Validation Log 2025-12-15 02:52:23.716235 mwtab Python Library Version: 2.0.0 Source: https://www.metabolomicsworkbench.org/rest/study/analysis_id/AN006242/mwtab/json Study ID: ST003797 Analysis ID: AN006242 File format: json Status: Contains Validation Issues Number of Issues: 15 Number of Warnings: 0 Number of Value Errors: 14 Number of Consistency Errors: 0 Number of Format Errors: 1 Issue Log: Error: The value, "1mL/min", in ["MS"]["HELIUM_FLOW"] should be a number followed by a space with a unit (ex. "5 V") from the following list: ['mL/min']. Ignore this when more complicated descriptions are required. Error: The value, "230℃", in ["MS"]["ION_SOURCE_TEMPERATURE"] should be a number followed by a space with a unit (ex. "5 V") from the following list: ['°C', 'C']. Ignore this when more complicated descriptions are required. Error: The value, "1411V", in ["MS"]["ION_SPRAY_VOLTAGE"] should be a number followed by a space with a unit (ex. "5 V") from the following list: ['V', 'kV']. Ignore this when more complicated descriptions are required. Error: An empty value or a null value was detected in ["CHROMATOGRAPHY"]["FLOW_GRADIENT"]. A legitimate value should be provided for this required key. Error: The value, "90℃-205℃-310℃", in ["CHROMATOGRAPHY"]["COLUMN_TEMPERATURE"] should be a number or range (ex. "5-6") followed by a space with a unit (ex. "5 V") from the following list: ['°C', 'C']. Ignore this when more complicated descriptions are required. Error: The value, "1μL", in ["CHROMATOGRAPHY"]["SAMPLE_INJECTION"] should be a number followed by a space with a unit (ex. "5 V") from the following list: ['μL', 'uL']. Ignore this when more complicated descriptions are required. Error: An empty value or a null value was detected in ["CHROMATOGRAPHY"]["SOLVENT_A"]. A legitimate value should be provided for this required key. Error: An empty value or a null value was detected in ["CHROMATOGRAPHY"]["SOLVENT_B"]. A legitimate value should be provided for this required key. Error: The value, "270°C", in ["CHROMATOGRAPHY"]["INJECTION_TEMPERATURE"] should be a number or range (ex. "5-6") followed by a space with a unit (ex. "5 V") from the following list: ['°C', 'C'] or "room temperature". Ignore this when more complicated descriptions are required. Error: The value, "29min(leaf); 38min(kernel)", in ["CHROMATOGRAPHY"]["ANALYTICAL_TIME"] should be a number or range (ex. "5-6") followed by a space with a unit (ex. "5 V") from the following list: ['min']. Ignore this when more complicated descriptions are required. Error: The value, "300℃", in ["CHROMATOGRAPHY"]["TRANSFERLINE_TEMPERATURE"] should be a number followed by a space with a unit (ex. "5 V") from the following list: ['°C', 'C']. Ignore this when more complicated descriptions are required. Error: The value, "8μL", in ["CHROMATOGRAPHY"]["WEAK_WASH_VOLUME"] should be a number followed by a space with a unit (ex. "5 V") from the following list: ['μL', 'uL']. Ignore this when more complicated descriptions are required. Error: The value, "8μL", in ["CHROMATOGRAPHY"]["STRONG_WASH_VOLUME"] should be a number followed by a space with a unit (ex. "5 V") from the following list: ['μL', 'uL']. Ignore this when more complicated descriptions are required. Error: The value, "10μL", in ["CHROMATOGRAPHY"]["SAMPLE_SYRINGE_SIZE"] should be a number followed by a space with a unit (ex. "5 V") from the following list: ['μL', 'uL']. Ignore this when more complicated descriptions are required. Error: The ["MS_METABOLITE_DATA"]["Metabolites"] table does not have a column for "Metabolite". It is likely misspelled or using a common incorrect substitute.