Validation Log
2025-12-15 02:56:03.870905
mwtab Python Library Version: 2.0.0
Source:        https://www.metabolomicsworkbench.org/rest/study/analysis_id/AN006357/mwtab/txt
Study ID:      ST003868
Analysis ID:   AN006357
File format:   txt
Status: Contains Validation Issues
Number of Issues: 10

Number of Warnings: 7

Number of Value Errors: 10

Number of Consistency Errors: 0

Number of Format Errors: 0

Issue Log:
Error: An empty value or a null value was detected for the subsection, "NUM_MALES", in the "STUDY" section. Either a legitimate value should be provided for this subsection, or it should be removed altogether.
Error: An empty value or a null value was detected for the subsection, "NUM_FEMALES", in the "STUDY" section. Either a legitimate value should be provided for this subsection, or it should be removed altogether.
Error: The value, "ambient", for the subsection, "COLUMN_TEMPERATURE", in the "CHROMATOGRAPHY" section should be a number or range (ex. "5-6") followed by a space with a unit (ex. "5 V") from the following list: ['°C', 'C']. Ignore this when more complicated descriptions are required.
Warning: The "Mass Accuracy Score" column at position 3 in the METABOLITES table, matches a standard column name, "mass". If this match was not in error, the column should be renamed to the standard name or a name that doesn't resemble the standard name.
Warning: The "Molecular Weight" column at position 9 in the METABOLITES table, matches a standard column name, "mass". If this match was not in error, the column should be renamed to the standard name or a name that doesn't resemble the standard name.
Warning: The "Molecular Formula" column at position 8 in the METABOLITES table, matches a standard column name, "formula". If this match was not in error, the column should be renamed to the standard name or a name that doesn't resemble the standard name.
Warning: The "Molecular Formula" column at position 8 in the METABOLITES table, matches a standard column name, "formula", and some of the values in the column do not match the expected type or format for that column. The non-matching values are:
0          C 9H 11NO 3
1          C 10H 12N 2
2           C 5H 9NO 2
3           C 5H 9NO 2
4         C 10H 11NO 3
5          C 9H 11NO 2
6        C 5H 12N 2O 2
7        C 5H 12N 2O 2
8           C 5H 9NO 4
9          C 6H 13NO 2
10         C 5H 11NO 3
11         C 5H 11NO 3
12          C 6H 6N 2O
13          C 6H 6N 2O
14       C 6H 14N 2O 2
15          C 5H 9NO 4
16         C 6H 13NO 2
17          C 5H 7NO 3
18            C 9H 7NO
19         C 6H 13NO 2
20         C 6H 13NO 2
21        C 6H 9N 3O 2
22       C 5H 12N 2O 2
23       C 5H 12N 2O 2
24       C 5H 10N 2O 3
25         C 6H 13NO 2
26         C 6H 13NO 2
27          C 4H 9NO 2
28       C 6H 14N 4O 2
29          C 5H 14N 4
30          C 5H 7NO 3
31          C 5H 7NO 3
32           C 6H 9NOS
33          C 4H 9NO 2
34          C 5H 9NO 2
35          C 5H 9NO 2
36         C 5H 11NO 2
37         C 9H 11NO 3
38      C 11H 12N 2O 2
39      C 11H 12N 2O 2
40       C 5H 10N 2O 3
41          C 5H 9NO 4
42          C 6H 6N 2O
43        C 5H 11NO 2S
44        C 5H 11NO 2S
45      C 19H 38N 2O 3
46          C 4H 9NO 2
47          C 5H 14N 2
48        C 4H 9N 3O 2
49         C 5H 11NO 2
50           C 5H 13NO
51           C 5H 13NO
52          C 4H 12N 2
53         C 8H 11NO 2
54            C 8H 11N
55         C 8H 11NO 2
56          C 4H 9NO 2
57            C 8H 9NO
58     C 21H 39N 7O 12
59        C 10H 13NO 2
60        C 5H 11NO 2S
61           C 6H 6O 3
62        C 11H 11NO 3
63          C 9H 10O 4
64           C 5H 13NO
65           C 8H 11NO
66         C 6H 13NO 5
67          C 6H 6N 2O
68          C 6H 6N 2O
69        C 4H 9N 3O 2
70             H 3O 4P
71        C 17H 17N 3S
72         C 7H 13NO 4
73         C 9H 11NO 2
74           C 4H 6O 2
75     C 17H 18FN 3O 3
76          C 4H 9NO 2
77           C 9H 8O 2
78         C 8H 11NO 2
79          C 10H 11NO
80          C 9H 10O 3
81            C 5H 5NO
82          C 5H 14N 2
83          C 9H 10O 4
84            C 9H 9NO
85          C 4H 9NO 2
86          C 9H 10O 4
87            C 4H 7NO
88         C 9H 11NO 3
89           C 9H 8O 3
90         C 9H 11NO 3
91          C 9H 10O 4
92          C 7H 7NO 2
93          C 5H 10O 3
94            C 9H 9NO
95          C 7H 7NO 2
96         C 9H 11NO 3
97          C 9H 10O 4
98      C 12H 12N 2O 2
99         C 9H 11NO 3
100     C 17H 20N 4O 6
101         C 8H 10O 2
102           C 8H 10O
103         C 8H 10O 2
104          C 8H 11NO
105          C 8H 11NO
106         C 8H 10O 2
107          C 8H 11NO
108          C 8H 11NO
109         C 9H 10O 4
110          C 9H 8O 3
111           C 5H 5NO
112          C 9H 8O 3
113           C 5H 5NO
114        C 6H 13NO 3
115         C 9H 10O 3
116         C 7H 7NO 2
117         C 9H 10O 4
118        C 9H 11NO 3
119         C 8H 10O 2
Warning: The "Retention Time (min)" column at position 10 in the METABOLITES table, matches a standard column name, "retention_time". If this match was not in error, the column should be renamed to the standard name or a name that doesn't resemble the standard name.
Warning: The "Method" column at position 11 in the METABOLITES table, matches a standard column name, "ms_method". If this match was not in error, the column should be renamed to the standard name or a name that doesn't resemble the standard name.
Warning: There are duplicate column names in the METABOLITES table.