Validation Log 2026-02-01 08:55:29.723235 mwtab Python Library Version: 2.0.0 Source: https://www.metabolomicsworkbench.org/rest/study/analysis_id/AN006750/mwtab/txt Study ID: ST004078 Analysis ID: AN006750 File format: txt Status: Contains Validation Issues Number of Issues: 33 Number of Warnings: 32 Number of Value Errors: 30 Number of Consistency Errors: 0 Number of Format Errors: 0 Issue Log: Error: The value, "25", for the subsection, "COLUMN_TEMPERATURE", in the "CHROMATOGRAPHY" section should be a number or range (ex. "5-6") followed by a space with a unit (ex. "5 V") from the following list: ['°C', 'C']. Ignore this when more complicated descriptions are required. Warning: The "m/z" column at position 4 in the METABOLITES table, matches a standard column name, "moverz_quant". If this match was not in error, the column should be renamed to the standard name or a name that doesn't resemble the standard name. Warning: The "Mass Error (ppm)" column at position 2 in the METABOLITES table, matches a standard column name, "mass". If this match was not in error, the column should be renamed to the standard name or a name that doesn't resemble the standard name. Warning: The "Formula" column at position 3 in the METABOLITES table, matches a standard column name, "formula", and some of the values in the column do not match the expected type or format for that column. The non-matching values are: 6 C18 H31 N O4 19 C17 H18 F N3 O4 21 C29 H32 F N3 O4 S 22 C20 H17 Cl N4 O4 29 C27 H37 N5 O S 39 C10 H11 N O4 50 C19 H19 Cl N4 O S 67 C9 H13 Br N2 O2 68 C17 H29 N O4 75 C20 H12 N4 O S 78 C22 H43 N O3 89 C21 H25 N O7 95 C21 H25 Cl N2 O2 S 106 C22 H30 F N5 O 109 C4 H7 N O4 118 C25 H40 N O8 P 120 C24 H51 N O7 P 123 C26 H29 N O5 S 130 C41 H72 N O7 P 133 C24 H50 N O7 P 135 C22 H31 N O4 136 C19 H22 F N3 O4 137 C26 H52 N O7 P 146 C18 H18 Cl N3 S 148 C20 H29 Cl O6 150 C14 H18 N O9 S2 152 C23 H48 N O7 P 155 C25 H44 N O7 P 156 C12 H16 Cl N O S 158 C18 H15 Cl N2 O2 S 162 C15 H13 N O3 S2 167 C14 H17 N O7 168 C29 H41 N O7 172 C10 H17 N O4 S2 175 C25 H45 Fe N6 O8 176 C20 H25 F N8 O6 S2 182 C22 H19 N O4 186 C5 H9 N O5 S2 188 C14 H13 Cl2 N S 191 C4 H9 N O3 193 C14 H21 N O14 S 194 C26 H54 N O7 P 196 C22 H22 F N3 O2 S 205 C36 H45 N O13 206 C22 H19 Cl O8 207 C8 H15 N O12 S2 213 C24 H48 N O7 P 215 C21 H24 Cl N3 O3 216 C18 H15 Br F2 N4 O2 220 C35 H36 Cl N O4 S 228 C28 H50 N O7 P 232 C19 H16 Cl F N2 O 233 C26 H45 N O6 S 235 H3 O3 P Se 238 C5 H3 I2 N O 245 C26 H50 N O7 P 247 C22 H39 N O5 252 C24 H46 N O9 P 254 C6 H5 N O3 256 C9 H9 Br F N3 257 C43 H76 N O9 P 267 C22 H46 N O7 P 270 C21 H33 N O4 274 C27 H46 N O7 P 288 C18 H14 F3 N O2 S 298 C18 H14 Cl4 F3 N O3 303 C20 H17 F O2 S 306 C27 H48 N O7 P 308 C18 H18 Cl N2 O2 P 313 C24 H48 N O9 P 327 C17 H16 Cl F N2 O2 328 C25 H46 N O7 P 335 C6 H9 N O6 339 C16 H18 F N3 O3 341 C22 H37 N O5 345 C28 H52 N O7 P 346 C21 H42 N O7 P 356 C24 H29 Cl O4 357 C12 H21 N O8 S 359 C24 H33 Cl N4 O6 366 C14 H20 Cl N O3 S 368 C13 H21 O3 P S 372 C16 H12 F N3 O3 375 C24 H29 Cl O5 377 C25 H50 N O7 P 386 C27 H27 F2 N O6 392 C23 H28 Cl N5 O3 399 C16 H13 Cl N2 O 400 C30 H41 N O6 404 C26 H27 Cl N2 407 C11 H15 N O4 S 408 C27 H28 Cl F N2 O S 412 C24 H20 Cl2 N2 O S 418 C10 H13 N O4 S2 429 C18 H18 Cl N S 431 C10 H11 N O3 441 C15 H9 Cl O5 443 C22 H23 F4 N O2 446 C41 H80 N O8 P 451 C12 H7 N O4 454 C25 H29 F O2 Si 465 C15 H12 Cl N O2 472 C5 H7 N O3 477 C7 H13 N O3 479 C26 H43 N O6 487 C5 H11 N O2 490 C8 H16 N O9 P 491 C26 H43 N O5 497 C7 H13 N O3 S 499 C6 H13 N O2 503 C9 H7 N O Warning: The "MAIN_CLASS(lipidmaps)" column at position 10 in the METABOLITES table, matches a standard column name, "class". If this match was not in error, the column should be renamed to the standard name or a name that doesn't resemble the standard name. Warning: The "SUB_CLASS" column at position 11 in the METABOLITES table, matches a standard column name, "class". If this match was not in error, the column should be renamed to the standard name or a name that doesn't resemble the standard name. Warning: The "super_class(HMDB)" column at position 15 in the METABOLITES table, matches a standard column name, "class". If this match was not in error, the column should be renamed to the standard name or a name that doesn't resemble the standard name. Warning: The "sub_class(HMDB)" column at position 17 in the METABOLITES table, matches a standard column name, "class". If this match was not in error, the column should be renamed to the standard name or a name that doesn't resemble the standard name. Warning: The "KEGG_pathway_annotation" column at position 7 in the METABOLITES table, matches a standard column name, "pathway". If this match was not in error, the column should be renamed to the standard name or a name that doesn't resemble the standard name. Warning: The "KEGG_annotation" column at position 6 in the METABOLITES table, matches a standard column name, "kegg_id". If this match was not in error, the column should be renamed to the standard name or a name that doesn't resemble the standard name. Warning: The "KEGG_pathway_annotation" column at position 7 in the METABOLITES table, matches a standard column name, "kegg_id". If this match was not in error, the column should be renamed to the standard name or a name that doesn't resemble the standard name. Warning: The "KEGG_pathway_annotation" column at position 7 in the METABOLITES table, matches a standard column name, "kegg_id", and some of the values in the column do not match the expected type or format for that column. The non-matching values are: 1 Pyrimidine metabolism(ko00240);;Metabolic path... 2 Biosynthesis of unsaturated fatty acids(ko01040) 8 Biosynthesis of unsaturated fatty acids(ko01040) 12 Linoleic acid metabolism(ko00591);;Biosynthesi... 33 Glycolysis / Gluconeogenesis(ko00010);;Citrate... 34 Metabolic pathways(ko01100) 37 Biosynthesis of unsaturated fatty acids(ko01040) 43 Amino sugar and nucleotide sugar metabolism(ko... 59 Pyrimidine metabolism(ko00240);;Valine, leucin... 64 Metabolic pathways(ko01100) 69 Fatty acid biosynthesis(ko00061);;Metabolic pa... 74 Biosynthesis of unsaturated fatty acids(ko01040) 84 Fructose and mannose metabolism(ko00051);;Meta... 86 Cysteine and methionine metabolism(ko00270) 93 Cutin, suberine and wax biosynthesis(ko00073);... 109 Arginine biosynthesis(ko00220);;Alanine, aspar... 115 Bile secretion(ko04976) 117 Metabolic pathways(ko01100) 128 Fatty acid biosynthesis(ko00061);;Fatty acid e... 150 2-Oxocarboxylic acid metabolism(ko01210) 167 Metabolic pathways(ko01100) 170 Fatty acid biosynthesis(ko00061);;Biosynthesis... 202 Purine metabolism(ko00230);;Metabolic pathways... 204 Steroid hormone biosynthesis(ko00140) 211 Cutin, suberine and wax biosynthesis(ko00073);... 223 Biosynthesis of unsaturated fatty acids(ko01040) 229 Monobactam biosynthesis(ko00261);;Metabolic pa... 234 Neuroactive ligand-receptor interaction(ko0408... 235 Selenocompound metabolism(ko00450);;Metabolic ... 243 Biosynthesis of unsaturated fatty acids(ko01040) 273 Steroid hormone biosynthesis(ko00140);;Metabol... 297 Metabolic pathways(ko01100) 304 Arachidonic acid metabolism(ko00590);;Linoleic... 329 Pyrimidine metabolism(ko00240);;Metabolic path... 336 Alanine, aspartate and glutamate metabolism(ko... 339 ABC transporters(ko02010) 344 Neomycin, kanamycin and gentamicin biosynthesi... 347 Metabolic pathways(ko01100) 350 Arginine and proline metabolism(ko00330) 365 Purine metabolism(ko00230);;Metabolic pathways... 382 Glutathione metabolism(ko00480) 384 Metabolic pathways(ko01100) 390 Bile secretion(ko04976) 395 Insect hormone biosynthesis(ko00981);;Apoptosi... 403 Metabolic pathways(ko01100) 416 Amino sugar and nucleotide sugar metabolism(ko... 421 Purine metabolism(ko00230);;Metabolic pathways... 431 Phenylalanine metabolism(ko00360) 442 Biosynthesis of unsaturated fatty acids(ko0104... 474 Valine, leucine and isoleucine biosynthesis(ko... 475 alpha-Linolenic acid metabolism(ko00592);;Bios... 478 alpha-Linolenic acid metabolism(ko00592) 479 Primary bile acid biosynthesis(ko00120);;Metab... 482 Metabolic pathways(ko01100);;Chemical carcinog... 486 Fatty acid biosynthesis(ko00061);;Lipoic acid ... 487 Lysine degradation(ko00310);;Arginine and prol... 490 Amino sugar and nucleotide sugar metabolism(ko... 499 Metabolic pathways(ko01100) 501 Primary bile acid biosynthesis(ko00120);;Metab... Warning: The "kingdom(HMDB)" column at position 14 in the METABOLITES table, matches a standard column name, "hmdb_id". If this match was not in error, the column should be renamed to the standard name or a name that doesn't resemble the standard name. Warning: The "HMDB_taxonomy" column at position 16 in the METABOLITES table, matches a standard column name, "hmdb_id". If this match was not in error, the column should be renamed to the standard name or a name that doesn't resemble the standard name. Warning: The "kingdom(HMDB)" column at position 14 in the METABOLITES table, matches a standard column name, "hmdb_id", and some of the values in the column do not match the expected type or format for that column. The non-matching values are: 1 Organic compounds 2 Organic compounds 3 Organic compounds 4 Organic compounds 6 Organic compounds 7 Organic compounds 8 Organic compounds 12 Organic compounds 14 Organic compounds 15 Organic compounds 20 Organic compounds 24 Organic compounds 27 Organic compounds 33 Organic compounds 34 Organic compounds 37 Organic compounds 43 Organic compounds 46 Organic compounds 52 Organic compounds 59 Organic compounds 64 Organic compounds 69 Organic compounds 74 Organic compounds 80 Organic compounds 82 Organic compounds 84 Organic compounds 86 Organic compounds 87 Organic compounds 93 Organic compounds 97 Organic compounds 99 Organic compounds 104 Organic compounds 108 Organic compounds 109 Organic compounds 115 Organic compounds 117 Organic compounds 119 Organic compounds 121 Organic compounds 128 Organic compounds 129 Organic compounds 132 Organic compounds 134 Organic compounds 138 Organic compounds 143 Organic compounds 145 Organic compounds 146 Organic compounds 147 Organic compounds 150 Organic compounds 156 Organic compounds 158 Organic compounds 159 Organic compounds 160 Organic compounds 163 Organic compounds 165 Organic compounds 166 Organic compounds 167 Organic compounds 168 Organic compounds 169 Organic compounds 170 Organic compounds 176 Organic compounds 181 Organic compounds 182 Organic compounds 191 Organic compounds 192 Organic compounds 202 Organic compounds 204 Organic compounds 205 Organic compounds 206 Organic compounds 207 Organic compounds 209 Organic compounds 210 Organic compounds 211 Organic compounds 217 Organic compounds 219 Organic compounds 223 Organic compounds 227 Organic compounds 230 Organic compounds 233 Organic compounds 234 Organic compounds 235 Inorganic compounds 237 Organic compounds 242 Organic compounds 243 Organic compounds 246 Organic compounds 247 Organic compounds 253 Organic compounds 254 Organic compounds 262 Organic compounds 263 Organic compounds 266 Organic compounds 272 Organic compounds 273 Organic compounds 279 Organic compounds 280 Organic compounds 281 Organic compounds 282 Organic compounds 286 Organic compounds 289 Organic compounds 290 Organic compounds 294 Organic compounds 296 Organic compounds 303 Organic compounds 304 Organic compounds 307 Organic compounds 312 Organic compounds 315 Organic compounds 320 Organic compounds 321 Organic compounds 322 Organic compounds 323 Organic compounds 329 Organic compounds 332 Organic compounds 335 Organic compounds 336 Organic compounds 339 Organic compounds 341 Organic compounds 342 Organic compounds 347 Organic compounds 350 Organic compounds 352 Organic compounds 353 Organic compounds 354 Organic compounds 355 Organic compounds 356 Organic compounds 359 Organic compounds 362 Organic compounds 365 Organic compounds 368 Organic compounds 369 Organic compounds 371 Organic compounds 372 Organic compounds 376 Organic compounds 379 Organic compounds 380 Organic compounds 387 Organic compounds 390 Organic compounds 392 Organic compounds 394 Organic compounds 395 Organic compounds 396 Organic compounds 399 Organic compounds 402 Organic compounds 403 Organic compounds 404 Organic compounds 409 Organic compounds 410 Organic compounds 413 Organic compounds 416 Organic compounds 418 Organic compounds 421 Organic compounds 423 Organic compounds 424 Organic compounds 426 Organic compounds 427 Organic compounds 429 Organic compounds 430 Organic compounds 431 Organic compounds 432 Organic compounds 435 Organic compounds 436 Organic compounds 439 Organic compounds 442 Organic compounds 443 Organic compounds 444 Organic compounds 445 Organic compounds 450 Organic compounds 451 Organic compounds 452 Organic compounds 453 Organic compounds 456 Organic compounds 463 Organic compounds 465 Organic compounds 468 Organic compounds 470 Organic compounds 471 Organic compounds 472 Organic compounds 474 Organic compounds 475 Organic compounds 476 Organic compounds 477 Organic compounds 479 Organic compounds 481 Organic compounds 482 Organic compounds 483 Organic compounds 486 Organic compounds 487 Organic compounds 489 Organic compounds 490 Organic compounds 491 Organic compounds 492 Organic compounds 494 Organic compounds 497 Organic compounds 499 Organic compounds 501 Organic compounds 504 Organic compounds 505 Organic compounds 506 Organic compounds 507 Organic compounds Warning: The "HMDB_taxonomy" column at position 16 in the METABOLITES table, matches a standard column name, "hmdb_id", and some of the values in the column do not match the expected type or format for that column. The non-matching values are: 1 Pyrimidine nucleosides 2 Fatty Acyls 3 Fatty Acyls 4 Organooxygen compounds 6 Fatty Acyls 7 Fatty Acyls 8 Fatty Acyls 12 Fatty Acyls 14 Prenol lipids 15 Benzene and substituted derivatives 20 Keto acids and derivatives 24 Organooxygen compounds 27 Hydroxy acids and derivatives 33 Keto acids and derivatives 34 Benzene and substituted derivatives 37 Fatty Acyls 43 Pyrimidine nucleotides 46 Benzene and substituted derivatives 52 Fatty Acyls 59 Carboxylic acids and derivatives 64 Fatty Acyls 69 Fatty Acyls 74 Fatty Acyls 80 Benzene and substituted derivatives 82 Fatty Acyls 84 Organooxygen compounds 86 Carboxylic acids and derivatives 87 Fatty Acyls 93 Fatty Acyls 97 Benzene and substituted derivatives 99 Carboxylic acids and derivatives 104 Imidazopyrimidines 108 Glycerophospholipids 109 Carboxylic acids and derivatives 115 Carboxylic acids and derivatives 117 Flavonoids 119 Carboxylic acids and derivatives 121 Tetracyclines 128 Fatty Acyls 129 Glycerophospholipids 132 Benzene and substituted derivatives 134 Carboxylic acids and derivatives 138 Pyrrolidines 143 Organic phosphonic acids and derivatives 145 Carboxylic acids and derivatives 146 Benzothiazepines 147 Steroids and steroid derivatives 150 Organooxygen compounds 156 Benzene and substituted derivatives 158 Pyridines and derivatives 159 Benzodiazepines 160 Benzene and substituted derivatives 163 Organooxygen compounds 165 Flavonoids 166 Benzene and substituted derivatives 167 Organooxygen compounds 168 Indanes 169 Carboxylic acids and derivatives 170 Fatty Acyls 176 Lactams 181 Organooxygen compounds 182 Benzene and substituted derivatives 191 Carboxylic acids and derivatives 192 Flavonoids 202 Purine nucleotides 204 Steroids and steroid derivatives 205 Anthracyclines 206 Depsides and depsidones 207 Organooxygen compounds 209 Pteridines and derivatives 210 Phenols 211 Fatty Acyls 217 Flavonoids 219 Isoindoles and derivatives 223 Fatty Acyls 227 Azoles 230 Fatty Acyls 233 Steroids and steroid derivatives 234 Endocannabinoids 235 Other mixed metal/non-metal oxoanionic compounds 237 Benzene and substituted derivatives 242 Fatty Acyls 243 Fatty Acyls 246 Thioethers 247 Fatty Acyls 253 Carboxylic acids and derivatives 254 Phenols 262 Tannins 263 Benzene and substituted derivatives 266 Phenols 272 Phenols 273 Steroids and steroid derivatives 279 Diazinanes 280 Flavonoids 281 Imidazopyrimidines 282 Carboxylic acids and derivatives 286 Fatty Acyls 289 Flavonoids 290 Steroids and steroid derivatives 294 Benzene and substituted derivatives 296 Benzene and substituted derivatives 303 Indenes and isoindenes 304 Fatty Acyls 307 Fatty Acyls 312 Tetracyclines 315 Fatty Acyls 320 Fatty Acyls 321 Indolonaphthyridine alkaloids 322 Organooxygen compounds 323 Emetine alkaloids 329 Pyrimidine nucleosides 332 Steroids and steroid derivatives 335 Carboxylic acids and derivatives 336 Fatty Acyls 339 Carboxylic acids and derivatives 341 Fatty Acyls 342 Benzene and substituted derivatives 347 Organooxygen compounds 350 Carboxylic acids and derivatives 352 Phenols 353 Benzene and substituted derivatives 354 Flavonoids 355 Fatty Acyls 356 Steroids and steroid derivatives 359 Carboxylic acids and derivatives 362 Prenol lipids 365 Organooxygen compounds 368 Benzene and substituted derivatives 369 Benzene and substituted derivatives 371 Imidazopyrimidines 372 Benzodiazepines 376 Benzene and substituted derivatives 379 Yohimbine alkaloids 380 Benzene and substituted derivatives 387 Benzodiazepines 390 Carboxylic acids and derivatives 392 Azolidines 394 Flavonoids 395 Steroids and steroid derivatives 396 Linear 1,3-diarylpropanoids 399 Benzodiazepines 402 Carboxylic acids and derivatives 403 Coumarins and derivatives 404 Benzene and substituted derivatives 409 Carboxylic acids and derivatives 410 Lactones 413 Benzodioxanes 416 Organooxygen compounds 418 Thiochromanes 421 Imidazopyrimidines 423 Benzene and substituted derivatives 424 Benzazepines 426 Neoflavonoids 427 Organooxygen compounds 429 Benzothiopyrans 430 Pyrimidine nucleosides 431 Carboxylic acids and derivatives 432 Prenol lipids 435 Cinnamic acids and derivatives 436 Benzodioxoles 439 Steroids and steroid derivatives 442 Fatty Acyls 443 Organooxygen compounds 444 Fatty Acyls 445 Prenol lipids 450 Naphthopyrans 451 Benzoxazines 452 Peptidomimetics 453 Hydroxy acids and derivatives 456 Benzene and substituted derivatives 463 Benzimidazoles 465 Indoles and derivatives 468 Glycerophospholipids 470 Hydroxy acids and derivatives 471 Phenylpropanoic acids 472 Carboxylic acids and derivatives 474 Fatty Acyls 475 Fatty Acyls 476 Fatty Acyls 477 Carboxylic acids and derivatives 479 Steroids and steroid derivatives 481 Benzene and substituted derivatives 482 Benzene and substituted derivatives 483 Benzene and substituted derivatives 486 Fatty Acyls 487 Carboxylic acids and derivatives 489 Hydroxy acids and derivatives 490 Organooxygen compounds 491 Steroids and steroid derivatives 492 Fatty Acyls 494 Fatty Acyls 497 Carboxylic acids and derivatives 499 Fatty Acyls 501 Steroids and steroid derivatives 504 Indoles and derivatives 505 Prenol lipids 506 Organooxygen compounds 507 Fatty Acyls Warning: The "LM_ID(lipidmaps)" column at position 8 in the METABOLITES table, matches a standard column name, "lm_id". If this match was not in error, the column should be renamed to the standard name or a name that doesn't resemble the standard name. Warning: The "CATEGORY(lipidmaps)" column at position 9 in the METABOLITES table, matches a standard column name, "lm_id". If this match was not in error, the column should be renamed to the standard name or a name that doesn't resemble the standard name. Warning: The "MAIN_CLASS(lipidmaps)" column at position 10 in the METABOLITES table, matches a standard column name, "lm_id". If this match was not in error, the column should be renamed to the standard name or a name that doesn't resemble the standard name. Warning: The "CATEGORY(lipidmaps)" column at position 9 in the METABOLITES table, matches a standard column name, "lm_id", and some of the values in the column do not match the expected type or format for that column. The non-matching values are: 2 Fatty Acyls [FA] 3 Fatty Acyls [FA] 7 Fatty Acyls [FA] 8 Fatty Acyls [FA] 12 Fatty Acyls [FA] 20 Fatty Acyls [FA] 33 Fatty Acyls [FA] 52 Fatty Acyls [FA] 59 Fatty Acyls [FA] 64 Fatty Acyls [FA] 69 Fatty Acyls [FA] 74 Fatty Acyls [FA] 82 Fatty Acyls [FA] 87 Fatty Acyls [FA] 93 Fatty Acyls [FA] 108 Glycerophospholipids [GP] 117 Polyketides [PK] 121 Polyketides [PK] 128 Fatty Acyls [FA] 165 Polyketides [PK] 170 Fatty Acyls [FA] 171 Prenol Lipids [PR] 192 Polyketides [PK] 217 Polyketides [PK] 230 Fatty Acyls [FA] 233 Sterol Lipids [ST] 234 Glycerolipids [GL] 243 Fatty Acyls [FA] 253 Fatty Acyls [FA] 273 Sterol Lipids [ST] 280 Polyketides [PK] 290 Sterol Lipids [ST] 304 Fatty Acyls [FA] 354 Polyketides [PK] 395 Sterol Lipids [ST] 396 Polyketides [PK] 411 Polyketides [PK] 441 Polyketides [PK] 442 Fatty Acyls [FA] 444 Fatty Acyls [FA] 474 Fatty Acyls [FA] 475 Fatty Acyls [FA] 476 Fatty Acyls [FA] 479 Sterol Lipids [ST] 486 Fatty Acyls [FA] 491 Sterol Lipids [ST] 501 Sterol Lipids [ST] 507 Fatty Acyls [FA] Warning: The "MAIN_CLASS(lipidmaps)" column at position 10 in the METABOLITES table, matches a standard column name, "lm_id", and some of the values in the column do not match the expected type or format for that column. The non-matching values are: 2 Fatty Acids and Conjugates [FA01] 3 Fatty Acids and Conjugates [FA01] 7 Fatty Acids and Conjugates [FA01] 8 Fatty Acids and Conjugates [FA01] 12 Fatty Acids and Conjugates [FA01] 20 Fatty Acids and Conjugates [FA01] 33 Fatty Acids and Conjugates [FA01] 52 Eicosanoids [FA03] 59 Fatty Acids and Conjugates [FA01] 64 Fatty Acids and Conjugates [FA01] 69 Fatty Acids and Conjugates [FA01] 74 Fatty Acids and Conjugates [FA01] 82 Fatty Acids and Conjugates [FA01] 87 Fatty Acids and Conjugates [FA01] 93 Fatty Acids and Conjugates [FA01] 108 Glycerophosphates [GP10] 117 Flavonoids [PK12] 121 Linear tetracyclines [PK07] 128 Fatty Acids and Conjugates [FA01] 165 Flavonoids [PK12] 170 Fatty Acids and Conjugates [FA01] 171 Isoprenoids [PR01] 192 Flavonoids [PK12] 217 Flavonoids [PK12] 230 Fatty esters [FA07] 233 Steroid conjugates [ST05] 234 Monoradylglycerols [GL01] 243 Docosanoids [FA04] 253 Fatty esters [FA07] 273 Steroid conjugates [ST05] 280 Flavonoids [PK12] 290 Sterols [ST01] 304 Fatty Acids and Conjugates [FA01] 354 Flavonoids [PK12] 395 Sterols [ST01] 396 Flavonoids [PK12] 411 Flavonoids [PK12] 441 Aromatic polyketides [PK13] 442 Fatty Acids and Conjugates [FA01] 444 Docosanoids [FA04] 474 Fatty Acids and Conjugates [FA01] 475 Fatty Acids and Conjugates [FA01] 476 Fatty Acids and Conjugates [FA01] 479 Steroid conjugates [ST05] 486 Fatty Acids and Conjugates [FA01] 491 Steroid conjugates [ST05] 501 Bile acids and derivatives [ST04] 507 Fatty Acids and Conjugates [FA01] Warning: The "CAS" column at position 13 in the METABOLITES table, matches a standard column name, "cas_number". If this match was not in error, the column should be renamed to the standard name or a name that doesn't resemble the standard name. Warning: The "CAS" column at position 13 in the METABOLITES table, matches a standard column name, "cas_number", and some of the values in the column do not match the expected type or format for that column. The non-matching values are: 128 1957/10/3 129 1957/3/4 170 1957/11/4 281 6493/5/6 390 1959/5/2 482 1980/5/7 504 4350/9/8 Warning: The "Retention time (min)" column at position 5 in the METABOLITES table, matches a standard column name, "retention_time". If this match was not in error, the column should be renamed to the standard name or a name that doesn't resemble the standard name. Warning: The "KEGG_annotation" column at position 6 in the METABOLITES table, matches a standard column name, "annotations". If this match was not in error, the column should be renamed to the standard name or a name that doesn't resemble the standard name. Warning: The "KEGG_pathway_annotation" column at position 7 in the METABOLITES table, matches a standard column name, "annotations". If this match was not in error, the column should be renamed to the standard name or a name that doesn't resemble the standard name. Warning: The column, "MAIN_CLASS(lipidmaps)", in the METABOLITES table was matched to multiple standard names, ['class', 'lm_id']. This is a good indication that the values in that column should be split into the appropriate individual columns. Warning: The column, "KEGG_pathway_annotation", in the METABOLITES table was matched to multiple standard names, ['pathway', 'kegg_id', 'annotations']. This is a good indication that the values in that column should be split into the appropriate individual columns. Warning: The column, "KEGG_annotation", in the METABOLITES table was matched to multiple standard names, ['kegg_id', 'annotations']. This is a good indication that the values in that column should be split into the appropriate individual columns. Warning: The "LM_ID(lipidmaps)" column at position 8 in the METABOLITES table may have incorrect values. 90% or more of the values are the same, but 10% or less are different. Warning: The "CATEGORY(lipidmaps)" column at position 9 in the METABOLITES table may have incorrect values. 90% or more of the values are the same, but 10% or less are different. Warning: The "MAIN_CLASS(lipidmaps)" column at position 10 in the METABOLITES table may have incorrect values. 90% or more of the values are the same, but 10% or less are different. Warning: The "SUB_CLASS" column at position 11 in the METABOLITES table may have incorrect values. 90% or more of the values are the same, but 10% or less are different.