Validation Log 2025-12-15 02:56:45.885933 mwtab Python Library Version: 2.0.0 Source: https://www.metabolomicsworkbench.org/rest/study/analysis_id/AN006373/mwtab/json Study ID: ST003880 Analysis ID: AN006373 File format: json Status: Contains Validation Issues Number of Issues: 73 Number of Warnings: 61 Number of Value Errors: 72 Number of Consistency Errors: 0 Number of Format Errors: 1 Issue Log: Error: The value, "22-76", in ["SUBJECT"]["AGE_OR_AGE_RANGE"] should be a number or range (ex. "5-6") followed by a space with a unit (ex. "5 V") from the following list: ['weeks', 'days', 'months', 'years']. Ignore this when more complicated descriptions are required. Error: The value, "Male and female", in ["SUBJECT"]["GENDER"] should be one of "Male", "Female", "Male, Female", "Hermaphrodite", or "N/A". Ignore this when more complicated descriptions are required. Error: The value, "320°C", in ["MS"]["CAPILLARY_TEMPERATURE"] should be a number or range (ex. "5-6") followed by a space with a unit (ex. "5 V") from the following list: ['°C', 'C']. Ignore this when more complicated descriptions are required. Error: The value, "3500 V", in ["MS"]["SPRAY_VOLTAGE"] should be a number followed by a space with a unit (ex. "5 V") from the following list: ['kV']. Ignore this when more complicated descriptions are required. Error: The value in ["MS"]["DESOLVATION_GAS_FLOW"] should be a number followed by a space with a unit (ex. "5 V") from the following list: ['L/hr', 'L/min']. Ignore this when more complicated descriptions are required. Error: The value, "40", in ["CHROMATOGRAPHY"]["COLUMN_TEMPERATURE"] should be a number or range (ex. "5-6") followed by a space with a unit (ex. "5 V") from the following list: ['°C', 'C']. Ignore this when more complicated descriptions are required. Error: The value, "4 microlitre", in ["CHROMATOGRAPHY"]["SAMPLE_INJECTION"] should be a number followed by a space with a unit (ex. "5 V") from the following list: ['μL', 'uL']. Ignore this when more complicated descriptions are required. Error: The value, "10", in ["CHROMATOGRAPHY"]["INJECTION_TEMPERATURE"] should be a number or range (ex. "5-6") followed by a space with a unit (ex. "5 V") from the following list: ['°C', 'C'] or "room temperature". Ignore this when more complicated descriptions are required. Error: The value, "350", in ["CHROMATOGRAPHY"]["TRANSFERLINE_TEMPERATURE"] should be a number followed by a space with a unit (ex. "5 V") from the following list: ['°C', 'C']. Ignore this when more complicated descriptions are required. Error: The value, "10", in ["CHROMATOGRAPHY"]["TARGET_SAMPLE_TEMPERATURE"] should be a number followed by a space with a unit (ex. "5 V") from the following list: ['°C', 'C']. Ignore this when more complicated descriptions are required. Error: The value, "20 microlitre", in ["CHROMATOGRAPHY"]["SAMPLE_LOOP_SIZE"] should be a number followed by a space with a unit (ex. "5 V") from the following list: ['μL', 'uL']. Ignore this when more complicated descriptions are required. Warning: The SSF at ["SUBJECT_SAMPLE_FACTORS"][0] has the following duplicate keys in its Additional sample data: "RAW_FILE_NAME(Raw_file_name)" "RAW_FILE_NAME(Raw_file_name)" Warning: The SSF at ["SUBJECT_SAMPLE_FACTORS"][1] has the following duplicate keys in its Additional sample data: "RAW_FILE_NAME(Raw_file_name)" "RAW_FILE_NAME(Raw_file_name)" Warning: The SSF at ["SUBJECT_SAMPLE_FACTORS"][2] has the following duplicate keys in its Additional sample data: "RAW_FILE_NAME(Raw_file_name)" "RAW_FILE_NAME(Raw_file_name)" Warning: The SSF at ["SUBJECT_SAMPLE_FACTORS"][3] has the following duplicate keys in its Additional sample data: "RAW_FILE_NAME(Raw_file_name)" "RAW_FILE_NAME(Raw_file_name)" Warning: The SSF at ["SUBJECT_SAMPLE_FACTORS"][4] has the following duplicate keys in its Additional sample data: "RAW_FILE_NAME(Raw_file_name)" "RAW_FILE_NAME(Raw_file_name)" Warning: The SSF at ["SUBJECT_SAMPLE_FACTORS"][5] has the following duplicate keys in its Additional sample data: "RAW_FILE_NAME(Raw_file_name)" "RAW_FILE_NAME(Raw_file_name)" Warning: The SSF at ["SUBJECT_SAMPLE_FACTORS"][6] has the following duplicate keys in its Additional sample data: "RAW_FILE_NAME(Raw_file_name)" "RAW_FILE_NAME(Raw_file_name)" Warning: The SSF at ["SUBJECT_SAMPLE_FACTORS"][7] has the following duplicate keys in its Additional sample data: "RAW_FILE_NAME(Raw_file_name)" "RAW_FILE_NAME(Raw_file_name)" Warning: The SSF at ["SUBJECT_SAMPLE_FACTORS"][8] has the following duplicate keys in its Additional sample data: "RAW_FILE_NAME(Raw_file_name)" "RAW_FILE_NAME(Raw_file_name)" Warning: The SSF at ["SUBJECT_SAMPLE_FACTORS"][9] has the following duplicate keys in its Additional sample data: "RAW_FILE_NAME(Raw_file_name)" "RAW_FILE_NAME(Raw_file_name)" Warning: The SSF at ["SUBJECT_SAMPLE_FACTORS"][10] has the following duplicate keys in its Additional sample data: "RAW_FILE_NAME(Raw_file_name)" "RAW_FILE_NAME(Raw_file_name)" Warning: The SSF at ["SUBJECT_SAMPLE_FACTORS"][11] has the following duplicate keys in its Additional sample data: "RAW_FILE_NAME(Raw_file_name)" "RAW_FILE_NAME(Raw_file_name)" Warning: The SSF at ["SUBJECT_SAMPLE_FACTORS"][12] has the following duplicate keys in its Additional sample data: "RAW_FILE_NAME(Raw_file_name)" "RAW_FILE_NAME(Raw_file_name)" Warning: The SSF at ["SUBJECT_SAMPLE_FACTORS"][13] has the following duplicate keys in its Additional sample data: "RAW_FILE_NAME(Raw_file_name)" "RAW_FILE_NAME(Raw_file_name)" Warning: The SSF at ["SUBJECT_SAMPLE_FACTORS"][14] has the following duplicate keys in its Additional sample data: "RAW_FILE_NAME(Raw_file_name)" "RAW_FILE_NAME(Raw_file_name)" Warning: The SSF at ["SUBJECT_SAMPLE_FACTORS"][15] has the following duplicate keys in its Additional sample data: "RAW_FILE_NAME(Raw_file_name)" "RAW_FILE_NAME(Raw_file_name)" Warning: The SSF at ["SUBJECT_SAMPLE_FACTORS"][16] has the following duplicate keys in its Additional sample data: "RAW_FILE_NAME(Raw_file_name)" "RAW_FILE_NAME(Raw_file_name)" Warning: The SSF at ["SUBJECT_SAMPLE_FACTORS"][17] has the following duplicate keys in its Additional sample data: "RAW_FILE_NAME(Raw_file_name)" "RAW_FILE_NAME(Raw_file_name)" Warning: The SSF at ["SUBJECT_SAMPLE_FACTORS"][18] has the following duplicate keys in its Additional sample data: "RAW_FILE_NAME(Raw_file_name)" "RAW_FILE_NAME(Raw_file_name)" Warning: The SSF at ["SUBJECT_SAMPLE_FACTORS"][19] has the following duplicate keys in its Additional sample data: "RAW_FILE_NAME(Raw_file_name)" "RAW_FILE_NAME(Raw_file_name)" Warning: The SSF at ["SUBJECT_SAMPLE_FACTORS"][20] has the following duplicate keys in its Additional sample data: "RAW_FILE_NAME(Raw_file_name)" "RAW_FILE_NAME(Raw_file_name)" Warning: The SSF at ["SUBJECT_SAMPLE_FACTORS"][21] has the following duplicate keys in its Additional sample data: "RAW_FILE_NAME(Raw_file_name)" "RAW_FILE_NAME(Raw_file_name)" Warning: The SSF at ["SUBJECT_SAMPLE_FACTORS"][22] has the following duplicate keys in its Additional sample data: "RAW_FILE_NAME(Raw_file_name)" "RAW_FILE_NAME(Raw_file_name)" Warning: The SSF at ["SUBJECT_SAMPLE_FACTORS"][23] has the following duplicate keys in its Additional sample data: "RAW_FILE_NAME(Raw_file_name)" "RAW_FILE_NAME(Raw_file_name)" Warning: The SSF at ["SUBJECT_SAMPLE_FACTORS"][24] has the following duplicate keys in its Additional sample data: "RAW_FILE_NAME(Raw_file_name)" "RAW_FILE_NAME(Raw_file_name)" Warning: The SSF at ["SUBJECT_SAMPLE_FACTORS"][25] has the following duplicate keys in its Additional sample data: "RAW_FILE_NAME(Raw_file_name)" "RAW_FILE_NAME(Raw_file_name)" Warning: The SSF at ["SUBJECT_SAMPLE_FACTORS"][26] has the following duplicate keys in its Additional sample data: "RAW_FILE_NAME(Raw_file_name)" "RAW_FILE_NAME(Raw_file_name)" Warning: The SSF at ["SUBJECT_SAMPLE_FACTORS"][27] has the following duplicate keys in its Additional sample data: "RAW_FILE_NAME(Raw_file_name)" "RAW_FILE_NAME(Raw_file_name)" Warning: The SSF at ["SUBJECT_SAMPLE_FACTORS"][28] has the following duplicate keys in its Additional sample data: "RAW_FILE_NAME(Raw_file_name)" "RAW_FILE_NAME(Raw_file_name)" Warning: The SSF at ["SUBJECT_SAMPLE_FACTORS"][29] has the following duplicate keys in its Additional sample data: "RAW_FILE_NAME(Raw_file_name)" "RAW_FILE_NAME(Raw_file_name)" Warning: The SSF at ["SUBJECT_SAMPLE_FACTORS"][30] has the following duplicate keys in its Additional sample data: "RAW_FILE_NAME(Raw_file_name)" "RAW_FILE_NAME(Raw_file_name)" Warning: The SSF at ["SUBJECT_SAMPLE_FACTORS"][31] has the following duplicate keys in its Additional sample data: "RAW_FILE_NAME(Raw_file_name)" "RAW_FILE_NAME(Raw_file_name)" Warning: The SSF at ["SUBJECT_SAMPLE_FACTORS"][32] has the following duplicate keys in its Additional sample data: "RAW_FILE_NAME(Raw_file_name)" "RAW_FILE_NAME(Raw_file_name)" Warning: The SSF at ["SUBJECT_SAMPLE_FACTORS"][33] has the following duplicate keys in its Additional sample data: "RAW_FILE_NAME(Raw_file_name)" "RAW_FILE_NAME(Raw_file_name)" Warning: The SSF at ["SUBJECT_SAMPLE_FACTORS"][34] has the following duplicate keys in its Additional sample data: "RAW_FILE_NAME(Raw_file_name)" "RAW_FILE_NAME(Raw_file_name)" Warning: The SSF at ["SUBJECT_SAMPLE_FACTORS"][35] has the following duplicate keys in its Additional sample data: "RAW_FILE_NAME(Raw_file_name)" "RAW_FILE_NAME(Raw_file_name)" Warning: The SSF at ["SUBJECT_SAMPLE_FACTORS"][36] has the following duplicate keys in its Additional sample data: "RAW_FILE_NAME(Raw_file_name)" "RAW_FILE_NAME(Raw_file_name)" Warning: The SSF at ["SUBJECT_SAMPLE_FACTORS"][37] has the following duplicate keys in its Additional sample data: "RAW_FILE_NAME(Raw_file_name)" "RAW_FILE_NAME(Raw_file_name)" Warning: The SSF at ["SUBJECT_SAMPLE_FACTORS"][38] has the following duplicate keys in its Additional sample data: "RAW_FILE_NAME(Raw_file_name)" "RAW_FILE_NAME(Raw_file_name)" Warning: The SSF at ["SUBJECT_SAMPLE_FACTORS"][39] has the following duplicate keys in its Additional sample data: "RAW_FILE_NAME(Raw_file_name)" "RAW_FILE_NAME(Raw_file_name)" Warning: The SSF at ["SUBJECT_SAMPLE_FACTORS"][40] has the following duplicate keys in its Additional sample data: "RAW_FILE_NAME(Raw_file_name)" "RAW_FILE_NAME(Raw_file_name)" Warning: The SSF at ["SUBJECT_SAMPLE_FACTORS"][41] has the following duplicate keys in its Additional sample data: "RAW_FILE_NAME(Raw_file_name)" "RAW_FILE_NAME(Raw_file_name)" Warning: The SSF at ["SUBJECT_SAMPLE_FACTORS"][42] has the following duplicate keys in its Additional sample data: "RAW_FILE_NAME(Raw_file_name)" "RAW_FILE_NAME(Raw_file_name)" Warning: The SSF at ["SUBJECT_SAMPLE_FACTORS"][43] has the following duplicate keys in its Additional sample data: "RAW_FILE_NAME(Raw_file_name)" "RAW_FILE_NAME(Raw_file_name)" Warning: The SSF at ["SUBJECT_SAMPLE_FACTORS"][44] has the following duplicate keys in its Additional sample data: "RAW_FILE_NAME(Raw_file_name)" "RAW_FILE_NAME(Raw_file_name)" Warning: The SSF at ["SUBJECT_SAMPLE_FACTORS"][45] has the following duplicate keys in its Additional sample data: "RAW_FILE_NAME(Raw_file_name)" "RAW_FILE_NAME(Raw_file_name)" Warning: The SSF at ["SUBJECT_SAMPLE_FACTORS"][46] has the following duplicate keys in its Additional sample data: "RAW_FILE_NAME(Raw_file_name)" "RAW_FILE_NAME(Raw_file_name)" Warning: The SSF at ["SUBJECT_SAMPLE_FACTORS"][47] has the following duplicate keys in its Additional sample data: "RAW_FILE_NAME(Raw_file_name)" "RAW_FILE_NAME(Raw_file_name)" Warning: The SSF at ["SUBJECT_SAMPLE_FACTORS"][48] has the following duplicate keys in its Additional sample data: "RAW_FILE_NAME(Raw_file_name)" "RAW_FILE_NAME(Raw_file_name)" Warning: The SSF at ["SUBJECT_SAMPLE_FACTORS"][49] has the following duplicate keys in its Additional sample data: "RAW_FILE_NAME(Raw_file_name)" "RAW_FILE_NAME(Raw_file_name)" Warning: The SSF at ["SUBJECT_SAMPLE_FACTORS"][50] has the following duplicate keys in its Additional sample data: "RAW_FILE_NAME(Raw_file_name)" "RAW_FILE_NAME(Raw_file_name)" Warning: The SSF at ["SUBJECT_SAMPLE_FACTORS"][51] has the following duplicate keys in its Additional sample data: "RAW_FILE_NAME(Raw_file_name)" "RAW_FILE_NAME(Raw_file_name)" Warning: The SSF at ["SUBJECT_SAMPLE_FACTORS"][52] has the following duplicate keys in its Additional sample data: "RAW_FILE_NAME(Raw_file_name)" "RAW_FILE_NAME(Raw_file_name)" Warning: The SSF at ["SUBJECT_SAMPLE_FACTORS"][53] has the following duplicate keys in its Additional sample data: "RAW_FILE_NAME(Raw_file_name)" "RAW_FILE_NAME(Raw_file_name)" Warning: The SSF at ["SUBJECT_SAMPLE_FACTORS"][54] has the following duplicate keys in its Additional sample data: "RAW_FILE_NAME(Raw_file_name)" "RAW_FILE_NAME(Raw_file_name)" Warning: The SSF at ["SUBJECT_SAMPLE_FACTORS"][55] has the following duplicate keys in its Additional sample data: "RAW_FILE_NAME(Raw_file_name)" "RAW_FILE_NAME(Raw_file_name)" Warning: The SSF at ["SUBJECT_SAMPLE_FACTORS"][56] has the following duplicate keys in its Additional sample data: "RAW_FILE_NAME(Raw_file_name)" "RAW_FILE_NAME(Raw_file_name)" Warning: The SSF at ["SUBJECT_SAMPLE_FACTORS"][57] has the following duplicate keys in its Additional sample data: "RAW_FILE_NAME(Raw_file_name)" "RAW_FILE_NAME(Raw_file_name)" Warning: The SSF at ["SUBJECT_SAMPLE_FACTORS"][58] has the following duplicate keys in its Additional sample data: "RAW_FILE_NAME(Raw_file_name)" "RAW_FILE_NAME(Raw_file_name)" Warning: The SSF at ["SUBJECT_SAMPLE_FACTORS"][59] has the following duplicate keys in its Additional sample data: "RAW_FILE_NAME(Raw_file_name)" "RAW_FILE_NAME(Raw_file_name)" Warning: The SSF at ["SUBJECT_SAMPLE_FACTORS"][60] has the following duplicate keys in its Additional sample data: "RAW_FILE_NAME(Raw_file_name)" "RAW_FILE_NAME(Raw_file_name)" Error: The ["MS_METABOLITE_DATA"]["Metabolites"] table does not have a column for "Metabolite". It is likely misspelled or using a common incorrect substitute.