H52 N O7 P 97 C30 H50 N O7 P 98 C24 H52 N O6 P 99 C23 H48 N O7 P 100 C23 H46 N O7 P 101 C23 H46 N O7 P 102 C25 H44 N O7 P 103 C27 H46 N O7 P 104 C27 H44 N O7 P 105 C41 H75 N O8 P 106 C49 H97 N O8 P 107 C49 H89 N O8 P 108 C51 H99 N O8 P 109 C51 H97 N O8 P 110 C59 H89 N O8 P 111 C36 H72 N O8 P 112 C37 H74 N O8 P 113 C38 H76 N O8 P 114 C39 H76 N O8 P 115 C40 H76 N O8 P 116 C39 H78 N O8 P 117 C41 H80 N O8 P 118 C40 H80 N O8 P 119 C40 H78 N O8 P 120 C42 H84 N O8 P 121 C42 H82 N O8 P 122 C42 H80 N O8 P 123 C44 H80 N O8 P 124 C44 H78 N O8 P 125 C46 H80 N O8 P 126 C50 H86 N O8 P 127 C42 H80 N O8 P 128 C42 H78 N O8 P 129 C43 H84 N O8 P 130 C43 H82 N O8 P 131 C44 H86 N O8 P 132 C46 H86 N O8 P 133 C46 H84 N O8 P 134 C48 H86 N O8 P 135 C48 H84 N O8 P 136 C44 H84 N O8 P 137 C45 H86 N O8 P 138 C45 H84 N O8 P 139 C46 H88 N O8 P 140 C46 H84 N O8 P 141 C46 H82 N O8 P 142 C46 H80 N O8 P 143 C47 H90 N O8 P 144 C48 H92 N O8 P 145 C48 H84 N O8 P 146 C48 H82 N O8 P 147 C50 H96 N O8 P 148 C52 H100 N O8 P 149 C48 H88 N O8 P 150 C48 H86 N O8 P 151 C42 H78 N O8 P 152 C50 H98 N O8 P 153 C48 H80 N O8 P 154 C45 H84 N O8 P 155 C44 H82 N O8 P 156 C38 H74 N O8 P 157 C41 H82 N O8 P 158 C41 H78 N O8 P 159 C44 H88 N O8 P 160 C44 H78 N O8 P 161 C45 H88 N O8 P 162 C46 H90 N O8 P 163 C48 H94 N O8 P 164 C48 H88 N O8 P 165 C45 H80 N O8 P 166 C40 H82 N O7 P 167 C42 H82 N O7 P 168 C48 H86 N O7 P 169 C43 H86 N O7 P 170 C42 H86 N O7 P 171 C44 H88 N O7 P 172 C46 H88 N O7 P 173 C46 H86 N O7 P 174 C48 H88 N O7 P 175 C48 H86 N O7 P 176 C44 H86 N O7 P 177 C46 H84 N O7 P 178 C48 H84 N O7 P 179 C44 H84 N O7 P 180 C47 H84 N O7 P 181 C48 H82 N O7 P 182 C46 H84 N O7 P 183 C45 H76 N O7 P 184 C48 H96 N O7 P 185 C39 H80 N O7 P 186 C40 H80 N O7 P 187 C41 H84 N O7 P 188 C41 H82 N O7 P 189 C42 H84 N O7 P 190 C43 H84 N O7 P 191 C44 H90 N O7 P 192 C44 H84 N O7 P 193 C44 H82 N O7 P 194 C46 H92 N O7 P 195 C46 H86 N O7 P 196 C46 H86 N O7 P 197 C46 H82 N O7 P 198 C46 H82 N O7 P 199 C48 H94 N O7 P 200 C48 H90 N O7 P 201 C37 H72 N O8 P 202 C39 H76 N O8 P 203 C41 H74 N O8 P 204 C39 H74 N O8 P 205 C40 H76 N O8 P 206 C41 H80 N O8 P 207 C41 H78 N O8 P 208 C45 H80 N O8 P 209 C45 H78 N O8 P 210 C41 H78 N O8 P 211 C41 H76 N O8 P 212 C41 H76 N O8 P 213 C47 H90 N O8 P 214 C37 H70 N O8 P 215 C39 H70 N O8 P 216 C41 H72 N O8 P 217 C43 H78 N O8 P 218 C43 H76 N O8 P 219 C49 H90 N O8 P 220 C41 H72 N O8 P 221 C43 H76 N O8 P 222 C43 H74 N O8 P 223 C26 H44 N O8 P 224 C43 H74 N O8 P 225 C45 H76 N O8 P 226 C45 H76 N O8 P 227 C47 H92 N O8 P 228 C39 H74 N O8 P 229 C39 H78 N O7 P 230 C41 H78 N O7 P 231 C41 H74 N O7 P 232 C43 H80 N O7 P 233 C42 H78 N O7 P 234 C43 H84 N O7 P 235 C43 H82 N O7 P 236 C45 H84 N O7 P 237 C45 H82 N O7 P 238 C43 H80 N O7 P 239 C41 H76 N O7 P 240 C45 H80 N O7 P 241 C41 H82 N O7 P 242 C41 H80 N O7 P 243 C43 H86 N O7 P 244 C45 H78 N O7 P 245 C37 H72 N O7 P 246 C41 H74 N O7 P 247 C41 H72 N O7 P 248 C43 H78 N O7 P 249 C43 H76 N O7 P 250 C43 H74 N O7 P 251 C42 H76 N O7 P 252 C43 H76 N O7 P 253 C45 H82 N O7 P 254 C45 H80 N O7 P 255 C41 H78 N O7 P 256 C43 H82 N O7 P 257 C43 H80 N O7 P 258 C45 H76 N O7 P 259 C38 H76 N O7 P 312 C16 H35 N O 313 C17 H37 N O2 314 C18 H39 N O 315 C18 H39 N O2 316 C18 H37 N O2 317 C18 H35 N O 318 C19 H41 N O 319 C19 H41 N O 320 C19 H41 N O 321 C19 H41 N O 322 C19 H41 N O 323 C19 H39 N O 324 C19 H37 N O 325 C20 H43 N O 327 C49 H93 N O8 P 328 C27 H51 N O4 Warning: The "Lipid Class" column at position 2 in the ["MS_METABOLITE_DATA"]["Metabolites"] table, matches a standard column name, "class". If this match was not in error, the column should be renamed to the standard name or a name that doesn't resemble the standard name. Warning: The "Lipid subclass" column at position 3 in the ["MS_METABOLITE_DATA"]["Metabolites"] table, matches a standard column name, "class". If this match was not in error, the column should be renamed to the standard name or a name that doesn't resemble the standard name. Warning: The "Reference Ion" column at position 9 in the ["MS_METABOLITE_DATA"]["Metabolites"] table, matches a standard column name, "ion". If this match was not in error, the column should be renamed to the standard name or a name that doesn't resemble the standard name. Warning: The "RT [min]" column at position 8 in the ["MS_METABOLITE_DATA"]["Metabolites"] table, matches a standard column name, "retention_time". If this match was not in error, the column should be renamed to the standard name or a name that doesn't resemble the standard name.