Validation Log
2025-12-15 02:49:53.930112
mwtab Python Library Version: 2.0.0
Source:        https://www.metabolomicsworkbench.org/rest/study/analysis_id/AN006205/mwtab/txt
Study ID:      ST003778
Analysis ID:   AN006205
File format:   txt
Status: Contains Validation Issues
Number of Issues: 21

Number of Warnings: 10

Number of Value Errors: 17

Number of Consistency Errors: 2

Number of Format Errors: 0

Issue Log:
Error: The value, "NA", for the subsection, "WEIGHT_OR_WEIGHT_RANGE", in the "SUBJECT" section should be a number or range (ex. "5-6") followed by a space with a unit (ex. "5 V") from the following list: ['g', 'mg', 'kg', 'lbs']. Ignore this when more complicated descriptions are required.
Error: The value, "NA", for the subsection, "HEIGHT_OR_HEIGHT_RANGE", in the "SUBJECT" section should be a number or range (ex. "5-6") followed by a space with a unit (ex. "5 V") from the following list: ['cm', 'in']. Ignore this when more complicated descriptions are required.
Error: An empty value or a null value was detected for the subsection, "ANIMAL_LIGHT_CYCLE", in the "SUBJECT" section. Either a legitimate value should be provided for this subsection, or it should be removed altogether.
Error: An empty value or a null value was detected for the subsection, "COLLISION_ENERGY", in the "MS" section. Either a legitimate value should be provided for this subsection, or it should be removed altogether.
Error: The value, "NA", for the subsection, "COLLISION_GAS", in the "MS" section should be one of "Nitrogen" or "Argon". Ignore this when more complicated descriptions are required.
Error: The value, "50", for the subsection, "DRY_GAS_FLOW", in the "MS" section should be a number followed by a space with a unit (ex. "5 V") from the following list: ['L/hr', 'L/min']. Ignore this when more complicated descriptions are required.
Error: The value, "120", for the subsection, "DRY_GAS_TEMP", in the "MS" section should be a number followed by a space with a unit (ex. "5 V") from the following list: ['°C', 'C']. Ignore this when more complicated descriptions are required.
Error: The value, "300", for the subsection, "SOURCE_TEMPERATURE", in the "MS" section should be a number followed by a space with a unit (ex. "5 V") from the following list: ['°C', 'C']. Ignore this when more complicated descriptions are required.
Error: The value, "60 bar at starting conditions. 180 bar at %A", for the subsection, "COLUMN_PRESSURE", in the "CHROMATOGRAPHY" section should be a number or range (ex. "5-6") followed by a space with a unit (ex. "5 V") from the following list: ['psi', 'bar']. Ignore this when more complicated descriptions are required.
Error: The following metabolites in the, MS_METABOLITE_DATA table were not found in the METABOLITES table:
	"1_1^-bis-valienamine"
	"1_1^-bis-valienamine_1"
	"16-bromo-hexadecadien-5_13-diynoic acid"
	"1-(beta-D-Ribofuranosyl)-1_4-dihydronicotinamide"
	"(1S_2R)-3-oxo-2-(5^-hydroxy-2^Z-pentenyl)-cyclopentaneacetic acid"
	"(2-{[3-(3_4-dihydroxy-5-methoxyphenyl)prop-2-enoyl]oxy}ethyl)trimethylazanium"
	"(2-{[3-(3_4-dihydroxy-5-methoxyphenyl)prop-2-enoyl]oxy}ethyl)trimethylazanium_1"
	"2-{[(3_5-dimethoxyphenyl)(hydroxy)methylidene]amino}acetic acid"
	"2_3-Dihydroxy-isovalerate"
	"2-Amino-2-methyl-1_3-propandiol"
	"2-Dimethylamino-5_6-dimethylpyrimidin-4-ol"
	"2-{[hydroxy(4-hydroxy-3_5-dimethoxyphenyl)methylidene]amino}acetic acid"
	"2-{[hydroxy(4-hydroxy-3_5-dimethoxyphenyl)methylidene]amino}acetic acid_1"
	"2^-hydroxypyridoxol"
	"2-oxohexa-4_5-cyclopropyl-5-enoate"
	"(2R_5R)-5-carboxymethyl proline"
	"3_4-dihydroquinoxaline-2-carboxylate"
	"3^_5^-Cyclic dGMP"
	"3_6_8-Trimethylallantoin"
	"3a_7a_12b-Trihydroxy-5b-cholanoic acid"
	"3-amino-2_3-dideoxy-scyllo-inosose"
	"3-Aminopropane-1_2-diol"
	"4-(2-Aminophenyl)-2_4-dioxobutanoic acid"
	"4-(2-aminophenyl)-3-hydroxy-2_4-dioxobutanoate"
	"4_4-Dimethyl-5a-cholesta-8_24-dien-3-b-ol"
	"4-propyl-2_3-dihydro-1H-pyrrole-2-carboxylate"
	"4-propylidene-2_3-dihydropyrrole-2-carboxylate"
	"4-propylidene-2_3-dihydropyrrole-2-carboxylate_1"
	"5-(2^-Carboxyethyl)-4_6-dihydroxypicolinate"
	"6-Butyryl-5_7-dihydroxy-8-(3^_3^-dimethylallyl)-4-phenylcoumarin"
	"9_10-dehydrofusarate"
	"9_10-DHOME"
	"Guanosine 2^_3^-cyclic phosphate"
	"N1-citryl-N3-oct-2-enoyl-N3-hydroxy-1_3-diaminopropane"
	"N-[2-(3_4-dimethoxyphenyl)ethyl]-3-(3-hydroxy-4-methoxyphenyl)prop-2-enimidic acid"
	"N-(2_3-Dihydroxybenzoyl)-L-serine"
	"N-(4_5-Dihydro-1-methyl-4-oxo-1H-imidazol-2-yl)alanine"
	"N6_N6_N6-Trimethyl-L-lysine"
	"Ne_Ne dimethyllysine"
	"N_N-diacetyl-L-lysyl-D-alanyl-D-lactate"
	"norspermidine-2_3-dihydroxybenzoate"
Error: The following metabolites in the METABOLITES table were not found in the MS_METABOLITE_DATA table:
	"1,1'-bis-valienamine"
	"1,1'-bis-valienamine_1"
	"16-bromo-hexadecadien-5,13-diynoic acid"
	"1-(beta-D-Ribofuranosyl)-1,4-dihydronicotinamide"
	"(1S,2R)-3-oxo-2-(5'-hydroxy-2'Z-pentenyl)-cyclopentaneacetic acid"
	"(2-{[3-(3,4-dihydroxy-5-methoxyphenyl)prop-2-enoyl]oxy}ethyl)trimethylazanium"
	"(2-{[3-(3,4-dihydroxy-5-methoxyphenyl)prop-2-enoyl]oxy}ethyl)trimethylazanium_1"
	"2-{[(3,5-dimethoxyphenyl)(hydroxy)methylidene]amino}acetic acid"
	"2,3-Dihydroxy-isovalerate"
	"2-Amino-2-methyl-1,3-propandiol"
	"2-Dimethylamino-5,6-dimethylpyrimidin-4-ol"
	"2-{[hydroxy(4-hydroxy-3,5-dimethoxyphenyl)methylidene]amino}acetic acid"
	"2-{[hydroxy(4-hydroxy-3,5-dimethoxyphenyl)methylidene]amino}acetic acid_1"
	"2'-hydroxypyridoxol"
	"2-oxohexa-4,5-cyclopropyl-5-enoate"
	"(2R,5R)-5-carboxymethyl proline"
	"3,4-dihydroquinoxaline-2-carboxylate"
	"3',5'-Cyclic dGMP"
	"3,6,8-Trimethylallantoin"
	"3a,7a,12b-Trihydroxy-5b-cholanoic acid"
	"3-amino-2,3-dideoxy-scyllo-inosose"
	"3-Aminopropane-1,2-diol"
	"4-(2-Aminophenyl)-2,4-dioxobutanoic acid"
	"4-(2-aminophenyl)-3-hydroxy-2,4-dioxobutanoate"
	"4,4-Dimethyl-5a-cholesta-8,24-dien-3-b-ol"
	"4-propyl-2,3-dihydro-1H-pyrrole-2-carboxylate"
	"4-propylidene-2,3-dihydropyrrole-2-carboxylate"
	"4-propylidene-2,3-dihydropyrrole-2-carboxylate_1"
	"5-(2'-Carboxyethyl)-4,6-dihydroxypicolinate"
	"6-Butyryl-5,7-dihydroxy-8-(3',3'-dimethylallyl)-4-phenylcoumarin"
	"9,10-dehydrofusarate"
	"9,10-DHOME"
	"Guanosine 2',3'-cyclic phosphate"
	"N1-citryl-N3-oct-2-enoyl-N3-hydroxy-1,3-diaminopropane"
	"N-[2-(3,4-dimethoxyphenyl)ethyl]-3-(3-hydroxy-4-methoxyphenyl)prop-2-enimidic acid"
	"N-(2,3-Dihydroxybenzoyl)-L-serine"
	"N-(4,5-Dihydro-1-methyl-4-oxo-1H-imidazol-2-yl)alanine"
	"N6,N6,N6-Trimethyl-L-lysine"
	"Ne,Ne dimethyllysine"
	"N,N-diacetyl-L-lysyl-D-alanyl-D-lactate"
	"norspermidine-2,3-dihydroxybenzoate"
Warning: The "ri" column at position 7 in the METABOLITES table, matches a standard column name, "retention_index". If this match was not in error, the column should be renamed to the standard name or a name that doesn't resemble the standard name.
Warning: The "ri_type" column at position 8 in the METABOLITES table, matches a standard column name, "retention_index_type". If this match was not in error, the column should be renamed to the standard name or a name that doesn't resemble the standard name.
Warning: The column pair, "ri" and "ri_type", in the METABOLITES table should have data in the same rows, but at least one row has data in one column and nothing in the other.
Warning: The standard column, "other_id", was found in the METABOLITES table as "other_id". If this column contains database IDs for standard databases such as KEGG, PubChem, HMDB, etc., it is recommended to make individual columns for these and not lump them together into a less descriptive "other_id" column.
Warning: The "pubchem_id" column at position 2 in the METABOLITES table has all null values.
Warning: The "inchi_key" column at position 3 in the METABOLITES table has all null values.
Warning: The "other_id" column at position 5 in the METABOLITES table has all null values.
Warning: The "other_id_type" column at position 6 in the METABOLITES table has all null values.
Warning: The "ri_type" column at position 8 in the METABOLITES table has all null values.
Warning: The "moverz_quant" column at position 9 in the METABOLITES table has all null values.