Validation Log 2025-12-15 03:23:10.792001 mwtab Python Library Version: 2.0.0 Source: https://www.metabolomicsworkbench.org/rest/study/analysis_id/AN006991/mwtab/json Study ID: ST004204 Analysis ID: AN006991 File format: json Status: Contains Validation Issues Number of Issues: 11 Number of Warnings: 5 Number of Value Errors: 11 Number of Consistency Errors: 0 Number of Format Errors: 0 Issue Log: Error: The value, "12 hours", in ["TREATMENT"]["TREATMENT_DOSEDURATION"] should be a number or range (ex. "5-6") followed by a space with a unit (ex. "5 V") from the following list: ['h', 'weeks', 'days']. Ignore this when more complicated descriptions are required. Error: The value, "320℃", in ["MS"]["CAPILLARY_TEMPERATURE"] should be a number or range (ex. "5-6") followed by a space with a unit (ex. "5 V") from the following list: ['°C', 'C']. Ignore this when more complicated descriptions are required. Error: The value, "35psi", in ["MS"]["DRY_GAS_FLOW"] should be a number followed by a space with a unit (ex. "5 V") from the following list: ['L/hr', 'L/min']. Ignore this when more complicated descriptions are required. Error: The value, "3.5kV", in ["MS"]["SPRAY_VOLTAGE"] should be a number followed by a space with a unit (ex. "5 V") from the following list: ['kV']. Ignore this when more complicated descriptions are required. Error: The value, "0.2mL/min", in ["CHROMATOGRAPHY"]["FLOW_RATE"] should be a number or range (ex. "5-6") followed by a space with a unit (ex. "5 V") from the following list: ['mL/min', 'uL/min', 'μL/min']. Ignore this when more complicated descriptions are required. Error: The value, "40℃", in ["CHROMATOGRAPHY"]["COLUMN_TEMPERATURE"] should be a number or range (ex. "5-6") followed by a space with a unit (ex. "5 V") from the following list: ['°C', 'C']. Ignore this when more complicated descriptions are required. Warning: The "m/z" column at position 5 in the ["MS_METABOLITE_DATA"]["Metabolites"] table, matches a standard column name, "moverz_quant". If this match was not in error, the column should be renamed to the standard name or a name that doesn't resemble the standard name. Warning: The "Molecular Weight" column at position 3 in the ["MS_METABOLITE_DATA"]["Metabolites"] table, matches a standard column name, "mass". If this match was not in error, the column should be renamed to the standard name or a name that doesn't resemble the standard name. Warning: The "Formula" column at position 2 in the ["MS_METABOLITE_DATA"]["Metabolites"] table, matches a standard column name, "formula", and some of the values in the column do not match the expected type or format for that column. The non-matching values are: 2 C11 H13 N O3 3 C8 H15 N O3 10 C9 H9 N O3 25 C6 H9 N O5 28 C26 H43 N O5 38 C11 H13 N O4 43 C11 H19 N O9 44 C26 H45 N O6 S 47 C7 H13 N O3 S 51 C7 H11 N O5 53 C10 H11 N O3 54 C26 H43 N O6 58 C21 H17 N O3 61 C10 H19 N O3 75 C26 H45 N O7 S 76 C7 H13 N O3 78 C10 H13 N O2 79 C11 H11 N O3 82 C10 H11 N O3 85 C9 H11 N O2 87 C9 H11 N O3 89 C23 H39 N O19 96 C5 H9 N O2 98 C5 H11 N O2 99 C6 H5 N O3 104 C8 H7 N O2 106 C23 H27 N O9 108 C24 H21 N O3 111 C8 H16 N O9 P 113 C6 H13 N O3 118 C7 H13 N O3 S 120 C10 H9 N O2 121 C15 H17 N O2 129 C22 H24 Cl N O 132 C14 H19 N O4 134 C17 H18 F N3 O4 135 C15 H12 N2 O S2 142 C11 H21 N O4 143 C11 H13 N O5 145 C21 H18 [2]H9 N O 146 C8 H10 N O6 P 157 C17 H20 F N3 O2 S 165 C11 H19 N O10 170 C4 H9 N O2 173 C10 H11 N O2 176 C11 H12 Cl N3 O 184 C10 H14 N5 O10 P S 188 C22 H23 N O2 189 C15 H6 [2]H4 Cl F N2 O 195 C9 H17 N O4 197 C20 H39 N O3 198 C8 H16 N O9 P 204 C15 H13 N O3 207 C3 H7 N O3 212 C41 H73 N O18 224 C21 H15 Cl N4 O3 227 C16 H17 N O8 239 C20 H36 N O7 P 246 C4 H9 N O5 S 248 C11 H12 [2]H3 N O 255 C10 H9 N O2 256 C9 H13 N O3 277 C17 H21 N O4 280 C10 H7 N O4 282 C23 H27 N O9 285 C26 H45 N O7 S 287 C40 H80 N O8 P 313 C3 H7 N O4 S 323 C21 H42 N O7 P 333 C3 H8 N O6 P 342 C6 H12 N Na O8 S 346 C15 H12 Cl N O3 369 C24 H50 N O7 P 370 C23 H46 N O7 P 377 C23 H46 N O7 P 383 C12 H15 N O4 385 C10 H13 N O3 386 C13 H17 N O3 391 C8 H11 N O3 394 C6 H9 N O5 396 C8 H9 N O4 397 C7 H7 N O3 401 C10 H15 N O3 406 C12 H23 N O4 407 C5 H9 N O5 409 C10 H13 N O4 410 C10 H19 N O4 411 C9 H11 N O4 413 C9 H9 N O2 414 C10 H15 N O2 416 C11 H13 N O6 422 C7 H7 N O2 431 C7 H11 N O4 448 C11 H17 N O3 461 C6 H11 N O4 465 C8 H7 N O4 S 472 C7 H5 N O4 475 C8 H15 N O S2 478 C10 H7 N O3 Warning: The "Lipidmaps_ID" column at position 8 in the ["MS_METABOLITE_DATA"]["Metabolites"] table, matches a standard column name, "lm_id". If this match was not in error, the column should be renamed to the standard name or a name that doesn't resemble the standard name. Warning: The "RT [min]" column at position 4 in the ["MS_METABOLITE_DATA"]["Metabolites"] table, matches a standard column name, "retention_time". If this match was not in error, the column should be renamed to the standard name or a name that doesn't resemble the standard name.