Validation Log 2025-12-15 03:15:47.382036 mwtab Python Library Version: 2.0.0 Source: https://www.metabolomicsworkbench.org/rest/study/analysis_id/AN006830/mwtab/txt Study ID: ST004119 Analysis ID: AN006830 File format: txt Status: Contains Validation Issues Number of Issues: 49 Number of Warnings: 47 Number of Value Errors: 46 Number of Consistency Errors: 0 Number of Format Errors: 0 Issue Log: Error: The value, "5 microLiters/min", for the subsection, "FLOW_RATE", in the "CHROMATOGRAPHY" section should be a number or range (ex. "5-6") followed by a space with a unit (ex. "5 V") from the following list: ['mL/min', 'uL/min', 'μL/min']. Ignore this when more complicated descriptions are required. Error: The value, "30℃", for the subsection, "COLUMN_TEMPERATURE", in the "CHROMATOGRAPHY" section should be a number or range (ex. "5-6") followed by a space with a unit (ex. "5 V") from the following list: ['°C', 'C']. Ignore this when more complicated descriptions are required. Warning: SUBJECT_SAMPLE_FACTORS entry #1 has the following duplicate keys in its Factors: "Sample source" Warning: SUBJECT_SAMPLE_FACTORS entry #2 has the following duplicate keys in its Factors: "Sample source" Warning: SUBJECT_SAMPLE_FACTORS entry #3 has the following duplicate keys in its Factors: "Sample source" Warning: SUBJECT_SAMPLE_FACTORS entry #4 has the following duplicate keys in its Factors: "Sample source" Warning: SUBJECT_SAMPLE_FACTORS entry #5 has the following duplicate keys in its Factors: "Sample source" Warning: SUBJECT_SAMPLE_FACTORS entry #6 has the following duplicate keys in its Factors: "Sample source" Warning: SUBJECT_SAMPLE_FACTORS entry #7 has the following duplicate keys in its Factors: "Sample source" Warning: SUBJECT_SAMPLE_FACTORS entry #8 has the following duplicate keys in its Factors: "Sample source" Warning: SUBJECT_SAMPLE_FACTORS entry #9 has the following duplicate keys in its Factors: "Sample source" Warning: SUBJECT_SAMPLE_FACTORS entry #10 has the following duplicate keys in its Factors: "Sample source" Warning: SUBJECT_SAMPLE_FACTORS entry #11 has the following duplicate keys in its Factors: "Sample source" Warning: SUBJECT_SAMPLE_FACTORS entry #12 has the following duplicate keys in its Factors: "Sample source" Warning: SUBJECT_SAMPLE_FACTORS entry #13 has the following duplicate keys in its Factors: "Sample source" Warning: SUBJECT_SAMPLE_FACTORS entry #14 has the following duplicate keys in its Factors: "Sample source" Warning: SUBJECT_SAMPLE_FACTORS entry #15 has the following duplicate keys in its Factors: "Sample source" Warning: SUBJECT_SAMPLE_FACTORS entry #16 has the following duplicate keys in its Factors: "Sample source" Warning: SUBJECT_SAMPLE_FACTORS entry #17 has the following duplicate keys in its Factors: "Sample source" Warning: SUBJECT_SAMPLE_FACTORS entry #18 has the following duplicate keys in its Factors: "Sample source" Warning: SUBJECT_SAMPLE_FACTORS entry #19 has the following duplicate keys in its Factors: "Sample source" Warning: SUBJECT_SAMPLE_FACTORS entry #20 has the following duplicate keys in its Factors: "Sample source" Warning: SUBJECT_SAMPLE_FACTORS entry #21 has the following duplicate keys in its Factors: "Sample source" Warning: SUBJECT_SAMPLE_FACTORS entry #22 has the following duplicate keys in its Factors: "Sample source" Warning: SUBJECT_SAMPLE_FACTORS entry #23 has the following duplicate keys in its Factors: "Sample source" Warning: SUBJECT_SAMPLE_FACTORS entry #24 has the following duplicate keys in its Factors: "Sample source" Warning: SUBJECT_SAMPLE_FACTORS entry #25 has the following duplicate keys in its Factors: "Sample source" Warning: SUBJECT_SAMPLE_FACTORS entry #26 has the following duplicate keys in its Factors: "Sample source" Warning: SUBJECT_SAMPLE_FACTORS entry #27 has the following duplicate keys in its Factors: "Sample source" Warning: SUBJECT_SAMPLE_FACTORS entry #28 has the following duplicate keys in its Factors: "Sample source" Warning: SUBJECT_SAMPLE_FACTORS entry #29 has the following duplicate keys in its Factors: "Sample source" Warning: SUBJECT_SAMPLE_FACTORS entry #30 has the following duplicate keys in its Factors: "Sample source" Warning: SUBJECT_SAMPLE_FACTORS entry #31 has the following duplicate keys in its Factors: "Sample source" Warning: SUBJECT_SAMPLE_FACTORS entry #32 has the following duplicate keys in its Factors: "Sample source" Warning: SUBJECT_SAMPLE_FACTORS entry #33 has the following duplicate keys in its Factors: "Sample source" Warning: SUBJECT_SAMPLE_FACTORS entry #34 has the following duplicate keys in its Factors: "Sample source" Warning: SUBJECT_SAMPLE_FACTORS entry #35 has the following duplicate keys in its Factors: "Sample source" Warning: SUBJECT_SAMPLE_FACTORS entry #36 has the following duplicate keys in its Factors: "Sample source" Warning: SUBJECT_SAMPLE_FACTORS entry #37 has the following duplicate keys in its Factors: "Sample source" Warning: SUBJECT_SAMPLE_FACTORS entry #38 has the following duplicate keys in its Factors: "Sample source" Warning: The "quantified m/z " column at position 3 in the METABOLITES table, matches a standard column name, "moverz_quant". If this match was not in error, the column should be renamed to the standard name or a name that doesn't resemble the standard name. Warning: The "PubChem ID" column at position 4 in the METABOLITES table, matches a standard column name, "pubchem_id". If this match was not in error, the column should be renamed to the standard name or a name that doesn't resemble the standard name. Warning: The "KEGG" column at position 5 in the METABOLITES table, matches a standard column name, "kegg_id". If this match was not in error, the column should be renamed to the standard name or a name that doesn't resemble the standard name. Warning: The "KEGG" column at position 5 in the METABOLITES table, matches a standard column name, "kegg_id", and some of the values in the column do not match the expected type or format for that column. The non-matching values are: 1 — Warning: The "Others" column at position 6 in the METABOLITES table, matches a standard column name, "other_id". If this match was not in error, the column should be renamed to the standard name or a name that doesn't resemble the standard name. Warning: The "retention index " column at position 2 in the METABOLITES table, matches a standard column name, "retention_index". If this match was not in error, the column should be renamed to the standard name or a name that doesn't resemble the standard name. Warning: The column "Others" was found in the METABOLITES table, but this column implies that another column, "other_id_type", should also exist, and that column was not found. Warning: The column "retention index " was found in the METABOLITES table, but this column implies that another column, "retention_index_type", should also exist, and that column was not found. Warning: The standard column, "other_id", was found in the METABOLITES table as "Others". If this column contains database IDs for standard databases such as KEGG, PubChem, HMDB, etc., it is recommended to make individual columns for these and not lump them together into a less descriptive "other_id" column.