Validation Log 2025-12-15 03:20:23.564858 mwtab Python Library Version: 2.0.0 Source: https://www.metabolomicsworkbench.org/rest/study/analysis_id/AN006918/mwtab/txt Study ID: ST004167 Analysis ID: AN006918 File format: txt Status: Contains Validation Issues Number of Issues: 6 Number of Warnings: 5 Number of Value Errors: 6 Number of Consistency Errors: 0 Number of Format Errors: 0 Issue Log: Error: The value, "45", for the subsection, "COLUMN_TEMPERATURE", in the "CHROMATOGRAPHY" section should be a number or range (ex. "5-6") followed by a space with a unit (ex. "5 V") from the following list: ['°C', 'C']. Ignore this when more complicated descriptions are required. Warning: The "IonFormula" column at position 8 in the METABOLITES table, matches a standard column name, "formula". If this match was not in error, the column should be renamed to the standard name or a name that doesn't resemble the standard name. Warning: The "IonFormula" column at position 8 in the METABOLITES table, matches a standard column name, "formula", and some of the values in the column do not match the expected type or format for that column. The non-matching values are: 74 C42 H78 O10 N0 P1 75 C46 H76 O10 N0 P1 77 C43 H80 O13 N0 P1 78 C45 H82 O13 N0 P1 79 C47 H84 O13 N0 P1 80 C47 H84 O13 N0 P1 81 C47 H82 O13 N0 P1 82 C47 H80 O13 N0 P1 83 C49 H84 O13 N0 P1 431 C22 H44 O9 N0 P1 433 C24 H48 O9 N0 P1 434 C24 H46 O9 N0 P1 435 C28 H44 O9 N0 P1 436 C25 H48 O12 N0 P1 437 C27 H52 O12 N0 P1 438 C27 H50 O12 N0 P1 445 C35 H68 O8 N0 P1 447 C36 H58 O8 N0 P1 448 C37 H72 O8 N0 P1 450 C37 H70 O8 N0 P1 451 C42 H78 O8 N0 P1 452 C45 H78 O7 N0 P1 453 C46 H86 O8 N0 P1 454 C47 H80 O8 N0 P1 455 C47 H82 O7 N0 P1 682 C30 H60 O9 N0 P1 683 C36 H70 O10 N0 P1 685 C38 H74 O10 N0 P1 686 C38 H72 O10 N0 P1 687 C39 H76 O10 N0 P1 688 C40 H78 O10 N0 P1 689 C40 H76 O10 N0 P1 691 C40 H74 O10 N0 P1 692 C40 H72 O10 N0 P1 693 C41 H78 O10 N0 P1 694 C41 H76 O10 N0 P1 695 C42 H80 O10 N0 P1 696 C42 H76 O10 N0 P1 698 C42 H74 O10 N0 P1 699 C42 H74 O10 N0 P1 700 C42 H70 O10 N0 P1 701 C43 H84 O10 N0 P1 702 C43 H80 O10 N0 P1 703 C44 H84 O10 N0 P1 704 C44 H82 O10 N0 P1 705 C44 H80 O10 N0 P1 706 C44 H78 O10 N0 P1 707 C44 H76 O10 N0 P1 708 C44 H74 O10 N0 P1 709 C44 H72 O10 N0 P1 710 C45 H74 O10 N0 P1 711 C46 H80 O10 N0 P1 712 C46 H78 O10 N0 P1 713 C46 H78 O10 N0 P1 714 C46 H74 O10 N0 P1 715 C46 H72 O10 N0 P1 716 C48 H74 O10 N0 P1 717 C48 H72 O10 N0 P1 718 C48 H80 O10 N0 P1 719 C48 H78 O10 N0 P1 720 C48 H76 O10 N0 P1 721 C50 H78 O10 N0 P1 722 C50 H76 O10 N0 P1 723 C50 H74 O10 N0 P1 724 C41 H78 O13 N0 P1 725 C41 H76 O13 N0 P1 726 C43 H82 O13 N0 P1 727 C43 H78 O13 N0 P1 728 C44 H82 O13 N0 P1 729 C44 H80 O13 N0 P1 730 C45 H86 O13 N0 P1 732 C45 H84 O13 N0 P1 733 C45 H82 O13 N0 P1 734 C45 H80 O13 N0 P1 735 C45 H78 O13 N0 P1 736 C45 H76 O13 N0 P1 737 C46 H86 O13 N0 P1 738 C46 H86 O13 N0 P1 739 C46 H84 O13 N0 P1 740 C46 H82 O13 N0 P1 741 C46 H80 O13 N0 P1 742 C47 H88 O13 N0 P1 743 C47 H86 O13 N0 P1 744 C47 H82 O13 N0 P1 745 C47 H80 O13 N0 P1 746 C47 H82 O12 N0 P1 747 C47 H78 O13 N0 P1 748 C48 H88 O13 N0 P1 749 C48 H86 O13 N0 P1 750 C48 H84 O13 N0 P1 751 C48 H82 O13 N0 P1 752 C48 H80 O13 N0 P1 753 C49 H92 O13 N0 P1 754 C49 H90 O13 N0 P1 757 C49 H88 O13 N0 P1 758 C49 H88 O13 N0 P1 759 C49 H88 O13 N0 P1 760 C49 H86 O13 N0 P1 761 C49 H86 O13 N0 P1 762 C49 H82 O13 N0 P1 763 C49 H82 O13 N0 P1 764 C49 H80 O13 N0 P1 765 C49 H78 O12 N0 P1 767 C51 H96 O13 N0 P1 768 C51 H94 O13 N0 P1 769 C51 H88 O13 N0 P1 770 C51 H86 O13 N0 P1 771 C31 H59 O15 N0 P2 772 C49 H81 O15 N0 P2 773 C51 H85 O15 N0 P2 774 C44 H84 O19 N0 P3 775 C45 H82 O19 N0 P3 776 C46 H88 O18 N0 P3 778 C46 H86 O18 N0 P3 Warning: The "RT-(min)" column at position 10 in the METABOLITES table, matches a standard column name, "retention_time". If this match was not in error, the column should be renamed to the standard name or a name that doesn't resemble the standard name. Warning: The "FA3" column at position 6 in the METABOLITES table may have incorrect values. 90% or more of the values are the same, but 10% or less are different. Warning: The "FA4" column at position 7 in the METABOLITES table may have incorrect values. 90% or more of the values are the same, but 10% or less are different.