Validation Log
2025-12-15 03:27:24.442652
mwtab Python Library Version: 2.0.0
Source:        https://www.metabolomicsworkbench.org/rest/study/analysis_id/AN007114/mwtab/txt
Study ID:      ST004275
Analysis ID:   AN007114
File format:   txt
Status: Contains Validation Issues
Number of Issues: 143

Number of Warnings: 128

Number of Value Errors: 142

Number of Consistency Errors: 0

Number of Format Errors: 0

Issue Log:
Error: An empty value or a null value was detected for the subsection, "GENOTYPE_STRAIN", in the "SUBJECT" section. Either a legitimate value should be provided for this subsection, or it should be removed altogether.
Error: The value, "30-65 year age range", for the subsection, "AGE_OR_AGE_RANGE", in the "SUBJECT" section should be a number or range (ex. "5-6") followed by a space with a unit (ex. "5 V") from the following list: ['weeks', 'days', 'months', 'years']. Ignore this when more complicated descriptions are required.
Error: The value, "24 to 35 kg/m2", for the subsection, "WEIGHT_OR_WEIGHT_RANGE", in the "SUBJECT" section should be a number or range (ex. "5-6") followed by a space with a unit (ex. "5 V") from the following list: ['g', 'mg', 'kg', 'lbs']. Ignore this when more complicated descriptions are required.
Error: The value, "1.74+/-1.23 meters", for the subsection, "HEIGHT_OR_HEIGHT_RANGE", in the "SUBJECT" section should be a number or range (ex. "5-6") followed by a space with a unit (ex. "5 V") from the following list: ['cm', 'in']. Ignore this when more complicated descriptions are required.
Error: The value, "Male and female", for the subsection, "GENDER", in the "SUBJECT" section should be one of "Male", "Female", "Male, Female", "Hermaphrodite", or "N/A". Ignore this when more complicated descriptions are required.
Error: An empty value or a null value was detected for the subsection, "HUMAN_RACE", in the "SUBJECT" section. Either a legitimate value should be provided for this subsection, or it should be removed altogether.
Error: An empty value or a null value was detected for the subsection, "HUMAN_ETHNICITY", in the "SUBJECT" section. Either a legitimate value should be provided for this subsection, or it should be removed altogether.
Error: The value, "6 months", for the subsection, "TREATMENT_DOSEDURATION", in the "TREATMENT" section should be a number or range (ex. "5-6") followed by a space with a unit (ex. "5 V") from the following list: ['h', 'weeks', 'days']. Ignore this when more complicated descriptions are required.
Error: An empty value or a null value was detected for the subsection, "FLOW_GRADIENT", in the "CHROMATOGRAPHY" section. A legitimate value should be provided for this required subsection.
Error: The value, "1mL/min", for the subsection, "FLOW_RATE", in the "CHROMATOGRAPHY" section should be a number or range (ex. "5-6") followed by a space with a unit (ex. "5 V") from the following list: ['mL/min', 'uL/min', 'μL/min']. Ignore this when more complicated descriptions are required.
Error: The value, "50-330", for the subsection, "COLUMN_TEMPERATURE", in the "CHROMATOGRAPHY" section should be a number or range (ex. "5-6") followed by a space with a unit (ex. "5 V") from the following list: ['°C', 'C']. Ignore this when more complicated descriptions are required.
Error: The value for the subsection, "SAMPLE_INJECTION", in the "CHROMATOGRAPHY" section should be a number followed by a space with a unit (ex. "5 V") from the following list: ['μL', 'uL']. Ignore this when more complicated descriptions are required.
Error: An empty value or a null value was detected for the subsection, "SOLVENT_A", in the "CHROMATOGRAPHY" section. A legitimate value should be provided for this required subsection.
Error: An empty value or a null value was detected for the subsection, "SOLVENT_B", in the "CHROMATOGRAPHY" section. A legitimate value should be provided for this required subsection.
Error: The value, "50°C ramped to 250°C by 12°C s-1", for the subsection, "INJECTION_TEMPERATURE", in the "CHROMATOGRAPHY" section should be a number or range (ex. "5-6") followed by a space with a unit (ex. "5 V") from the following list: ['°C', 'C'] or "room temperature". Ignore this when more complicated descriptions are required.
Warning: SUBJECT_SAMPLE_FACTORS entry #1 has the following duplicate keys in its Additional sample data:
	"Group"
Warning: SUBJECT_SAMPLE_FACTORS entry #2 has the following duplicate keys in its Additional sample data:
	"Group"
Warning: SUBJECT_SAMPLE_FACTORS entry #3 has the following duplicate keys in its Additional sample data:
	"Group"
Warning: SUBJECT_SAMPLE_FACTORS entry #4 has the following duplicate keys in its Additional sample data:
	"Group"
Warning: SUBJECT_SAMPLE_FACTORS entry #5 has the following duplicate keys in its Additional sample data:
	"Group"
Warning: SUBJECT_SAMPLE_FACTORS entry #6 has the following duplicate keys in its Additional sample data:
	"Group"
Warning: SUBJECT_SAMPLE_FACTORS entry #7 has the following duplicate keys in its Additional sample data:
	"Group"
Warning: SUBJECT_SAMPLE_FACTORS entry #8 has the following duplicate keys in its Additional sample data:
	"Group"
Warning: SUBJECT_SAMPLE_FACTORS entry #9 has the following duplicate keys in its Additional sample data:
	"Group"
Warning: SUBJECT_SAMPLE_FACTORS entry #10 has the following duplicate keys in its Additional sample data:
	"Group"
Warning: SUBJECT_SAMPLE_FACTORS entry #11 has the following duplicate keys in its Additional sample data:
	"Group"
Warning: SUBJECT_SAMPLE_FACTORS entry #12 has the following duplicate keys in its Additional sample data:
	"Group"
Warning: SUBJECT_SAMPLE_FACTORS entry #13 has the following duplicate keys in its Additional sample data:
	"Group"
Warning: SUBJECT_SAMPLE_FACTORS entry #14 has the following duplicate keys in its Additional sample data:
	"Group"
Warning: SUBJECT_SAMPLE_FACTORS entry #15 has the following duplicate keys in its Additional sample data:
	"Group"
Warning: SUBJECT_SAMPLE_FACTORS entry #16 has the following duplicate keys in its Additional sample data:
	"Group"
Warning: SUBJECT_SAMPLE_FACTORS entry #17 has the following duplicate keys in its Additional sample data:
	"Group"
Warning: SUBJECT_SAMPLE_FACTORS entry #18 has the following duplicate keys in its Additional sample data:
	"Group"
Warning: SUBJECT_SAMPLE_FACTORS entry #19 has the following duplicate keys in its Additional sample data:
	"Group"
Warning: SUBJECT_SAMPLE_FACTORS entry #20 has the following duplicate keys in its Additional sample data:
	"Group"
Warning: SUBJECT_SAMPLE_FACTORS entry #21 has the following duplicate keys in its Additional sample data:
	"Group"
Warning: SUBJECT_SAMPLE_FACTORS entry #22 has the following duplicate keys in its Additional sample data:
	"Group"
Warning: SUBJECT_SAMPLE_FACTORS entry #23 has the following duplicate keys in its Additional sample data:
	"Group"
Warning: SUBJECT_SAMPLE_FACTORS entry #24 has the following duplicate keys in its Additional sample data:
	"Group"
Warning: SUBJECT_SAMPLE_FACTORS entry #25 has the following duplicate keys in its Additional sample data:
	"Group"
Warning: SUBJECT_SAMPLE_FACTORS entry #26 has the following duplicate keys in its Additional sample data:
	"Group"
Warning: SUBJECT_SAMPLE_FACTORS entry #27 has the following duplicate keys in its Additional sample data:
	"Group"
Warning: SUBJECT_SAMPLE_FACTORS entry #28 has the following duplicate keys in its Additional sample data:
	"Group"
Warning: SUBJECT_SAMPLE_FACTORS entry #29 has the following duplicate keys in its Additional sample data:
	"Group"
Warning: SUBJECT_SAMPLE_FACTORS entry #30 has the following duplicate keys in its Additional sample data:
	"Group"
Warning: SUBJECT_SAMPLE_FACTORS entry #31 has the following duplicate keys in its Additional sample data:
	"Group"
Warning: SUBJECT_SAMPLE_FACTORS entry #32 has the following duplicate keys in its Additional sample data:
	"Group"
Warning: SUBJECT_SAMPLE_FACTORS entry #33 has the following duplicate keys in its Additional sample data:
	"Group"
Warning: SUBJECT_SAMPLE_FACTORS entry #34 has the following duplicate keys in its Additional sample data:
	"Group"
Warning: SUBJECT_SAMPLE_FACTORS entry #35 has the following duplicate keys in its Additional sample data:
	"Group"
Warning: SUBJECT_SAMPLE_FACTORS entry #36 has the following duplicate keys in its Additional sample data:
	"Group"
Warning: SUBJECT_SAMPLE_FACTORS entry #37 has the following duplicate keys in its Additional sample data:
	"Group"
Warning: SUBJECT_SAMPLE_FACTORS entry #38 has the following duplicate keys in its Additional sample data:
	"Group"
Warning: SUBJECT_SAMPLE_FACTORS entry #39 has the following duplicate keys in its Additional sample data:
	"Group"
Warning: SUBJECT_SAMPLE_FACTORS entry #40 has the following duplicate keys in its Additional sample data:
	"Group"
Warning: SUBJECT_SAMPLE_FACTORS entry #41 has the following duplicate keys in its Additional sample data:
	"Group"
Warning: SUBJECT_SAMPLE_FACTORS entry #42 has the following duplicate keys in its Additional sample data:
	"Group"
Warning: SUBJECT_SAMPLE_FACTORS entry #43 has the following duplicate keys in its Additional sample data:
	"Group"
Warning: SUBJECT_SAMPLE_FACTORS entry #44 has the following duplicate keys in its Additional sample data:
	"Group"
Warning: SUBJECT_SAMPLE_FACTORS entry #45 has the following duplicate keys in its Additional sample data:
	"Group"
Warning: SUBJECT_SAMPLE_FACTORS entry #46 has the following duplicate keys in its Additional sample data:
	"Group"
Warning: SUBJECT_SAMPLE_FACTORS entry #47 has the following duplicate keys in its Additional sample data:
	"Group"
Warning: SUBJECT_SAMPLE_FACTORS entry #48 has the following duplicate keys in its Additional sample data:
	"Group"
Warning: SUBJECT_SAMPLE_FACTORS entry #49 has the following duplicate keys in its Additional sample data:
	"Group"
Warning: SUBJECT_SAMPLE_FACTORS entry #50 has the following duplicate keys in its Additional sample data:
	"Group"
Warning: SUBJECT_SAMPLE_FACTORS entry #51 has the following duplicate keys in its Additional sample data:
	"Group"
Warning: SUBJECT_SAMPLE_FACTORS entry #52 has the following duplicate keys in its Additional sample data:
	"Group"
Warning: SUBJECT_SAMPLE_FACTORS entry #53 has the following duplicate keys in its Additional sample data:
	"Group"
Warning: SUBJECT_SAMPLE_FACTORS entry #54 has the following duplicate keys in its Additional sample data:
	"Group"
Warning: SUBJECT_SAMPLE_FACTORS entry #55 has the following duplicate keys in its Additional sample data:
	"Group"
Warning: SUBJECT_SAMPLE_FACTORS entry #56 has the following duplicate keys in its Additional sample data:
	"Group"
Warning: SUBJECT_SAMPLE_FACTORS entry #57 has the following duplicate keys in its Additional sample data:
	"Group"
Warning: SUBJECT_SAMPLE_FACTORS entry #58 has the following duplicate keys in its Additional sample data:
	"Group"
Warning: SUBJECT_SAMPLE_FACTORS entry #59 has the following duplicate keys in its Additional sample data:
	"Group"
Warning: SUBJECT_SAMPLE_FACTORS entry #60 has the following duplicate keys in its Additional sample data:
	"Group"
Warning: SUBJECT_SAMPLE_FACTORS entry #61 has the following duplicate keys in its Additional sample data:
	"Group"
Warning: SUBJECT_SAMPLE_FACTORS entry #62 has the following duplicate keys in its Additional sample data:
	"Group"
Warning: SUBJECT_SAMPLE_FACTORS entry #63 has the following duplicate keys in its Additional sample data:
	"Group"
Warning: SUBJECT_SAMPLE_FACTORS entry #64 has the following duplicate keys in its Additional sample data:
	"Group"
Warning: SUBJECT_SAMPLE_FACTORS entry #65 has the following duplicate keys in its Additional sample data:
	"Group"
Warning: SUBJECT_SAMPLE_FACTORS entry #66 has the following duplicate keys in its Additional sample data:
	"Group"
Warning: SUBJECT_SAMPLE_FACTORS entry #67 has the following duplicate keys in its Additional sample data:
	"Group"
Warning: SUBJECT_SAMPLE_FACTORS entry #68 has the following duplicate keys in its Additional sample data:
	"Group"
Warning: SUBJECT_SAMPLE_FACTORS entry #69 has the following duplicate keys in its Additional sample data:
	"Group"
Warning: SUBJECT_SAMPLE_FACTORS entry #70 has the following duplicate keys in its Additional sample data:
	"Group"
Warning: SUBJECT_SAMPLE_FACTORS entry #71 has the following duplicate keys in its Additional sample data:
	"Group"
Warning: SUBJECT_SAMPLE_FACTORS entry #72 has the following duplicate keys in its Additional sample data:
	"Group"
Warning: SUBJECT_SAMPLE_FACTORS entry #73 has the following duplicate keys in its Additional sample data:
	"Group"
Warning: SUBJECT_SAMPLE_FACTORS entry #74 has the following duplicate keys in its Additional sample data:
	"Group"
Warning: SUBJECT_SAMPLE_FACTORS entry #75 has the following duplicate keys in its Additional sample data:
	"Group"
Warning: SUBJECT_SAMPLE_FACTORS entry #76 has the following duplicate keys in its Additional sample data:
	"Group"
Warning: SUBJECT_SAMPLE_FACTORS entry #77 has the following duplicate keys in its Additional sample data:
	"Group"
Warning: SUBJECT_SAMPLE_FACTORS entry #78 has the following duplicate keys in its Additional sample data:
	"Group"
Warning: SUBJECT_SAMPLE_FACTORS entry #79 has the following duplicate keys in its Additional sample data:
	"Group"
Warning: SUBJECT_SAMPLE_FACTORS entry #80 has the following duplicate keys in its Additional sample data:
	"Group"
Warning: SUBJECT_SAMPLE_FACTORS entry #81 has the following duplicate keys in its Additional sample data:
	"Group"
Warning: SUBJECT_SAMPLE_FACTORS entry #82 has the following duplicate keys in its Additional sample data:
	"Group"
Warning: SUBJECT_SAMPLE_FACTORS entry #83 has the following duplicate keys in its Additional sample data:
	"Group"
Warning: SUBJECT_SAMPLE_FACTORS entry #84 has the following duplicate keys in its Additional sample data:
	"Group"
Warning: SUBJECT_SAMPLE_FACTORS entry #85 has the following duplicate keys in its Additional sample data:
	"Group"
Warning: SUBJECT_SAMPLE_FACTORS entry #86 has the following duplicate keys in its Additional sample data:
	"Group"
Warning: SUBJECT_SAMPLE_FACTORS entry #87 has the following duplicate keys in its Additional sample data:
	"Group"
Warning: SUBJECT_SAMPLE_FACTORS entry #88 has the following duplicate keys in its Additional sample data:
	"Group"
Warning: SUBJECT_SAMPLE_FACTORS entry #89 has the following duplicate keys in its Additional sample data:
	"Group"
Warning: SUBJECT_SAMPLE_FACTORS entry #90 has the following duplicate keys in its Additional sample data:
	"Group"
Warning: SUBJECT_SAMPLE_FACTORS entry #91 has the following duplicate keys in its Additional sample data:
	"Group"
Warning: SUBJECT_SAMPLE_FACTORS entry #92 has the following duplicate keys in its Additional sample data:
	"Group"
Warning: SUBJECT_SAMPLE_FACTORS entry #93 has the following duplicate keys in its Additional sample data:
	"Group"
Warning: SUBJECT_SAMPLE_FACTORS entry #94 has the following duplicate keys in its Additional sample data:
	"Group"
Warning: SUBJECT_SAMPLE_FACTORS entry #95 has the following duplicate keys in its Additional sample data:
	"Group"
Warning: SUBJECT_SAMPLE_FACTORS entry #96 has the following duplicate keys in its Additional sample data:
	"Group"
Warning: SUBJECT_SAMPLE_FACTORS entry #97 has the following duplicate keys in its Additional sample data:
	"Group"
Warning: SUBJECT_SAMPLE_FACTORS entry #98 has the following duplicate keys in its Additional sample data:
	"Group"
Warning: SUBJECT_SAMPLE_FACTORS entry #99 has the following duplicate keys in its Additional sample data:
	"Group"
Warning: SUBJECT_SAMPLE_FACTORS entry #100 has the following duplicate keys in its Additional sample data:
	"Group"
Warning: SUBJECT_SAMPLE_FACTORS entry #101 has the following duplicate keys in its Additional sample data:
	"Group"
Warning: SUBJECT_SAMPLE_FACTORS entry #102 has the following duplicate keys in its Additional sample data:
	"Group"
Warning: SUBJECT_SAMPLE_FACTORS entry #103 has the following duplicate keys in its Additional sample data:
	"Group"
Warning: SUBJECT_SAMPLE_FACTORS entry #104 has the following duplicate keys in its Additional sample data:
	"Group"
Warning: SUBJECT_SAMPLE_FACTORS entry #105 has the following duplicate keys in its Additional sample data:
	"Group"
Warning: SUBJECT_SAMPLE_FACTORS entry #106 has the following duplicate keys in its Additional sample data:
	"Group"
Warning: SUBJECT_SAMPLE_FACTORS entry #107 has the following duplicate keys in its Additional sample data:
	"Group"
Warning: SUBJECT_SAMPLE_FACTORS entry #108 has the following duplicate keys in its Additional sample data:
	"Group"
Warning: SUBJECT_SAMPLE_FACTORS entry #109 has the following duplicate keys in its Additional sample data:
	"Group"
Warning: SUBJECT_SAMPLE_FACTORS entry #110 has the following duplicate keys in its Additional sample data:
	"Group"
Warning: SUBJECT_SAMPLE_FACTORS entry #111 has the following duplicate keys in its Additional sample data:
	"Group"
Warning: SUBJECT_SAMPLE_FACTORS entry #112 has the following duplicate keys in its Additional sample data:
	"Group"
Warning: SUBJECT_SAMPLE_FACTORS entry #113 has the following duplicate keys in its Additional sample data:
	"Group"
Warning: SUBJECT_SAMPLE_FACTORS entry #114 has the following duplicate keys in its Additional sample data:
	"Group"
Warning: SUBJECT_SAMPLE_FACTORS entry #115 has the following duplicate keys in its Additional sample data:
	"Group"
Warning: SUBJECT_SAMPLE_FACTORS entry #116 has the following duplicate keys in its Additional sample data:
	"Group"
Warning: SUBJECT_SAMPLE_FACTORS entry #117 has the following duplicate keys in its Additional sample data:
	"Group"
Warning: SUBJECT_SAMPLE_FACTORS entry #118 has the following duplicate keys in its Additional sample data:
	"Group"
Warning: SUBJECT_SAMPLE_FACTORS entry #119 has the following duplicate keys in its Additional sample data:
	"Group"
Warning: SUBJECT_SAMPLE_FACTORS entry #120 has the following duplicate keys in its Additional sample data:
	"Group"
Warning: The "quant mz" column at position 3 in the METABOLITES table, matches a standard column name, "moverz_quant". If this match was not in error, the column should be renamed to the standard name or a name that doesn't resemble the standard name.
Warning: The "mass spec" column at position 5 in the METABOLITES table, matches a standard column name, "mass_spectrum". If this match was not in error, the column should be renamed to the standard name or a name that doesn't resemble the standard name.
Warning: The "InChI Key" column at position 8 in the METABOLITES table, matches a standard column name, "inchi_key". If this match was not in error, the column should be renamed to the standard name or a name that doesn't resemble the standard name.
Warning: The "PubChem" column at position 6 in the METABOLITES table, matches a standard column name, "pubchem_id". If this match was not in error, the column should be renamed to the standard name or a name that doesn't resemble the standard name.
Warning: The "KEGG" column at position 7 in the METABOLITES table, matches a standard column name, "kegg_id". If this match was not in error, the column should be renamed to the standard name or a name that doesn't resemble the standard name.
Warning: The "BB id" column at position 4 in the METABOLITES table, matches a standard column name, "binbase_id". If this match was not in error, the column should be renamed to the standard name or a name that doesn't resemble the standard name.
Warning: The "ret.index" column at position 2 in the METABOLITES table, matches a standard column name, "retention_index". If this match was not in error, the column should be renamed to the standard name or a name that doesn't resemble the standard name.
Warning: The column "ret.index" was found in the METABOLITES table, but this column implies that another column, "retention_index_type", should also exist, and that column was not found.