Validation Log 2025-12-15 03:12:21.408752 mwtab Python Library Version: 2.0.0 Source: https://www.metabolomicsworkbench.org/rest/study/analysis_id/AN006736/mwtab/json Study ID: ST004070 Analysis ID: AN006736 File format: json Status: Contains Validation Issues Number of Issues: 12 Number of Warnings: 4 Number of Value Errors: 12 Number of Consistency Errors: 0 Number of Format Errors: 0 Issue Log: Error: An empty value or a null value was detected in ["MS_METABOLITE_DATA"]["Units"]. A legitimate value should be provided for this required key. Error: An empty value or a null value was detected in ["CHROMATOGRAPHY"]["INSTRUMENT_NAME"]. A legitimate value should be provided for this required key. Error: An empty value or a null value was detected in ["CHROMATOGRAPHY"]["COLUMN_NAME"]. A legitimate value should be provided for this required key. Error: An empty value or a null value was detected in ["CHROMATOGRAPHY"]["FLOW_GRADIENT"]. A legitimate value should be provided for this required key. Error: The value, "none", in ["CHROMATOGRAPHY"]["FLOW_RATE"] should be a number or range (ex. "5-6") followed by a space with a unit (ex. "5 V") from the following list: ['mL/min', 'uL/min', 'μL/min']. Ignore this when more complicated descriptions are required. Error: The value, "none", in ["CHROMATOGRAPHY"]["COLUMN_TEMPERATURE"] should be a number or range (ex. "5-6") followed by a space with a unit (ex. "5 V") from the following list: ['°C', 'C']. Ignore this when more complicated descriptions are required. Error: An empty value or a null value was detected in ["CHROMATOGRAPHY"]["SOLVENT_A"]. A legitimate value should be provided for this required key. Error: An empty value or a null value was detected in ["CHROMATOGRAPHY"]["SOLVENT_B"]. A legitimate value should be provided for this required key. Warning: The SSF at ["SUBJECT_SAMPLE_FACTORS"][0] has the following duplicate keys in its Additional sample data: "RAW_FILE_NAME(Raw Data Files)" "RAW_FILE_NAME(Raw Data Files)" Warning: The SSF at ["SUBJECT_SAMPLE_FACTORS"][1] has the following duplicate keys in its Additional sample data: "RAW_FILE_NAME(Raw Data Files)" "RAW_FILE_NAME(Raw Data Files)" Warning: The SSF at ["SUBJECT_SAMPLE_FACTORS"][2] has the following duplicate keys in its Additional sample data: "RAW_FILE_NAME(Raw Data Files)" "RAW_FILE_NAME(Raw Data Files)" Warning: The "mz" column at position 2 in the ["MS_METABOLITE_DATA"]["Metabolites"] table, matches a standard column name, "moverz_quant". If this match was not in error, the column should be renamed to the standard name or a name that doesn't resemble the standard name.