Validation Log 2025-12-15 02:43:05.622507 mwtab Python Library Version: 2.0.0 Source: https://www.metabolomicsworkbench.org/rest/study/analysis_id/AN006039/mwtab/txt Study ID: ST003678 Analysis ID: AN006039 File format: txt Status: Contains Validation Issues Number of Issues: 6 Number of Warnings: 4 Number of Value Errors: 6 Number of Consistency Errors: 0 Number of Format Errors: 0 Issue Log: Error: The value, "~200–270 μL/min", for the subsection, "FLOW_RATE", in the "CHROMATOGRAPHY" section should be a number or range (ex. "5-6") followed by a space with a unit (ex. "5 V") from the following list: ['mL/min', 'uL/min', 'μL/min']. Ignore this when more complicated descriptions are required. Error: The value, "25", for the subsection, "COLUMN_TEMPERATURE", in the "CHROMATOGRAPHY" section should be a number or range (ex. "5-6") followed by a space with a unit (ex. "5 V") from the following list: ['°C', 'C']. Ignore this when more complicated descriptions are required. Warning: The "CalcMz" column at position 9 in the METABOLITES table, matches a standard column name, "moverz_quant". If this match was not in error, the column should be renamed to the standard name or a name that doesn't resemble the standard name. Warning: The "IonFormula" column at position 10 in the METABOLITES table, matches a standard column name, "formula". If this match was not in error, the column should be renamed to the standard name or a name that doesn't resemble the standard name. Warning: The "IonFormula" column at position 10 in the METABOLITES table, matches a standard column name, "formula", and some of the values in the column do not match the expected type or format for that column. The non-matching values are: 182 C28 H47 O0 563 C22 H44 O9 N0 P1 564 C23 H44 O9 N0 P1 565 C25 H48 O9 N0 P1 640 C31 H60 O8 N0 P1 641 C33 H64 O8 N0 P1 642 C35 H68 O8 N0 P1 644 C37 H70 O8 N0 P1 645 C39 H68 O8 N0 P1 646 C35 H70 O7 N0 P1 647 C41 H72 O7 N0 P1 648 C33 H62 O8 N0 P1 649 C35 H64 O8 N0 P1 650 C37 H68 O8 N0 P1 651 C37 H66 O8 N0 P1 652 C41 H66 O8 N0 P1 653 C36 H68 O8 N0 P1 654 C37 H72 O8 N0 P1 655 C39 H74 O8 N0 P1 656 C35 H66 O8 N0 P1 657 C39 H72 O8 N0 P1 658 C41 H70 O8 N0 P1 659 C37 H72 O7 N0 P1 660 C38 H72 O8 N0 P1 661 C35 H66 O10 N0 P1 662 C37 H70 O10 N0 P1 663 C37 H72 O7 N0 P1 664 C39 H76 O7 N0 P1 665 C41 H70 O7 N0 P1 1483 C31 H60 O8 N0 P1 1484 C35 H64 O8 N0 P1 1485 C37 H68 O8 N0 P1 1486 C39 H72 O8 N0 P1 1487 C37 H66 O8 N0 P1 1488 C41 H76 O15 N0 P1 1489 C41 H76 O10 N0 P1 1490 C42 H84 O8 N0 P1 1491 C46 H82 O8 N0 P1 1492 C34 H66 O10 N0 P1 1494 C36 H70 O10 N0 P1 1496 C38 H72 O10 N0 P1 1498 C42 H74 O10 N0 P1 1499 C44 H74 O10 N0 P1 1500 C38 H70 O10 N0 P1 1502 C40 H74 O10 N0 P1 1503 C40 H72 O10 N0 P1 1504 C37 H70 O10 N0 P1 1506 C41 H76 O10 N0 P1 1508 C42 H78 O10 N0 P1 1509 C42 H76 O10 N0 P1 1510 C44 H76 O10 N0 P1 1511 C40 H76 O11 N0 P1 1513 C43 H82 O10 N0 P1 1514 C36 H70 O10 N0 P1 1520 C41 H76 O15 N0 P1 1521 C43 H74 O13 N0 P1 1522 C35 H66 O13 N0 P1 1524 C37 H70 O13 N0 P1 1525 C39 H74 O13 N0 P1 1527 C41 H78 O13 N0 P1 1528 C41 H76 O13 N0 P1 1530 C43 H80 O13 N0 P1 1531 C45 H80 O13 N0 P1 1533 C45 H78 O13 N0 P1 1535 C47 H78 O13 N0 P1 1536 C45 H80 O12 N0 P1 1537 C47 H84 O12 N0 P1 1538 C39 H72 O13 N0 P1 1540 C41 H74 O13 N0 P1 1541 C42 H78 O13 N0 P1 1542 C43 H80 O13 N0 P1 1544 C43 H78 O13 N0 P1 1546 C43 H76 O13 N0 P1 1548 C45 H76 O13 N0 P1 1549 C46 H82 O13 N0 P1 1551 C46 H80 O13 N0 P1 1552 C42 H76 O13 N0 P1 1554 C44 H80 O13 N0 P1 1556 C46 H78 O13 N0 P1 1558 C43 H82 O13 N0 P1 1559 C44 H84 O13 N0 P1 1560 C45 H86 O13 N0 P1 1561 C45 H86 O13 N0 P1 1562 C45 H85 O13 N0 P1 Na1 1564 C45 H84 O13 N0 P1 1565 C47 H88 O13 N0 P1 1567 C47 H86 O13 N0 P1 1569 C47 H84 O13 N0 P1 1571 C47 H82 O13 N0 P1 1572 C49 H92 O13 N0 P1 1573 C49 H90 O13 N0 P1 1574 C49 H88 O13 N0 P1 1576 C49 H86 O13 N0 P1 1578 C49 H84 O13 N0 P1 1580 C49 H82 O13 N0 P1 1581 C43 H84 O12 N0 P1 1582 C49 H88 O12 N0 P1 1583 C45 H84 O13 N0 P1 1584 C45 H83 O13 N0 P1 Na1 1586 C45 H82 O13 N0 P1 1588 C45 H80 O13 N0 P1 1590 C47 H82 O13 N0 P1 1591 C47 H82 O13 N0 P1 1592 C47 H81 O13 N0 P1 Na1 1594 C47 H80 O13 N0 P1 1596 C49 H82 O13 N0 P1 1598 C49 H80 O13 N0 P1 1599 C43 H80 O14 N0 P1 1600 C43 H82 O12 N0 P1 1601 C47 H82 O12 N0 P1 1602 C49 H82 O12 N0 P1 1604 C47 H78 O13 N0 P1 1605 C43 H78 O14 N0 P1 1606 C48 H86 O13 N0 P1 1607 C48 H84 O13 N0 P1 1608 C44 H82 O13 N0 P1 1609 C46 H86 O13 N0 P1 1610 C46 H84 O13 N0 P1 1612 C48 H82 O13 N0 P1 1613 C49 H78 O13 N0 P1 1614 C47 H82 O15 N0 P1 1615 C51 H80 O13 N0 P1 1618 C41 H76 O14 N0 P1 1619 C43 H82 O13 N0 P1 1621 C48 H84 O15 N0 P1 1622 C50 H82 O15 N0 P1 1623 C47 H85 O15 N0 P2 1624 C47 H87 O15 N0 P2 1625 C44 H87 O15 N0 P2 1626 C40 H68 O18 N0 P3 1627 C38 H72 O10 N0 P1 2080 C27 H43 O0 Warning: The "FA4" column at position 8 in the METABOLITES table may have incorrect values. 90% or more of the values are the same, but 10% or less are different.