Validation Log 2025-12-15 02:42:27.590068 mwtab Python Library Version: 2.0.0 Source: https://www.metabolomicsworkbench.org/rest/study/analysis_id/AN006021/mwtab/json Study ID: ST003664 Analysis ID: AN006021 File format: json Status: Contains Validation Issues Number of Issues: 11 Number of Warnings: 9 Number of Value Errors: 11 Number of Consistency Errors: 0 Number of Format Errors: 0 Issue Log: Error: The value, "45℃", in ["CHROMATOGRAPHY"]["COLUMN_TEMPERATURE"] should be a number or range (ex. "5-6") followed by a space with a unit (ex. "5 V") from the following list: ['°C', 'C']. Ignore this when more complicated descriptions are required. Error: The value, "15℃", in ["CHROMATOGRAPHY"]["INJECTION_TEMPERATURE"] should be a number or range (ex. "5-6") followed by a space with a unit (ex. "5 V") from the following list: ['°C', 'C'] or "room temperature". Ignore this when more complicated descriptions are required. Warning: The "m/z" column at position 7 in the ["MS_METABOLITE_DATA"]["Metabolites"] table, matches a standard column name, "moverz_quant". If this match was not in error, the column should be renamed to the standard name or a name that doesn't resemble the standard name. Warning: The "Calc. MW" column at position 6 in the ["MS_METABOLITE_DATA"]["Metabolites"] table, matches a standard column name, "mass". If this match was not in error, the column should be renamed to the standard name or a name that doesn't resemble the standard name. Warning: The "Formula" column at position 4 in the ["MS_METABOLITE_DATA"]["Metabolites"] table, matches a standard column name, "formula", and some of the values in the column do not match the expected type or format for that column. The non-matching values are: 9 C39 H78 N O8 P 10 C40 H78 N O8 P 11 C43 H80 N O8 P 12 C45 H82 N O8 P 13 C43 H82 N O8 P 14 C45 H78 N O8 P 15 C39 H72 N O8 P 16 C37 H72 N O7 P 17 C39 H74 N O7 P 18 C41 H74 N O7 P 19 C41 H72 N O7 P 20 C43 H78 N O7 P 21 C43 H76 N O7 P 22 C43 H74 N O7 P 23 C41 H80 N O7 P 24 C41 H78 N O7 P 25 C43 H84 N O7 P 26 C43 H78 N O7 P 27 C43 H76 N O7 P 28 C45 H82 N O7 P 29 C45 H80 N O7 P 30 C45 H78 N O7 P 62 C42 H78 N O10 P 63 C44 H80 N O10 P 64 C46 H80 N O10 P Warning: The "Lipid Class" column at position 2 in the ["MS_METABOLITE_DATA"]["Metabolites"] table, matches a standard column name, "class". If this match was not in error, the column should be renamed to the standard name or a name that doesn't resemble the standard name. Warning: The "Lipid subclass" column at position 3 in the ["MS_METABOLITE_DATA"]["Metabolites"] table, matches a standard column name, "class". If this match was not in error, the column should be renamed to the standard name or a name that doesn't resemble the standard name. Warning: The "Reference Ion" column at position 9 in the ["MS_METABOLITE_DATA"]["Metabolites"] table, matches a standard column name, "ion". If this match was not in error, the column should be renamed to the standard name or a name that doesn't resemble the standard name. Warning: The "RT [min]" column at position 8 in the ["MS_METABOLITE_DATA"]["Metabolites"] table, matches a standard column name, "retention_time". If this match was not in error, the column should be renamed to the standard name or a name that doesn't resemble the standard name. Warning: The "Lipid subclass" column at position 3 in the ["MS_METABOLITE_DATA"]["Metabolites"] table has all null values. Warning: The "Annotation Source" column at position 10 in the ["MS_METABOLITE_DATA"]["Metabolites"] table may have incorrect values. 90% or more of the values are the same, but 10% or less are different.