Validation Log 2025-12-15 03:16:06.059607 mwtab Python Library Version: 2.0.0 Source: https://www.metabolomicsworkbench.org/rest/study/analysis_id/AN006836/mwtab/txt Study ID: ST004123 Analysis ID: AN006836 File format: txt Status: Contains Validation Issues Number of Issues: 13 Number of Warnings: 4 Number of Value Errors: 11 Number of Consistency Errors: 0 Number of Format Errors: 1 Issue Log: Error: An empty value or a null value was detected for the subsection, "GENOTYPE_STRAIN", in the "SUBJECT" section. Either a legitimate value should be provided for this subsection, or it should be removed altogether. Error: The value, "25 ± 2 °C", for the subsection, "PLANT_TEMP", in the "TREATMENT" section should be a number or range (ex. "5-6") followed by a space with a unit (ex. "5 V") from the following list: ['°C', 'C']. Ignore this when more complicated descriptions are required. Error: An empty value or a null value was detected for the subsection, "FLOW_GRADIENT", in the "CHROMATOGRAPHY" section. A legitimate value should be provided for this required subsection. Error: The value, "1.2 mL/min (Helium)", for the subsection, "FLOW_RATE", in the "CHROMATOGRAPHY" section should be a number or range (ex. "5-6") followed by a space with a unit (ex. "5 V") from the following list: ['mL/min', 'uL/min', 'μL/min']. Ignore this when more complicated descriptions are required. Error: The value for the subsection, "COLUMN_TEMPERATURE", in the "CHROMATOGRAPHY" section should be a number or range (ex. "5-6") followed by a space with a unit (ex. "5 V") from the following list: ['°C', 'C']. Ignore this when more complicated descriptions are required. Error: An empty value or a null value was detected for the subsection, "SOLVENT_A", in the "CHROMATOGRAPHY" section. A legitimate value should be provided for this required subsection. Error: An empty value or a null value was detected for the subsection, "SOLVENT_B", in the "CHROMATOGRAPHY" section. A legitimate value should be provided for this required subsection. Error: The value, "250°C (splitless mode)", for the subsection, "INJECTION_TEMPERATURE", in the "CHROMATOGRAPHY" section should be a number or range (ex. "5-6") followed by a space with a unit (ex. "5 V") from the following list: ['°C', 'C'] or "room temperature". Ignore this when more complicated descriptions are required. Error: Unknown or invalid subsection, "SOLVENT_C", in the "CHROMATOGRAPHY" section . Warning: The "quant_mz" column at position 2 in the METABOLITES table, matches a standard column name, "moverz_quant". If this match was not in error, the column should be renamed to the standard name or a name that doesn't resemble the standard name. Warning: The "Molecular weight (Da)" column at position 6 in the METABOLITES table, matches a standard column name, "mass". If this match was not in error, the column should be renamed to the standard name or a name that doesn't resemble the standard name. Warning: The "CAS_ID" column at position 4 in the METABOLITES table, matches a standard column name, "cas_number". If this match was not in error, the column should be renamed to the standard name or a name that doesn't resemble the standard name. Warning: The column "retention_index" was found in the METABOLITES table, but this column implies that another column, "retention_index_type", should also exist, and that column was not found.