Validation Log 2025-12-15 03:12:25.489897 mwtab Python Library Version: 2.0.0 Source: https://www.metabolomicsworkbench.org/rest/study/analysis_id/AN006738/mwtab/txt Study ID: ST004072 Analysis ID: AN006738 File format: txt Status: Contains Validation Issues Number of Issues: 22 Number of Warnings: 13 Number of Value Errors: 22 Number of Consistency Errors: 0 Number of Format Errors: 0 Issue Log: Error: The value, "1 month", for the subsection, "AGE_OR_AGE_RANGE", in the "SUBJECT" section should be a number or range (ex. "5-6") followed by a space with a unit (ex. "5 V") from the following list: ['weeks', 'days', 'months', 'years']. Ignore this when more complicated descriptions are required. Error: An empty value or a null value was detected for the subsection, "Units", in the "MS_METABOLITE_DATA" section. A legitimate value should be provided for this required subsection. Error: An empty value or a null value was detected for the subsection, "INSTRUMENT_NAME", in the "CHROMATOGRAPHY" section. A legitimate value should be provided for this required subsection. Error: An empty value or a null value was detected for the subsection, "COLUMN_NAME", in the "CHROMATOGRAPHY" section. A legitimate value should be provided for this required subsection. Error: An empty value or a null value was detected for the subsection, "FLOW_GRADIENT", in the "CHROMATOGRAPHY" section. A legitimate value should be provided for this required subsection. Error: The value, "none", for the subsection, "FLOW_RATE", in the "CHROMATOGRAPHY" section should be a number or range (ex. "5-6") followed by a space with a unit (ex. "5 V") from the following list: ['mL/min', 'uL/min', 'μL/min']. Ignore this when more complicated descriptions are required. Error: The value, "none", for the subsection, "COLUMN_TEMPERATURE", in the "CHROMATOGRAPHY" section should be a number or range (ex. "5-6") followed by a space with a unit (ex. "5 V") from the following list: ['°C', 'C']. Ignore this when more complicated descriptions are required. Error: An empty value or a null value was detected for the subsection, "SOLVENT_A", in the "CHROMATOGRAPHY" section. A legitimate value should be provided for this required subsection. Error: An empty value or a null value was detected for the subsection, "SOLVENT_B", in the "CHROMATOGRAPHY" section. A legitimate value should be provided for this required subsection. Warning: SUBJECT_SAMPLE_FACTORS entry #1 has the following duplicate keys in its Factors: "Sample source" Warning: SUBJECT_SAMPLE_FACTORS entry #1 has the following duplicate keys in its Additional sample data: "RAW_FILE_NAME(Raw Data Files)" Warning: SUBJECT_SAMPLE_FACTORS entry #2 has the following duplicate keys in its Factors: "Sample source" Warning: SUBJECT_SAMPLE_FACTORS entry #2 has the following duplicate keys in its Additional sample data: "RAW_FILE_NAME(Raw Data Files)" Warning: SUBJECT_SAMPLE_FACTORS entry #3 has the following duplicate keys in its Factors: "Sample source" Warning: SUBJECT_SAMPLE_FACTORS entry #3 has the following duplicate keys in its Additional sample data: "RAW_FILE_NAME(Raw Data Files)" Warning: SUBJECT_SAMPLE_FACTORS entry #4 has the following duplicate keys in its Factors: "Sample source" Warning: SUBJECT_SAMPLE_FACTORS entry #4 has the following duplicate keys in its Additional sample data: "RAW_FILE_NAME(Raw Data Files)" Warning: SUBJECT_SAMPLE_FACTORS entry #5 has the following duplicate keys in its Factors: "Sample source" Warning: SUBJECT_SAMPLE_FACTORS entry #5 has the following duplicate keys in its Additional sample data: "RAW_FILE_NAME(Raw Data Files)" Warning: SUBJECT_SAMPLE_FACTORS entry #6 has the following duplicate keys in its Factors: "Sample source" Warning: SUBJECT_SAMPLE_FACTORS entry #6 has the following duplicate keys in its Additional sample data: "RAW_FILE_NAME(Raw Data Files)" Warning: The "m/z" column at position 2 in the METABOLITES table, matches a standard column name, "moverz_quant". If this match was not in error, the column should be renamed to the standard name or a name that doesn't resemble the standard name.