Validation Log 2025-12-15 03:20:08.717494 mwtab Python Library Version: 2.0.0 Source: https://www.metabolomicsworkbench.org/rest/study/analysis_id/AN006913/mwtab/json Study ID: ST004164 Analysis ID: AN006913 File format: json Status: Contains Validation Issues Number of Issues: 8 Number of Warnings: 5 Number of Value Errors: 7 Number of Consistency Errors: 1 Number of Format Errors: 0 Issue Log: Error: The value, "40℃", in ["CHROMATOGRAPHY"]["COLUMN_TEMPERATURE"] should be a number or range (ex. "5-6") followed by a space with a unit (ex. "5 V") from the following list: ['°C', 'C']. Ignore this when more complicated descriptions are required. Error: SUBJECT_SAMPLE_FACTORS section missing sample ID(s). The following IDs were found in the ["MS_METABOLITE_DATA"]["Data"] section but not in the SUBJECT_SAMPLE_FACTORS: "" Warning: The "Formula" column at position 2 in the ["MS_METABOLITE_DATA"]["Metabolites"] table, matches a standard column name, "formula", and some of the values in the column do not match the expected type or format for that column. The non-matching values are: 1 C9 H10 Cl N O2 7 C3 H7 N O2 11 C4 H7 N O4 14 C3 H7 N O2 S 27 C5 H9 N O4 28 C2 H5 N O2 30 C6 H13 N O2 35 C6 H13 N O2 39 C5 H11 N O2 S 42 C9 H11 N O2 43 C5 H9 N O2 48 C3 H7 N O3 50 C4 H9 N O3 54 C9 H11 N O3 60 C5 H11 N O2 Warning: The "CAS ID" column at position 5 in the ["MS_METABOLITE_DATA"]["Metabolites"] table, matches a standard column name, "cas_number". If this match was not in error, the column should be renamed to the standard name or a name that doesn't resemble the standard name. Warning: The "CAS ID" column at position 5 in the ["MS_METABOLITE_DATA"]["Metabolites"] table, matches a standard column name, "cas_number", and some of the values in the column do not match the expected type or format for that column. The non-matching values are: 20 643-13-0 / 59-56-3 Warning: The "RT" column at position 4 in the ["MS_METABOLITE_DATA"]["Metabolites"] table, matches a standard column name, "retention_time". If this match was not in error, the column should be renamed to the standard name or a name that doesn't resemble the standard name. Error: Column(s) with no name were found in the ["MS_METABOLITE_DATA"]["Data"] table. Warning: The "" column at position 42 in the ["MS_METABOLITE_DATA"]["Data"] table has all null values.