Validation Log 2025-12-15 03:18:31.475179 mwtab Python Library Version: 2.0.0 Source: https://www.metabolomicsworkbench.org/rest/study/analysis_id/AN006894/mwtab/txt Study ID: ST004153 Analysis ID: AN006894 File format: txt Status: Contains Validation Issues Number of Issues: 13 Number of Warnings: 12 Number of Value Errors: 11 Number of Consistency Errors: 0 Number of Format Errors: 0 Issue Log: Error: The value, "40", for the subsection, "COLUMN_TEMPERATURE", in the "CHROMATOGRAPHY" section should be a number or range (ex. "5-6") followed by a space with a unit (ex. "5 V") from the following list: ['°C', 'C']. Ignore this when more complicated descriptions are required. Warning: The "m/z" column at position 2 in the METABOLITES table, matches a standard column name, "moverz_quant". If this match was not in error, the column should be renamed to the standard name or a name that doesn't resemble the standard name. Warning: The "Mass Error (ppm)" column at position 14 in the METABOLITES table, matches a standard column name, "mass". If this match was not in error, the column should be renamed to the standard name or a name that doesn't resemble the standard name. Warning: The "Formula" column at position 13 in the METABOLITES table, matches a standard column name, "formula", and some of the values in the column do not match the expected type or format for that column. The non-matching values are: 1484 C14H32N4O2+2 2097 C23H46O7-2 4715 C9H12O6S-2 5194 C12H31N4O+3 5540 C38H48N2+2 5646 C35H30N4O5-2 Warning: The "Super Class" column at position 5 in the METABOLITES table, matches a standard column name, "class". If this match was not in error, the column should be renamed to the standard name or a name that doesn't resemble the standard name. Warning: The "Sub Class" column at position 7 in the METABOLITES table, matches a standard column name, "class". If this match was not in error, the column should be renamed to the standard name or a name that doesn't resemble the standard name. Warning: The "Adducts" column at position 12 in the METABOLITES table, matches a standard column name, "adduct". If this match was not in error, the column should be renamed to the standard name or a name that doesn't resemble the standard name. Warning: The "kegg" column at position 9 in the METABOLITES table, matches a standard column name, "kegg_id". If this match was not in error, the column should be renamed to the standard name or a name that doesn't resemble the standard name. Warning: The "kegg" column at position 9 in the METABOLITES table, matches a standard column name, "kegg_id", and some of the values in the column do not match the expected type or format for that column. The non-matching values are: 1 Unclassified 2 Unclassified 4 Unclassified 5 Unclassified 9 Unclassified 12 Unclassified 13 Unclassified 17 Unclassified 18 Unclassified 21 Unclassified 23 Unclassified 24 Unclassified 25 Unclassified 26 Unclassified 27 Unclassified 28 Unclassified 29 Unclassified 30 Unclassified 32 Unclassified 33 Unclassified 34 Unclassified 35 Unclassified 36 Unclassified 38 Unclassified 39 Unclassified 40 Unclassified 45 Unclassified 46 Unclassified 47 Unclassified 48 Unclassified 50 Unclassified 51 Unclassified 52 Unclassified 54 Unclassified 56 Unclassified 58 Unclassified 59 Unclassified 60 Unclassified 62 Unclassified 63 Unclassified 64 Unclassified 65 Unclassified 69 Unclassified 70 Unclassified 71 Unclassified 72 Unclassified 73 Unclassified 75 Unclassified 77 Unclassified 80 Unclassified 81 Unclassified 82 Unclassified 84 Unclassified 85 Unclassified 86 Unclassified 87 Unclassified 89 Unclassified 90 Unclassified 91 Unclassified 94 Unclassified 95 Unclassified 96 Unclassified 97 Unclassified 98 Unclassified 99 Unclassified 100 Unclassified 101 Unclassified 102 Unclassified 103 Unclassified 104 Unclassified 105 Unclassified 106 Unclassified 107 Unclassified 108 Unclassified 109 Unclassified 110 Unclassified 111 Unclassified 114 Unclassified 116 Unclassified 118 Unclassified 119 Unclassified 120 Unclassified 123 Unclassified 124 Unclassified 125 Unclassified 126 Unclassified 128 Unclassified 130 Unclassified 131 Unclassified 137 Unclassified 138 Unclassified 139 Unclassified 140 Unclassified 141 Unclassified 142 Unclassified 143 Unclassified 144 Unclassified 145 Unclassified 147 Unclassified 148 Unclassified 149 Unclassified 150 Unclassified 151 Unclassified 152 Unclassified 153 Unclassified 155 Unclassified 156 Unclassified 159 Unclassified 160 Unclassified 161 Unclassified 162 Unclassified 163 Unclassified 164 Unclassified 165 Unclassified 166 Unclassified 167 Unclassified 168 Unclassified 170 Unclassified 173 Unclassified 174 Unclassified 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If this match was not in error, the column should be renamed to the standard name or a name that doesn't resemble the standard name. Warning: The "Retention time (min)" column at position 3 in the METABOLITES table, matches a standard column name, "retention_time". If this match was not in error, the column should be renamed to the standard name or a name that doesn't resemble the standard name. Warning: The column "Compound ID" was found in the METABOLITES table, but this column implies that another column, "other_id_type", should also exist, and that column was not found. Warning: The standard column, "other_id", was found in the METABOLITES table as "Compound ID". If this column contains database IDs for standard databases such as KEGG, PubChem, HMDB, etc., it is recommended to make individual columns for these and not lump them together into a less descriptive "other_id" column.