Validation Log 2026-04-12 08:17:47.499326 mwtab Python Library Version: 2.0.0 Source: https://www.metabolomicsworkbench.org/rest/study/analysis_id/AN006313/mwtab/txt Study ID: ST003841 Analysis ID: AN006313 File format: txt Status: Contains Validation Issues Number of Issues: 13 Number of Warnings: 10 Number of Value Errors: 10 Number of Consistency Errors: 2 Number of Format Errors: 0 Issue Log: Error: The value, "20-25", for the subsection, "COLUMN_TEMPERATURE", in the "CHROMATOGRAPHY" section should be a number or range (ex. "5-6") followed by a space with a unit (ex. "5 V") from the following list: ['°C', 'C']. Ignore this when more complicated descriptions are required. Error: The following metabolites in the, MS_METABOLITE_DATA table were not found in the METABOLITES table: "1_3-bisphospho-D-glycerate" "2_3-bisphospho-D-glycerate" "3_4-dihydroxymandelic acid" "3_4-dihydroxyphenylpropanoate" "5^-deoxyadenosine" "5^-methylthioadenosine" "cAMP(2^_3^) / cAMP(3^_5^)" "cCMP(2^_3^-)" "D-arabinono-1_4-lactone" "F-1_6/2_6-DP" Error: The following metabolites in the METABOLITES table were not found in the MS_METABOLITE_DATA table: "1,3-bisphospho-D-glycerate" "2,3-bisphospho-D-glycerate" "3,4-dihydroxymandelic acid" "3,4-dihydroxyphenylpropanoate" "5'-deoxyadenosine" "5'-methylthioadenosine" "cAMP(2',3') / cAMP(3',5')" "cCMP(2',3'-)" "D-arabinono-1,4-lactone" "F-1,6/2,6-DP" Warning: The "ri" column at position 7 in the METABOLITES table, matches a standard column name, "retention_index". If this match was not in error, the column should be renamed to the standard name or a name that doesn't resemble the standard name. Warning: The "ri_type" column at position 8 in the METABOLITES table, matches a standard column name, "retention_index_type". If this match was not in error, the column should be renamed to the standard name or a name that doesn't resemble the standard name. Warning: The standard column, "other_id", was found in the METABOLITES table as "other_id". If this column contains database IDs for standard databases such as KEGG, PubChem, HMDB, etc., it is recommended to make individual columns for these and not lump them together into a less descriptive "other_id" column. Warning: The "pubchem_id" column at position 2 in the METABOLITES table has all null values. Warning: The "inchi_key" column at position 3 in the METABOLITES table has all null values. Warning: The "other_id" column at position 5 in the METABOLITES table has all null values. Warning: The "other_id_type" column at position 6 in the METABOLITES table has all null values. Warning: The "ri" column at position 7 in the METABOLITES table has all null values. Warning: The "ri_type" column at position 8 in the METABOLITES table has all null values. Warning: The "moverz_quant" column at position 9 in the METABOLITES table has all null values.