Validation Log 2025-12-15 03:27:26.249066 mwtab Python Library Version: 2.0.0 Source: https://www.metabolomicsworkbench.org/rest/study/analysis_id/AN007114/mwtab/json Study ID: ST004275 Analysis ID: AN007114 File format: json Status: Contains Validation Issues Number of Issues: 143 Number of Warnings: 128 Number of Value Errors: 142 Number of Consistency Errors: 0 Number of Format Errors: 0 Issue Log: Error: An empty value or a null value was detected in ["SUBJECT"]["GENOTYPE_STRAIN"]. Either a legitimate value should be provided for this key, or it should be removed altogether. Error: The value, "30-65 year age range", in ["SUBJECT"]["AGE_OR_AGE_RANGE"] should be a number or range (ex. "5-6") followed by a space with a unit (ex. "5 V") from the following list: ['weeks', 'days', 'months', 'years']. Ignore this when more complicated descriptions are required. Error: The value, "24 to 35 kg/m2", in ["SUBJECT"]["WEIGHT_OR_WEIGHT_RANGE"] should be a number or range (ex. "5-6") followed by a space with a unit (ex. "5 V") from the following list: ['g', 'mg', 'kg', 'lbs']. Ignore this when more complicated descriptions are required. Error: The value, "1.74+/-1.23 meters", in ["SUBJECT"]["HEIGHT_OR_HEIGHT_RANGE"] should be a number or range (ex. "5-6") followed by a space with a unit (ex. "5 V") from the following list: ['cm', 'in']. Ignore this when more complicated descriptions are required. Error: The value, "Male and female", in ["SUBJECT"]["GENDER"] should be one of "Male", "Female", "Male, Female", "Hermaphrodite", or "N/A". Ignore this when more complicated descriptions are required. Error: An empty value or a null value was detected in ["SUBJECT"]["HUMAN_RACE"]. Either a legitimate value should be provided for this key, or it should be removed altogether. Error: An empty value or a null value was detected in ["SUBJECT"]["HUMAN_ETHNICITY"]. Either a legitimate value should be provided for this key, or it should be removed altogether. Error: The value, "6 months", in ["TREATMENT"]["TREATMENT_DOSEDURATION"] should be a number or range (ex. "5-6") followed by a space with a unit (ex. "5 V") from the following list: ['h', 'weeks', 'days']. Ignore this when more complicated descriptions are required. Error: An empty value or a null value was detected in ["CHROMATOGRAPHY"]["FLOW_GRADIENT"]. A legitimate value should be provided for this required key. Error: The value, "1mL/min", in ["CHROMATOGRAPHY"]["FLOW_RATE"] should be a number or range (ex. "5-6") followed by a space with a unit (ex. "5 V") from the following list: ['mL/min', 'uL/min', 'μL/min']. Ignore this when more complicated descriptions are required. Error: The value, "50-330", in ["CHROMATOGRAPHY"]["COLUMN_TEMPERATURE"] should be a number or range (ex. "5-6") followed by a space with a unit (ex. "5 V") from the following list: ['°C', 'C']. Ignore this when more complicated descriptions are required. Error: The value in ["CHROMATOGRAPHY"]["SAMPLE_INJECTION"] should be a number followed by a space with a unit (ex. "5 V") from the following list: ['μL', 'uL']. Ignore this when more complicated descriptions are required. Error: An empty value or a null value was detected in ["CHROMATOGRAPHY"]["SOLVENT_A"]. A legitimate value should be provided for this required key. Error: An empty value or a null value was detected in ["CHROMATOGRAPHY"]["SOLVENT_B"]. A legitimate value should be provided for this required key. Error: The value, "50°C ramped to 250°C by 12°C s-1", in ["CHROMATOGRAPHY"]["INJECTION_TEMPERATURE"] should be a number or range (ex. "5-6") followed by a space with a unit (ex. "5 V") from the following list: ['°C', 'C'] or "room temperature". Ignore this when more complicated descriptions are required. Warning: The SSF at ["SUBJECT_SAMPLE_FACTORS"][0] has the following duplicate keys in its Additional sample data: "Group" Warning: The SSF at ["SUBJECT_SAMPLE_FACTORS"][1] has the following duplicate keys in its Additional sample data: "Group" Warning: The SSF at ["SUBJECT_SAMPLE_FACTORS"][2] has the following duplicate keys in its Additional sample data: "Group" Warning: The SSF at ["SUBJECT_SAMPLE_FACTORS"][3] has the following duplicate keys in its Additional sample data: "Group" Warning: The SSF at ["SUBJECT_SAMPLE_FACTORS"][4] has the following duplicate keys in its Additional sample data: "Group" Warning: The SSF at ["SUBJECT_SAMPLE_FACTORS"][5] has the following duplicate keys in its Additional sample data: "Group" Warning: The SSF at ["SUBJECT_SAMPLE_FACTORS"][6] has the following duplicate keys in its Additional sample data: "Group" Warning: The SSF at ["SUBJECT_SAMPLE_FACTORS"][7] has the following duplicate keys in its Additional sample data: "Group" Warning: The SSF at ["SUBJECT_SAMPLE_FACTORS"][8] has the following duplicate keys in its Additional sample data: "Group" Warning: The SSF at ["SUBJECT_SAMPLE_FACTORS"][9] has the following duplicate keys in its Additional sample data: "Group" Warning: The SSF at ["SUBJECT_SAMPLE_FACTORS"][10] has the following duplicate keys in its Additional sample data: "Group" Warning: The SSF at ["SUBJECT_SAMPLE_FACTORS"][11] has the following duplicate keys in its Additional sample data: "Group" Warning: The SSF at ["SUBJECT_SAMPLE_FACTORS"][12] has the following duplicate keys in its Additional sample data: "Group" Warning: The SSF at ["SUBJECT_SAMPLE_FACTORS"][13] has the following duplicate keys in its Additional sample data: "Group" Warning: The SSF at ["SUBJECT_SAMPLE_FACTORS"][14] has the following duplicate keys in its Additional sample data: "Group" Warning: The SSF at ["SUBJECT_SAMPLE_FACTORS"][15] has the following duplicate keys in its Additional sample data: "Group" Warning: The SSF at ["SUBJECT_SAMPLE_FACTORS"][16] has the following duplicate keys in its Additional sample data: "Group" Warning: The SSF at ["SUBJECT_SAMPLE_FACTORS"][17] has the following duplicate keys in its Additional sample data: "Group" Warning: The SSF at ["SUBJECT_SAMPLE_FACTORS"][18] has the following duplicate keys in its Additional sample data: "Group" Warning: The SSF at ["SUBJECT_SAMPLE_FACTORS"][19] has the following duplicate keys in its Additional sample data: "Group" Warning: The SSF at ["SUBJECT_SAMPLE_FACTORS"][20] has the following duplicate keys in its Additional sample data: "Group" Warning: The SSF at ["SUBJECT_SAMPLE_FACTORS"][21] has the following duplicate keys in its Additional sample data: "Group" Warning: The SSF at ["SUBJECT_SAMPLE_FACTORS"][22] has the following duplicate keys in its Additional sample data: "Group" Warning: The SSF at ["SUBJECT_SAMPLE_FACTORS"][23] has the following duplicate keys in its Additional sample data: "Group" Warning: The SSF at ["SUBJECT_SAMPLE_FACTORS"][24] has the following duplicate keys in its Additional sample data: "Group" Warning: The SSF at ["SUBJECT_SAMPLE_FACTORS"][25] has the following duplicate keys in its Additional sample data: "Group" Warning: The SSF at ["SUBJECT_SAMPLE_FACTORS"][26] has the following duplicate keys in its Additional sample data: "Group" Warning: The SSF at ["SUBJECT_SAMPLE_FACTORS"][27] has the following duplicate keys in its Additional sample data: "Group" Warning: The SSF at ["SUBJECT_SAMPLE_FACTORS"][28] has the following duplicate keys in its Additional sample data: "Group" Warning: The SSF at ["SUBJECT_SAMPLE_FACTORS"][29] has the following duplicate keys in its Additional sample data: "Group" Warning: The SSF at ["SUBJECT_SAMPLE_FACTORS"][30] has the following duplicate keys in its Additional sample data: "Group" Warning: The SSF at ["SUBJECT_SAMPLE_FACTORS"][31] has the following duplicate keys in its Additional sample data: "Group" Warning: The SSF at ["SUBJECT_SAMPLE_FACTORS"][32] has the following duplicate keys in its Additional sample data: "Group" Warning: The SSF at ["SUBJECT_SAMPLE_FACTORS"][33] has the following duplicate keys in its Additional sample data: "Group" Warning: The SSF at ["SUBJECT_SAMPLE_FACTORS"][34] has the following duplicate keys in its Additional sample data: "Group" Warning: The SSF at ["SUBJECT_SAMPLE_FACTORS"][35] has the following duplicate keys in its Additional sample data: "Group" Warning: The SSF at ["SUBJECT_SAMPLE_FACTORS"][36] has the following duplicate keys in its Additional sample data: "Group" Warning: The SSF at ["SUBJECT_SAMPLE_FACTORS"][37] has the following duplicate keys in its Additional sample data: "Group" Warning: The SSF at ["SUBJECT_SAMPLE_FACTORS"][38] has the following duplicate keys in its Additional sample data: "Group" Warning: The SSF at ["SUBJECT_SAMPLE_FACTORS"][39] has the following duplicate keys in its Additional sample data: "Group" Warning: The SSF at ["SUBJECT_SAMPLE_FACTORS"][40] has the following duplicate keys in its Additional sample data: "Group" Warning: The SSF at ["SUBJECT_SAMPLE_FACTORS"][41] has the following duplicate keys in its Additional sample data: "Group" Warning: The SSF at ["SUBJECT_SAMPLE_FACTORS"][42] has the following duplicate keys in its Additional sample data: "Group" Warning: The SSF at ["SUBJECT_SAMPLE_FACTORS"][43] has the following duplicate keys in its Additional sample data: "Group" Warning: The SSF at ["SUBJECT_SAMPLE_FACTORS"][44] has the following duplicate keys in its Additional sample data: "Group" Warning: The SSF at ["SUBJECT_SAMPLE_FACTORS"][45] has the following duplicate keys in its Additional sample data: "Group" Warning: The SSF at ["SUBJECT_SAMPLE_FACTORS"][46] has the following duplicate keys in its Additional sample data: "Group" Warning: The SSF at ["SUBJECT_SAMPLE_FACTORS"][47] has the following duplicate keys in its Additional sample data: "Group" Warning: The SSF at ["SUBJECT_SAMPLE_FACTORS"][48] has the following duplicate keys in its Additional sample data: "Group" Warning: The SSF at ["SUBJECT_SAMPLE_FACTORS"][49] has the following duplicate keys in its Additional sample data: "Group" Warning: The SSF at ["SUBJECT_SAMPLE_FACTORS"][50] has the following duplicate keys in its Additional sample data: "Group" Warning: The SSF at ["SUBJECT_SAMPLE_FACTORS"][51] has the following duplicate keys in its Additional sample data: "Group" Warning: The SSF at ["SUBJECT_SAMPLE_FACTORS"][52] has the following duplicate keys in its Additional sample data: "Group" Warning: The SSF at ["SUBJECT_SAMPLE_FACTORS"][53] has the following duplicate keys in its Additional sample data: "Group" Warning: The SSF at ["SUBJECT_SAMPLE_FACTORS"][54] has the following duplicate keys in its Additional sample data: "Group" Warning: The SSF at ["SUBJECT_SAMPLE_FACTORS"][55] has the following duplicate keys in its Additional sample data: "Group" Warning: The SSF at ["SUBJECT_SAMPLE_FACTORS"][56] has the following duplicate keys in its Additional sample data: "Group" Warning: The SSF at ["SUBJECT_SAMPLE_FACTORS"][57] has the following duplicate keys in its Additional sample data: "Group" Warning: The SSF at ["SUBJECT_SAMPLE_FACTORS"][58] has the following duplicate keys in its Additional sample data: "Group" Warning: The SSF at ["SUBJECT_SAMPLE_FACTORS"][59] has the following duplicate keys in its Additional sample data: "Group" Warning: The SSF at ["SUBJECT_SAMPLE_FACTORS"][60] has the following duplicate keys in its Additional sample data: "Group" Warning: The SSF at ["SUBJECT_SAMPLE_FACTORS"][61] has the following duplicate keys in its Additional sample data: "Group" Warning: The SSF at ["SUBJECT_SAMPLE_FACTORS"][62] has the following duplicate keys in its Additional sample data: "Group" Warning: The SSF at ["SUBJECT_SAMPLE_FACTORS"][63] has the following duplicate keys in its Additional sample data: "Group" Warning: The SSF at ["SUBJECT_SAMPLE_FACTORS"][64] has the following duplicate keys in its Additional sample data: "Group" Warning: The SSF at ["SUBJECT_SAMPLE_FACTORS"][65] has the following duplicate keys in its Additional sample data: "Group" Warning: The SSF at ["SUBJECT_SAMPLE_FACTORS"][66] has the following duplicate keys in its Additional sample data: "Group" Warning: The SSF at ["SUBJECT_SAMPLE_FACTORS"][67] has the following duplicate keys in its Additional sample data: "Group" Warning: The SSF at ["SUBJECT_SAMPLE_FACTORS"][68] has the following duplicate keys in its Additional sample data: "Group" Warning: The SSF at ["SUBJECT_SAMPLE_FACTORS"][69] has the following duplicate keys in its Additional sample data: "Group" Warning: The SSF at ["SUBJECT_SAMPLE_FACTORS"][70] has the following duplicate keys in its Additional sample data: "Group" Warning: The SSF at ["SUBJECT_SAMPLE_FACTORS"][71] has the following duplicate keys in its Additional sample data: "Group" Warning: The SSF at ["SUBJECT_SAMPLE_FACTORS"][72] has the following duplicate keys in its Additional sample data: "Group" Warning: The SSF at ["SUBJECT_SAMPLE_FACTORS"][73] has the following duplicate keys in its Additional sample data: "Group" Warning: The SSF at ["SUBJECT_SAMPLE_FACTORS"][74] has the following duplicate keys in its Additional sample data: "Group" Warning: The SSF at ["SUBJECT_SAMPLE_FACTORS"][75] has the following duplicate keys in its Additional sample data: "Group" Warning: The SSF at ["SUBJECT_SAMPLE_FACTORS"][76] has the following duplicate keys in its Additional sample data: "Group" Warning: The SSF at ["SUBJECT_SAMPLE_FACTORS"][77] has the following duplicate keys in its Additional sample data: "Group" Warning: The SSF at ["SUBJECT_SAMPLE_FACTORS"][78] has the following duplicate keys in its Additional sample data: "Group" Warning: The SSF at ["SUBJECT_SAMPLE_FACTORS"][79] has the following duplicate keys in its Additional sample data: "Group" Warning: The SSF at ["SUBJECT_SAMPLE_FACTORS"][80] has the following duplicate keys in its Additional sample data: "Group" Warning: The SSF at ["SUBJECT_SAMPLE_FACTORS"][81] has the following duplicate keys in its Additional sample data: "Group" Warning: The SSF at ["SUBJECT_SAMPLE_FACTORS"][82] has the following duplicate keys in its Additional sample data: "Group" Warning: The SSF at ["SUBJECT_SAMPLE_FACTORS"][83] has the following duplicate keys in its Additional sample data: "Group" Warning: The SSF at ["SUBJECT_SAMPLE_FACTORS"][84] has the following duplicate keys in its Additional sample data: "Group" Warning: The SSF at ["SUBJECT_SAMPLE_FACTORS"][85] has the following duplicate keys in its Additional sample data: "Group" Warning: The SSF at ["SUBJECT_SAMPLE_FACTORS"][86] has the following duplicate keys in its Additional sample data: "Group" Warning: The SSF at ["SUBJECT_SAMPLE_FACTORS"][87] has the following duplicate keys in its Additional sample data: "Group" Warning: The SSF at ["SUBJECT_SAMPLE_FACTORS"][88] has the following duplicate keys in its Additional sample data: "Group" Warning: The SSF at ["SUBJECT_SAMPLE_FACTORS"][89] has the following duplicate keys in its Additional sample data: "Group" Warning: The SSF at ["SUBJECT_SAMPLE_FACTORS"][90] has the following duplicate keys in its Additional sample data: "Group" Warning: The SSF at ["SUBJECT_SAMPLE_FACTORS"][91] has the following duplicate keys in its Additional sample data: "Group" Warning: The SSF at ["SUBJECT_SAMPLE_FACTORS"][92] has the following duplicate keys in its Additional sample data: "Group" Warning: The SSF at ["SUBJECT_SAMPLE_FACTORS"][93] has the following duplicate keys in its Additional sample data: "Group" Warning: The SSF at ["SUBJECT_SAMPLE_FACTORS"][94] has the following duplicate keys in its Additional sample data: "Group" Warning: The SSF at ["SUBJECT_SAMPLE_FACTORS"][95] has the following duplicate keys in its Additional sample data: "Group" Warning: The SSF at ["SUBJECT_SAMPLE_FACTORS"][96] has the following duplicate keys in its Additional sample data: "Group" Warning: The SSF at ["SUBJECT_SAMPLE_FACTORS"][97] has the following duplicate keys in its Additional sample data: "Group" Warning: The SSF at ["SUBJECT_SAMPLE_FACTORS"][98] has the following duplicate keys in its Additional sample data: "Group" Warning: The SSF at ["SUBJECT_SAMPLE_FACTORS"][99] has the following duplicate keys in its Additional sample data: "Group" Warning: The SSF at ["SUBJECT_SAMPLE_FACTORS"][100] has the following duplicate keys in its Additional sample data: "Group" Warning: The SSF at ["SUBJECT_SAMPLE_FACTORS"][101] has the following duplicate keys in its Additional sample data: "Group" Warning: The SSF at ["SUBJECT_SAMPLE_FACTORS"][102] has the following duplicate keys in its Additional sample data: "Group" Warning: The SSF at ["SUBJECT_SAMPLE_FACTORS"][103] has the following duplicate keys in its Additional sample data: "Group" Warning: The SSF at ["SUBJECT_SAMPLE_FACTORS"][104] has the following duplicate keys in its Additional sample data: "Group" Warning: The SSF at ["SUBJECT_SAMPLE_FACTORS"][105] has the following duplicate keys in its Additional sample data: "Group" Warning: The SSF at ["SUBJECT_SAMPLE_FACTORS"][106] has the following duplicate keys in its Additional sample data: "Group" Warning: The SSF at ["SUBJECT_SAMPLE_FACTORS"][107] has the following duplicate keys in its Additional sample data: "Group" Warning: The SSF at ["SUBJECT_SAMPLE_FACTORS"][108] has the following duplicate keys in its Additional sample data: "Group" Warning: The SSF at ["SUBJECT_SAMPLE_FACTORS"][109] has the following duplicate keys in its Additional sample data: "Group" Warning: The SSF at ["SUBJECT_SAMPLE_FACTORS"][110] has the following duplicate keys in its Additional sample data: "Group" Warning: The SSF at ["SUBJECT_SAMPLE_FACTORS"][111] has the following duplicate keys in its Additional sample data: "Group" Warning: The SSF at ["SUBJECT_SAMPLE_FACTORS"][112] has the following duplicate keys in its Additional sample data: "Group" Warning: The SSF at ["SUBJECT_SAMPLE_FACTORS"][113] has the following duplicate keys in its Additional sample data: "Group" Warning: The SSF at ["SUBJECT_SAMPLE_FACTORS"][114] has the following duplicate keys in its Additional sample data: "Group" Warning: The SSF at ["SUBJECT_SAMPLE_FACTORS"][115] has the following duplicate keys in its Additional sample data: "Group" Warning: The SSF at ["SUBJECT_SAMPLE_FACTORS"][116] has the following duplicate keys in its Additional sample data: "Group" Warning: The SSF at ["SUBJECT_SAMPLE_FACTORS"][117] has the following duplicate keys in its Additional sample data: "Group" Warning: The SSF at ["SUBJECT_SAMPLE_FACTORS"][118] has the following duplicate keys in its Additional sample data: "Group" Warning: The SSF at ["SUBJECT_SAMPLE_FACTORS"][119] has the following duplicate keys in its Additional sample data: "Group" Warning: The "quant mz" column at position 3 in the ["MS_METABOLITE_DATA"]["Metabolites"] table, matches a standard column name, "moverz_quant". If this match was not in error, the column should be renamed to the standard name or a name that doesn't resemble the standard name. Warning: The "mass spec" column at position 5 in the ["MS_METABOLITE_DATA"]["Metabolites"] table, matches a standard column name, "mass_spectrum". If this match was not in error, the column should be renamed to the standard name or a name that doesn't resemble the standard name. Warning: The "InChI Key" column at position 8 in the ["MS_METABOLITE_DATA"]["Metabolites"] table, matches a standard column name, "inchi_key". If this match was not in error, the column should be renamed to the standard name or a name that doesn't resemble the standard name. Warning: The "PubChem" column at position 6 in the ["MS_METABOLITE_DATA"]["Metabolites"] table, matches a standard column name, "pubchem_id". If this match was not in error, the column should be renamed to the standard name or a name that doesn't resemble the standard name. Warning: The "KEGG" column at position 7 in the ["MS_METABOLITE_DATA"]["Metabolites"] table, matches a standard column name, "kegg_id". If this match was not in error, the column should be renamed to the standard name or a name that doesn't resemble the standard name. Warning: The "BB id" column at position 4 in the ["MS_METABOLITE_DATA"]["Metabolites"] table, matches a standard column name, "binbase_id". If this match was not in error, the column should be renamed to the standard name or a name that doesn't resemble the standard name. Warning: The "ret.index" column at position 2 in the ["MS_METABOLITE_DATA"]["Metabolites"] table, matches a standard column name, "retention_index". If this match was not in error, the column should be renamed to the standard name or a name that doesn't resemble the standard name. Warning: The column "ret.index" was found in the ["MS_METABOLITE_DATA"]["Metabolites"] table, but this column implies that another column, "retention_index_type", should also exist, and that column was not found.