Validation Log 2025-12-15 03:22:24.326137 mwtab Python Library Version: 2.0.0 Source: https://www.metabolomicsworkbench.org/rest/study/analysis_id/AN006962/mwtab/txt Study ID: ST004190 Analysis ID: AN006962 File format: txt Status: Contains Validation Issues Number of Issues: 11 Number of Warnings: 4 Number of Value Errors: 11 Number of Consistency Errors: 0 Number of Format Errors: 0 Issue Log: Error: The value, "20-24 grams", for the subsection, "WEIGHT_OR_WEIGHT_RANGE", in the "SUBJECT" section should be a number or range (ex. "5-6") followed by a space with a unit (ex. "5 V") from the following list: ['g', 'mg', 'kg', 'lbs']. Ignore this when more complicated descriptions are required. Error: The value, "Male and female", for the subsection, "GENDER", in the "SUBJECT" section should be one of "Male", "Female", "Male, Female", "Hermaphrodite", or "N/A". Ignore this when more complicated descriptions are required. Error: The value, "320", for the subsection, "CAPILLARY_TEMPERATURE", in the "MS" section should be a number or range (ex. "5-6") followed by a space with a unit (ex. "5 V") from the following list: ['°C', 'C']. Ignore this when more complicated descriptions are required. Error: The value, "+3600", for the subsection, "CAPILLARY_VOLTAGE", in the "MS" section should be a number followed by a space with a unit (ex. "5 V") from the following list: ['V', 'kV']. Ignore this when more complicated descriptions are required. Error: The value, "5", for the subsection, "DRY_GAS_FLOW", in the "MS" section should be a number followed by a space with a unit (ex. "5 V") from the following list: ['L/hr', 'L/min']. Ignore this when more complicated descriptions are required. Error: The value, "320", for the subsection, "DRY_GAS_TEMP", in the "MS" section should be a number followed by a space with a unit (ex. "5 V") from the following list: ['°C', 'C']. Ignore this when more complicated descriptions are required. Error: The value, "50 µL/min", for the subsection, "FLOW_RATE", in the "CHROMATOGRAPHY" section should be a number or range (ex. "5-6") followed by a space with a unit (ex. "5 V") from the following list: ['mL/min', 'uL/min', 'μL/min']. Ignore this when more complicated descriptions are required. Warning: The "m/z" column at position 2 in the METABOLITES table, matches a standard column name, "moverz_quant". If this match was not in error, the column should be renamed to the standard name or a name that doesn't resemble the standard name. Warning: The "Reference_Ion" column at position 4 in the METABOLITES table, matches a standard column name, "ion". If this match was not in error, the column should be renamed to the standard name or a name that doesn't resemble the standard name. Warning: The "Reference_Ion" column at position 4 in the METABOLITES table, matches a standard column name, "ion", and some of the values in the column do not match the expected type or format for that column. The non-matching values are: 159 [M+H+MeOH]+1 329 [M+H+MeOH]+1 359 [M+H+MeOH]+1 562 [M+H+MeOH]+1 579 [M+H+MeOH]+1 669 [M+H+MeOH]+1 728 [M+H+MeOH]+1 746 [M+H+MeOH]+1 751 [M+H+MeOH]+1 753 [M+H+MeOH]+1 794 [M+H+MeOH]+1 838 [M+H+MeOH]+1 862 [M+H+MeOH]+1 890 [M+H+MeOH]+1 900 [M+H+MeOH]+1 933 [M+H+MeOH]+1 953 [M+H]-H2O 1020 [M+H+MeOH]+1 1060 [M+H+MeOH]+1 1097 [M+H+MeOH]+1 1156 [M+H+MeOH]+1 1183 [M+H+MeOH]+1 1192 [M+H+MeOH]+1 1199 [M+H+MeOH]+1 1232 [M+H+MeOH]+1 1246 [M+H+MeOH]+1 1256 [M+H+MeOH]+1 1257 [M+H+MeOH]+1 1264 [M+H+MeOH]+1 1265 [M+H+MeOH]+1 1273 [M+H+MeOH]+1 1276 [M+H+MeOH]+1 1338 [M+H+MeOH]+1 1392 [M+H+MeOH]+1 1427 [M+H+MeOH]+1 1581 [M+H+MeOH]+1 1668 [M+DMSO+H]+1 1780 [M+H+MeOH]+1 1803 [M+H+MeOH]+1 Warning: The "RT(min)" column at position 3 in the METABOLITES table, matches a standard column name, "retention_time". If this match was not in error, the column should be renamed to the standard name or a name that doesn't resemble the standard name.