Validation Log
2025-12-15 02:43:46.401214
mwtab Python Library Version: 2.0.0
Source:        https://www.metabolomicsworkbench.org/rest/study/analysis_id/AN006061/mwtab/txt
Study ID:      ST003694
Analysis ID:   AN006061
File format:   txt
Status: Contains Validation Issues
Number of Issues: 13

Number of Warnings: 11

Number of Value Errors: 13

Number of Consistency Errors: 0

Number of Format Errors: 0

Issue Log:
Error: The value, "0.35 mL/min;", for the subsection, "FLOW_RATE", in the "CHROMATOGRAPHY" section should be a number or range (ex. "5-6") followed by a space with a unit (ex. "5 V") from the following list: ['mL/min', 'uL/min', 'μL/min']. Ignore this when more complicated descriptions are required.
Error: The value, "45°C", for the subsection, "COLUMN_TEMPERATURE", in the "CHROMATOGRAPHY" section should be a number or range (ex. "5-6") followed by a space with a unit (ex. "5 V") from the following list: ['°C', 'C']. Ignore this when more complicated descriptions are required.
Warning: The "Molecular Weight" column at position 3 in the METABOLITES table, matches a standard column name, "mass". If this match was not in error, the column should be renamed to the standard name or a name that doesn't resemble the standard name.
Warning: The "Pubchem CID" column at position 8 in the METABOLITES table, matches a standard column name, "pubchem_id". If this match was not in error, the column should be renamed to the standard name or a name that doesn't resemble the standard name.
Warning: The "HMDB" column at position 6 in the METABOLITES table, matches a standard column name, "hmdb_id". If this match was not in error, the column should be renamed to the standard name or a name that doesn't resemble the standard name.
Warning: The "lipidmaps ID" column at position 7 in the METABOLITES table, matches a standard column name, "lm_id". If this match was not in error, the column should be renamed to the standard name or a name that doesn't resemble the standard name.
Warning: The "Metlin" column at position 11 in the METABOLITES table, matches a standard column name, "metlin_id". If this match was not in error, the column should be renamed to the standard name or a name that doesn't resemble the standard name.
Warning: The "CAS" column at position 9 in the METABOLITES table, matches a standard column name, "cas_number". If this match was not in error, the column should be renamed to the standard name or a name that doesn't resemble the standard name.
Warning: The "ChEBI" column at position 10 in the METABOLITES table, matches a standard column name, "chebi_id". If this match was not in error, the column should be renamed to the standard name or a name that doesn't resemble the standard name.
Warning: The "Ionization model" column at position 4 in the METABOLITES table, matches a standard column name, "ionization_mode". If this match was not in error, the column should be renamed to the standard name or a name that doesn't resemble the standard name.
Warning: The "Ionization model" column at position 4 in the METABOLITES table, matches a standard column name, "ionization_mode", and some of the values in the column do not match the expected type or format for that column. The non-matching values are:
0          [M+H]+
1          [M+H]+
2          [M+H]+
3          [M+H]+
4          [M+H]+
5          [M+H]+
6          [M+H]+
7          [M+H]+
8          [M+H]+
9          [M+H]+
10         [M+H]+
11         [M+H]+
12         [M+H]+
13         [M+H]+
14         [M+H]+
15         [M+H]+
16         [M+H]+
17         [M+H]+
18         [M+H]+
19         [M+H]+
20         [M+H]+
21     [M-H2O+H]+
22         [M+H]+
23         [M+H]+
24         [M+H]+
25         [M+H]+
26         [M+H]+
27         [M+H]+
28         [M+H]+
29         [M+H]+
30         [M+H]+
31         [M+H]+
32         [M+H]+
33         [M+H]+
34         [M+H]+
35         [M+H]+
36         [M+H]+
37         [M+H]+
38         [M+H]+
39         [M+H]+
40         [M+H]+
41         [M+H]+
42         [M+H]+
43         [M+H]+
44         [M+H]+
45         [M+H]+
46         [M+H]+
47         [M+H]+
48         [M+H]+
49         [M+H]+
50         [M+H]+
51         [M+H]+
52         [M+H]+
53         [M+H]+
54         [M+H]+
55         [M+H]+
56         [M+H]+
57         [M+H]+
58         [M+H]+
59         [M+H]+
60         [M+H]+
61         [M+H]+
62         [M+H]+
63       [M+NH4]+
64       [M+NH4]+
65       [M+NH4]+
66       [M+NH4]+
67       [M+NH4]+
68       [M+NH4]+
69       [M+NH4]+
70       [M+NH4]+
71       [M+NH4]+
72       [M+NH4]+
73       [M+NH4]+
74       [M+NH4]+
75       [M+NH4]+
76       [M+NH4]+
77       [M+NH4]+
78       [M+NH4]+
79       [M+NH4]+
80       [M+NH4]+
81       [M+NH4]+
82       [M+NH4]+
83       [M+NH4]+
84       [M+NH4]+
85       [M+NH4]+
86       [M+NH4]+
87       [M+NH4]+
88         [M+H]+
89         [M+H]+
90         [M+H]+
91         [M+H]+
92         [M+H]+
93         [M+H]+
94         [M+H]+
95         [M+H]+
96         [M+H]+
97         [M+H]+
98         [M+H]+
99         [M+H]+
100        [M+H]+
101        [M+H]+
102        [M+H]+
103        [M+H]+
104        [M+H]+
105        [M+H]+
106        [M+H]+
107        [M+H]+
108        [M+H]+
109        [M+H]+
110        [M+H]+
111        [M+H]+
112        [M+H]+
113        [M+H]+
114        [M+H]+
115        [M+H]+
116        [M+H]+
117        [M+H]+
118        [M+H]+
119        [M+H]+
120        [M+H]+
121        [M+H]+
122        [M+H]+
123        [M+H]+
124        [M+H]+
125        [M+H]+
126        [M+H]+
127        [M+H]+
128        [M+H]+
129        [M+H]+
130        [M+H]+
131        [M+H]+
132        [M+H]+
133        [M+H]+
134        [M+H]+
135        [M+H]+
136        [M+H]+
137        [M+H]+
138        [M+H]+
139        [M+H]+
140        [M+H]+
141        [M+H]+
142        [M+H]+
143        [M+H]+
144        [M+H]+
145        [M+H]+
146        [M+H]+
147        [M+H]+
148        [M+H]+
149        [M+H]+
150        [M+H]+
151        [M+H]+
152        [M+H]+
153        [M+H]+
154        [M+H]+
155        [M+H]+
156        [M+H]+
157        [M+H]+
158        [M+H]+
159        [M+H]+
160        [M+H]+
161        [M+H]+
162        [M+H]+
163        [M+H]+
164        [M+H]+
165        [M+H]+
166        [M+H]+
167        [M+H]+
168        [M+H]+
169        [M+H]+
170        [M+H]+
171        [M+H]+
172        [M+H]+
173        [M+H]+
174        [M+H]+
175        [M+H]+
176        [M+H]+
177        [M+H]+
178        [M+H]+
179        [M+H]+
180        [M+H]+
181        [M+H]+
182        [M+H]+
183        [M+H]+
184        [M+H]+
185        [M+H]+
186        [M+H]+
187        [M+H]+
188        [M+H]+
189        [M+H]+
190        [M+H]+
191        [M+H]+
192        [M+H]+
193        [M+H]+
194        [M+H]+
195        [M+H]+
196        [M+H]+
197        [M+H]+
198        [M+H]+
199        [M+H]+
200        [M+H]+
201        [M+H]+
202        [M+H]+
203        [M+H]+
204        [M+H]+
205        [M+H]+
206        [M+H]+
207        [M+H]+
208        [M+H]+
209        [M+H]+
210        [M+H]+
211        [M+H]+
212        [M+H]+
213        [M+H]+
214        [M+H]+
215        [M+H]+
216        [M+H]+
217        [M+H]+
218        [M+H]+
219        [M+H]+
220        [M+H]+
221        [M+H]+
222        [M+H]+
223        [M+H]+
224        [M+H]+
225        [M+H]+
226        [M+H]+
227        [M+H]+
228        [M+H]+
229        [M+H]+
230        [M+H]+
231        [M+H]+
232        [M+H]+
233        [M+H]+
234        [M+H]+
235        [M+H]+
236        [M+H]+
237        [M+H]+
238        [M+H]+
239        [M+H]+
240        [M+H]+
241        [M+H]+
242        [M+H]+
243        [M+H]+
244        [M+H]+
245        [M+H]+
246        [M+H]+
247        [M+H]+
248        [M+H]+
249        [M+H]+
250        [M+H]+
251        [M+H]+
252        [M+H]+
253        [M+H]+
254        [M+H]+
255        [M+H]+
256        [M+H]+
257        [M+H]+
258        [M+H]+
259        [M+H]+
260        [M+H]+
261        [M+H]+
262        [M+H]+
263        [M+H]+
264        [M+H]+
265        [M+H]+
266        [M+H]+
267        [M+H]+
268        [M+H]+
269        [M+H]+
270        [M+H]+
271        [M+H]+
272        [M+H]+
273        [M+H]+
274        [M+H]+
275        [M+H]+
276        [M+H]+
277        [M+H]+
278        [M+H]+
279        [M+H]+
280        [M+H]+
281        [M+H]+
282        [M+H]+
283        [M+H]+
284        [M+H]+
285        [M+H]+
286        [M+H]+
287        [M+H]+
288        [M+H]+
289        [M+H]+
290        [M+H]+
291        [M+H]+
292        [M+H]+
293        [M+H]+
294      [M+NH4]+
295      [M+NH4]+
296      [M+NH4]+
297      [M+NH4]+
298      [M+NH4]+
299      [M+NH4]+
300      [M+NH4]+
301      [M+NH4]+
302      [M+NH4]+
303      [M+NH4]+
304      [M+NH4]+
305      [M+NH4]+
306      [M+NH4]+
307      [M+NH4]+
308      [M+NH4]+
309      [M+NH4]+
310      [M+NH4]+
311      [M+NH4]+
312      [M+NH4]+
313      [M+NH4]+
314      [M+NH4]+
315      [M+NH4]+
316      [M+NH4]+
317      [M+NH4]+
318      [M+NH4]+
319      [M+NH4]+
320      [M+NH4]+
321      [M+NH4]+
322      [M+NH4]+
323      [M+NH4]+
324      [M+NH4]+
325      [M+NH4]+
326      [M+NH4]+
327      [M+NH4]+
328      [M+NH4]+
329      [M+NH4]+
330      [M+NH4]+
331      [M+NH4]+
332      [M+NH4]+
333      [M+NH4]+
334      [M+NH4]+
335      [M+NH4]+
336      [M+NH4]+
337      [M+NH4]+
338      [M+NH4]+
339      [M+NH4]+
340      [M+NH4]+
341      [M+NH4]+
342      [M+NH4]+
343      [M+NH4]+
344      [M+NH4]+
345      [M+NH4]+
346      [M+NH4]+
347      [M+NH4]+
348      [M+NH4]+
349      [M+NH4]+
350      [M+NH4]+
351      [M+NH4]+
352      [M+NH4]+
353      [M+NH4]+
354      [M+NH4]+
355      [M+NH4]+
356      [M+NH4]+
357      [M+NH4]+
358      [M+NH4]+
359      [M+NH4]+
360      [M+NH4]+
361      [M+NH4]+
362      [M+NH4]+
363      [M+NH4]+
364      [M+NH4]+
365      [M+NH4]+
366      [M+NH4]+
367      [M+NH4]+
368      [M+NH4]+
369      [M+NH4]+
370      [M+NH4]+
371      [M+NH4]+
372      [M+NH4]+
373      [M+NH4]+
374      [M+NH4]+
375      [M+NH4]+
376      [M+NH4]+
377      [M+NH4]+
378      [M+NH4]+
379      [M+NH4]+
380      [M+NH4]+
381      [M+NH4]+
382      [M+NH4]+
383      [M+NH4]+
384      [M+NH4]+
385      [M+NH4]+
386      [M+NH4]+
387      [M+NH4]+
388      [M+NH4]+
389      [M+NH4]+
390      [M+NH4]+
391      [M+NH4]+
392      [M+NH4]+
393      [M+NH4]+
394      [M+NH4]+
395      [M+NH4]+
396      [M+NH4]+
397      [M+NH4]+
398      [M+NH4]+
399      [M+NH4]+
400      [M+NH4]+
401        [M+H]+
402        [M+H]+
403        [M+H]+
404        [M+H]+
405        [M+H]+
406        [M+H]+
407        [M+H]+
408        [M+H]+
409        [M+H]+
410        [M+H]+
411        [M+H]+
412        [M+H]+
413        [M+H]+
414        [M+H]+
415        [M+H]+
416        [M+H]+
417        [M+H]+
418        [M+H]+
419        [M+H]+
420        [M+H]+
421        [M+H]+
422        [M+H]+
423        [M+H]+
424        [M+H]+
425        [M+H]+
426        [M+H]+
427        [M+H]+
428        [M+H]+
429        [M+H]+
430        [M+H]+
431        [M+H]+
432        [M+H]+
433        [M+H]+
434        [M+H]+
435        [M+H]+
436        [M+H]+
437        [M+H]+
438        [M+H]+
439        [M+H]+
440        [M+H]+
441        [M+H]+
442        [M+H]+
443        [M+H]+
444        [M+H]+
445      [M+NH4]+
446      [M+NH4]+
447      [M+NH4]+
448      [M+NH4]+
449        [M+H]+
450        [M+H]+
451        [M+H]+
452        [M+H]+
453        [M+H]+
454    [M-H2O+H]+
455    [M-H2O+H]+
456    [M-H2O+H]+
457    [M-H2O+H]+
458    [M-H2O+H]+
459    [M-H2O+H]+
460    [M-H2O+H]+
461    [M-H2O+H]+
462    [M-H2O+H]+
463    [M-H2O+H]+
464    [M-H2O+H]+
465    [M-H2O+H]+
466    [M-H2O+H]+
467    [M-H2O+H]+
468    [M-H2O+H]+
469    [M-H2O+H]+
470    [M-H2O+H]+
471    [M-H2O+H]+
472    [M-H2O+H]+
473    [M-H2O+H]+
474    [M-H2O+H]+
475    [M-H2O+H]+
476    [M-H2O+H]+
477    [M-H2O+H]+
478    [M-H2O+H]+
479    [M-H2O+H]+
480    [M-H2O+H]+
481    [M-H2O+H]+
482    [M-H2O+H]+
483    [M-H2O+H]+
484    [M-H2O+H]+
485    [M-H2O+H]+
486    [M-H2O+H]+
487    [M-H2O+H]+
488    [M-H2O+H]+
489    [M-H2O+H]+
490    [M-H2O+H]+
491    [M-H2O+H]+
492    [M-H2O+H]+
493    [M-H2O+H]+
494    [M-H2O+H]+
495    [M-H2O+H]+
496    [M-H2O+H]+
497    [M-H2O+H]+
498    [M-H2O+H]+
499    [M-H2O+H]+
500    [M-H2O+H]+
501    [M-H2O+H]+
502    [M-H2O+H]+
503    [M-H2O+H]+
504    [M-H2O+H]+
505    [M-H2O+H]+
506    [M-H2O+H]+
507    [M-H2O+H]+
508    [M-H2O+H]+
509      [M+NH4]+
510      [M+NH4]+
511      [M+NH4]+
512      [M+NH4]+
513      [M+NH4]+
514      [M+NH4]+
515      [M+NH4]+
516      [M+NH4]+
517      [M+NH4]+
518      [M+NH4]+
519      [M+NH4]+
520      [M+NH4]+
521      [M+NH4]+
522      [M+NH4]+
523    [M-H2O+H]+
524    [M-H2O+H]+
525    [M-H2O+H]+
526    [M-H2O+H]+
527    [M-H2O+H]+
528    [M-H2O+H]+
529    [M-H2O+H]+
530    [M-H2O+H]+
531    [M-H2O+H]+
532    [M-H2O+H]+
533    [M-H2O+H]+
534    [M-H2O+H]+
535    [M-H2O+H]+
536    [M-H2O+H]+
537    [M-H2O+H]+
538    [M-H2O+H]+
539    [M-H2O+H]+
540    [M-H2O+H]+
541    [M-H2O+H]+
542    [M-H2O+H]+
543    [M-H2O+H]+
544    [M-H2O+H]+
545    [M-H2O+H]+
546    [M-H2O+H]+
547    [M-H2O+H]+
548    [M-H2O+H]+
549    [M-H2O+H]+
550    [M-H2O+H]+
Warning: The "ChEBI" column at position 10 in the METABOLITES table has all null values.
Warning: The "Metlin" column at position 11 in the METABOLITES table has all null values.