Validation Log 2025-12-15 03:28:46.122413 mwtab Python Library Version: 2.0.0 Source: https://www.metabolomicsworkbench.org/rest/study/analysis_id/AN007163/mwtab/json Study ID: ST004301 Analysis ID: AN007163 File format: json Status: Contains Validation Issues Number of Issues: 9 Number of Warnings: 8 Number of Value Errors: 9 Number of Consistency Errors: 0 Number of Format Errors: 0 Issue Log: Error: The value, "40", in ["CHROMATOGRAPHY"]["COLUMN_TEMPERATURE"] should be a number or range (ex. "5-6") followed by a space with a unit (ex. "5 V") from the following list: ['°C', 'C']. Ignore this when more complicated descriptions are required. Warning: The "Molecular weight (Da)" column at position 8 in the ["MS_METABOLITE_DATA"]["Metabolites"] table, matches a standard column name, "mass". If this match was not in error, the column should be renamed to the standard name or a name that doesn't resemble the standard name. Warning: The "Class I" column at position 3 in the ["MS_METABOLITE_DATA"]["Metabolites"] table, matches a standard column name, "class". If this match was not in error, the column should be renamed to the standard name or a name that doesn't resemble the standard name. Warning: The "Class II" column at position 4 in the ["MS_METABOLITE_DATA"]["Metabolites"] table, matches a standard column name, "class". If this match was not in error, the column should be renamed to the standard name or a name that doesn't resemble the standard name. Warning: The "kegg_map" column at position 11 in the ["MS_METABOLITE_DATA"]["Metabolites"] table, matches a standard column name, "kegg_id". If this match was not in error, the column should be renamed to the standard name or a name that doesn't resemble the standard name. Warning: The "CAS" column at position 5 in the ["MS_METABOLITE_DATA"]["Metabolites"] table, matches a standard column name, "cas_number". If this match was not in error, the column should be renamed to the standard name or a name that doesn't resemble the standard name. Warning: The "Ionization model" column at position 2 in the ["MS_METABOLITE_DATA"]["Metabolites"] table, matches a standard column name, "ionization_mode". If this match was not in error, the column should be renamed to the standard name or a name that doesn't resemble the standard name. Warning: The "Ionization model" column at position 2 in the ["MS_METABOLITE_DATA"]["Metabolites"] table, matches a standard column name, "ionization_mode", and some of the values in the column do not match the expected type or format for that column. The non-matching values are: 0 [2M+H]+ 1 [M-H2O+H]+ 2 [M-H2O+H]+ 3 [M]+ 4 [M]+ 5 [M]+ 6 [M]+ 7 [M]+ 8 [M+H]+ 9 [M+H]+ 10 [M+H]+ 11 [M+H]+ 12 [M+H]+ 13 [M+H]+ 14 [M+H]+ 15 [M+H]+ 16 [M+H]+ 17 [M+H]+ 18 [M+H]+ 19 [M+H]+ 20 [M+H]+ 21 [M+H]+ 22 [M+H]+ 23 [M+H]+ 24 [M+H]+ 25 [M+H]+ 26 [M+H]+ 27 [M+H]+ 28 [M+H]+ 29 [M+H]+ 30 [M+H]+ 31 [M+H]+ 32 [M+H]+ 33 [M+H]+ 34 [M+H]+ 35 [M+H]+ 36 [M+H]+ 37 [M+H]+ 38 [M+H]+ 39 [M+H]+ 40 [M+H]+ 41 [M+H]+ 42 [M+H]+ 43 [M+H]+ 44 [M+H]+ 45 [M+H]+ 46 [M+H]+ 47 [M+H]+ 48 [M+H]+ 49 [M+H]+ 50 [M+H]+ 51 [M+H]+ 52 [M+H]+ 53 [M+H]+ 54 [M+H]+ 55 [M+H]+ 56 [M+H]+ 57 [M+H]+ 58 [M+H]+ 59 [M+H]+ 60 [M+H]+ 61 [M+H]+ 62 [M+H]+ 63 [M+H]+ 64 [M+H]+ 65 [M+H]+ 66 [M+H]+ 67 [M+H]+ 68 [M+H]+ 69 [M+H]+ 70 [M+H]+ 71 [M+H]+ 72 [M+H]+ 73 [M+H]+ 74 [M+H]+ 75 [M+H]+ 76 [M+H]+ 77 [M+H]+ 78 [M+H]+ 79 [M+H]+ 80 [M+H]+ 81 [M+H]+ 82 [M+H]+ 83 [M+H]+ 84 [M+H]+ 85 [M+H]+ 86 [M+H]+ 87 [M+H]+ 88 [M+H]+ 89 [M+H]+ 90 [M+H]+ 91 [M+H]+ 92 [M+H]+ 93 [M+H]+ 94 [M+H]+ 95 [M+H]+ 96 [M+H]+ 97 [M+H]+ 98 [M+H]+ 99 [M+H]+ 100 [M+H]+ 101 [M+H]+ 102 [M+H]+ 103 [M+H]+ 104 [M+H]+ 105 [M+H]+ 106 [M+H]+ 107 [M+H]+ 108 [M+H]+ 109 [M+H]+ 110 [M+H]+ 111 [M+H]+ 112 [M+H]+ 113 [M+H]+ 114 [M+H]+ 115 [M+H]+ 116 [M+H]+ 117 [M+H]+ 118 [M+H]+ 119 [M+H]+ 120 [M+H]+ 121 [M+H]+ 122 [M+H]+ 123 [M+H]+ 124 [M+H]+ 125 [M+H]+ 126 [M+H]+ 127 [M+H]+ 128 [M+H]+ 129 [M+H]+ 130 [M+H]+ 131 [M+H]+ 132 [M+H]+ 133 [M+H]+ 134 [M+H]+ 135 [M+H]+ 136 [M+H]+ 137 [M+H]+ 138 [M+H]+ 139 [M+H]+ 140 [M+H]+ 141 [M+H]+ 142 [M+H]+ 143 [M+H]+ 144 [M+H]+ 145 [M+H]+ 146 [M+H]+ 147 [M+H]+ 148 [M+H]+ 149 [M+H]+ 150 [M+H]+ 151 [M+H]+ 152 [M+H]+ 153 [M+H]+ 154 [M+H]+ 155 [M+H]+ 156 [M+H]+ 157 [M+H]+ 158 [M+H]+ 159 [M+H]+ 160 [M+H]+ 161 [M+H]+ 162 [M+H]+ 163 [M+H]+ 164 [M+H]+ 165 [M+H]+ 166 [M+H]+ 167 [M+H]+ 168 [M+H]+ 169 [M+H]+ 170 [M+H]+ 171 [M+H]+ 172 [M+H]+ 173 [M+H]+ 174 [M+H]+ 175 [M+H]+ 176 [M+H]+ 177 [M+H]+ 178 [M+H]+ 179 [M+H]+ 180 [M+H]+ 181 [M+H]+ 182 [M+H]+ 183 [M+H]+ 184 [M+H]+ 185 [M+H]+ 186 [M+H]+ 187 [M+H]+ 188 [M+H]+ 189 [M+H]+ 190 [M+H]+ 191 [M+H]+ 192 [M+H]+ 193 [M+H]+ 194 [M+H]+ 195 [M+H]+ 196 [M+H]+ 197 [M+H]+ 198 [M+H]+ 199 [M+H]+ 200 [M+H]+ 201 [M+H]+ 202 [M+H]+ 203 [M+H]+ 204 [M+H]+ 205 [M+H]+ 206 [M+H]+ 207 [M+H]+ 208 [M+H]+ 209 [M+H]+ 210 [M+H]+ 211 [M+H]+ 212 [M+H]+ 213 [M+H]+ 214 [M+H]+ 215 [M+H]+ 216 [M+H]+ 217 [M+H]+ 218 [M+H]+ 219 [M+H]+ 220 [M+H]+ 221 [M+H]+ 222 [M+H]+ 223 [M+H]+ 224 [M+H]+ 225 [M+H]+ 226 [M+H]+ 227 [M+H]+ 228 [M+H]+ 229 [M+H]+ 230 [M+H]+ 231 [M+H]+ 232 [M+H]+ 233 [M+H]+ 234 [M+H]+ 235 [M+H]+ 236 [M+H]+ 237 [M+H]+ 238 [M+H]+ 239 [M+H]+ 240 [M+H]+ 241 [M+H]+ 242 [M+H]+ 243 [M+H]+ 244 [M+H]+ 245 [M+H]+ 246 [M+H]+ 247 [M+H]+ 248 [M+H]+ 249 [M+H]+ 250 [M+H]+ 251 [M+H]+ 252 [M+H]+ 253 [M+H]+ 254 [M+H]+ 255 [M+H]+ 256 [M+H]+ 257 [M+H]+ 258 [M+H]+ 259 [M+H]+ 260 [M+H]+ 261 [M+H]+ 262 [M+H]+ 263 [M+H]+ 264 [M+H]+ 265 [M+H]+ 266 [M+H]+ 267 [M+H]+ 268 [M+H]+ 269 [M+H]+ 270 [M+H]+ 271 [M+H]+ 272 [M+H]+ 273 [M+H]+ 274 [M+H]+ 275 [M+H]+ 276 [M+H]+ 277 [M+H]+ 278 [M+H]+ 279 [M+H]+ 280 [M+H]+ 281 [M+H]+ 282 [M+H]+ 283 [M+H]+ 284 [M+H]+ 285 [M+H]+ 286 [M+H]+ 287 [M+H]+ 288 [M+H]+ 289 [M+H]+ 290 [M+H]+ 291 [M+H]+ 292 [M+H]+ 293 [M+H]+ 294 [M+H]+ 295 [M+H]+ 296 [M+H]+ 297 [M+H]+ 298 [M+H]+ 299 [M+H]+ 300 [M+H]+ 301 [M+H]+ 302 [M+H]+ 303 [M+H]+ 304 [M+H]+ 305 [M+H]+ 306 [M+H]+ 307 [M+H]+ 308 [M+H]+ 309 [M+H]+ 310 [M+H]+ 311 [M+H]+ 312 [M+H]+ 313 [M+H]+ 314 [M+H]+ 315 [M+H]+ 316 [M+H]+ 317 [M+H]+ 318 [M+H]+ 319 [M+H]+ 320 [M+H]+ 321 [M+H]+ 322 [M+H]+ 323 [M+H]+ 324 [M+H]+ 325 [M+H]+ 326 [M+H]+ 327 [M+H]+ 328 [M+H]+ 329 [M+H]+ 330 [M+H]+ 331 [M+H]+ 332 [M+H]+ 333 [M+H]+ 334 [M+H]+ 335 [M+H]+ 336 [M+H]+ 337 [M+H]+ 338 [M+H]+ 339 [M+H]+ 340 [M+H]+ 341 [M+H]+ 342 [M+H]+ 343 [M+H]+ 344 [M+H]+ 345 [M+H]+ 346 [M+H]+ 347 [M+H]+ 348 [M+H]+ 349 [M+H]+ 350 [M+H]+ 351 [M+H]+ 352 [M+H]+ 353 [M+H]+ 354 [M+H]+ 355 [M+H]+ 356 [M+H]+ 357 [M+H]+ 358 [M+H]+ 359 [M+H]+ 360 [M+H]+ 361 [M+H]+ 362 [M+H]+ 363 [M+H]+ 364 [M+H]+ 365 [M+H]+ 366 [M+H]+ 367 [M+H]+ 368 [M+H]+ 369 [M+H]+ 370 [M+H]+ 371 [M+H]+ 372 [M+H]+ 373 [M+H]+ 374 [M+H]+ 375 [M+H]+ 376 [M+H]+ 377 [M+H]+ 378 [M+H]+ 379 [M+H]+ 380 [M+H]+ 381 [M+H]+ 382 [M+H]+ 383 [M+H]+ 384 [M+H]+ 385 [M+H]+ 386 [M+H]+ 387 [M+H]+ 388 [M+H]+ 389 [M+H]+ 390 [M+H]+ 391 [M+H]+ 392 [M+H]+ 393 [M+H]+ 394 [M+H]+ 395 [M+H]+ 396 [M+H]+ 397 [M+H]+ 398 [M+H]+ 399 [M+H]+ 400 [M+H]+ 401 [M+H]+ 402 [M+H]+ 403 [M+H]+ 404 [M+H]+ 405 [M+H]+ 406 [M+H]+ 407 [M+H]+ 408 [M+H]+ 409 [M+H]+ 410 [M+H]+ 411 [M+H]+ 412 [M+H]+ 413 [M+H]+ 414 [M+H]+ 415 [M+H]+ 416 [M+H]+ 417 [M+H]+ 418 [M+H]+ 419 [M+H]+ 420 [M+H]+ 421 [M+H]+ 422 [M+H]+ 423 [M+H]+ 424 [M+H]+ 425 [M+H]+ 426 [M+H]+ 427 [M+H]+ 428 [M+H]+ 429 [M+H]+ 430 [M+H]+ 431 [M+H]+ 432 [M+H]+ 433 [M+H]+ 434 [M+H]+ 435 [M+H]+ 436 [M+H]+ 437 [M+H]+ 438 [M+H]+ 439 [M+H]+ 440 [M+H]+ 441 [M+H]+ 442 [M+H]+ 443 [M+H]+ 444 [M+H]+ 445 [M+H]+ 446 [M+H]+ 447 [M+H]+ 448 [M+H]+ 449 [M+H]+ 450 [M+H]+ 451 [M+H]+ 452 [M+H]+ 453 [M+H]+ 454 [M+H]+ 455 [M+H]+ 456 [M+H]+ 457 [M+H]+ 458 [M+H]+ 459 [M+H]+ 460 [M+H]+ 461 [M+H]+ 462 [M+H]+ 463 [M+H]+ 464 [M+H]+ 465 [M+H]+ 466 [M+H]+ 467 [M+H]+ 468 [M+H]+ 469 [M+H]+ 470 [M+H]+ 471 [M+H]+ 472 [M+H]+ 473 [M+H]+ 474 [M+H]+ 475 [M+H]+ 476 [M+H]+ 477 [M+H]+ 478 [M+H]+ 479 [M+H]+ 480 [M+H]+ 481 [M+H]+ 482 [M+H]+ 483 [M+H]+ 484 [M+H]+ 485 [M+H]+ 486 [M+H]+ 487 [M+H]+ 488 [M+H]+ 489 [M+H]+ 490 [M+H]+ 491 [M+H]+ 492 [M+H]+ 493 [M+H]+ 494 [M+H]+ 495 [M+H]+ 496 [M+H]+ 497 [M+H]+ 498 [M+H]+ 499 [M+H]+ 500 [M+H]+ 501 [M+H]+ 502 [M+H]+ 503 [M+H]+ 504 [M+H]+ 505 [M+H]+ 506 [M+H]+ 507 [M+H]+ 508 [M+H]+ 509 [M+H]+ 510 [M+H]+ 511 [M+H]+ 512 [M+H]+ 513 [M+H]+ 514 [M+H]+ 515 [M+H]+ 516 [M+H]+ 517 [M+H]+ 518 [M+H]+ 519 [M+H]+ 520 [M+H]+ 521 [M+H]+ 522 [M+H]+ 523 [M+H]+ 524 [M+H]+ 525 [M+H]+ 526 [M+H]+ 527 [M+H]+ 528 [M+H]+ 529 [M+H]+ 530 [M+H]+ 531 [M+H]+ 532 [M+H]+ 533 [M+H]+ 534 [M+H]+ 535 [M+H]+ 536 [M+H]+ 537 [M+H]+ 538 [M+H]+ 539 [M+H]+ 540 [M+H]+ 541 [M+H]+ 542 [M+H]+ 543 [M+H]+ 544 [M+H]+ 545 [M+H]+ 546 [M+H]+ 547 [M+H]+ 548 [M+H]+ 549 [M+H]+ 550 [M+H]+ 551 [M+H]+ 552 [M+H]+ 553 [M+H]+ 554 [M+H]+ 555 [M+H]+ 556 [M+H]+ 557 [M+H]+ 558 [M+H]+ 559 [M+H]+ 560 [M+H]+ 561 [M+H]+ 562 [M+H]+ 563 [M+H]+ 564 [M+H]+ 565 [M+H]+ 566 [M+H]+ 567 [M+H]+ 568 [M+H]+ 569 [M+H]+ 570 [M+H]+ 571 [M+H]+ 572 [M+H]+ 573 [M+H]+ 574 [M+H]+ 575 [M+H]+ 576 [M+H]+ 577 [M+H]+ 578 [M+H]+ 579 [M+H]+ 580 [M+H]+ 581 [M+H]+ 582 [M+H]+ 583 [M+H]+ 584 [M+H]+ 585 [M+H]+ 586 [M+H]+ 587 [M+H]+ 588 [M+H]+ 589 [M+H]+ 590 [M+H]+ 591 [M+H]+ 592 [M+H]+ 593 [M+H]+ 594 [M+H]+ 595 [M+H]+ 596 [M+H]+ 597 [M+H]+ 598 [M+H]+ 599 [M+H]+ 600 [M+H]+ 601 [M+H]+ 602 [M+H]+ 603 [M+H]+ 604 [M+H]+ 605 [M+H]+ 606 [M+H]+ 607 [M+H]+ 608 [M+H]+ 609 [M+H]+ 610 [M+H]+ 611 [M+H]+ 612 [M+H]+ 613 [M+H]+ 614 [M+H]+ 615 [M+H]+ 616 [M+H]+ 617 [M+H]+ 618 [M+H]+ 619 [M+H]+ 620 [M+H]+ 621 [M+H]+ 622 [M+H]+ 623 [M+H]+ 624 [M+H]+ 625 [M+H]+ 626 [M+H]+ 627 [M+H]+ 628 [M+H]+ 629 [M+H]+ 630 [M+H]+ 631 [M+H]+ 632 [M+H]+ 633 [M+H]+ 634 [M+H]+ 635 [M+H]+ 636 [M+H]+ 637 [M+H]+ 638 [M+H]+ 639 [M+H]+ 640 [M+H]+ 641 [M+H]+ 642 [M+H]+ 643 [M+H]+ 644 [M+H]+ 645 [M+H]+ 646 [M+H]+ 647 [M+H]+ 648 [M+H]+ 649 [M+H]+ 650 [M+H]+ 651 [M+H]+ 652 [M+H]+ 653 [M+H]+ 654 [M+H]+ 655 [M+H]+ 656 [M+H]+ 657 [M+H]+ 658 [M+H]+ 659 [M+H]+ 660 [M+H]+ 661 [M+H]+ 662 [M+H]+ 663 [M+H]+ 664 [M+H]+ 665 [M+H]+ 666 [M+H]+ 667 [M+H]+ 668 [M+H]+ 669 [M+H]+ 670 [M+H]+ 671 [M+H]+ 672 [M+H]+ 673 [M+H]+ 674 [M+H]+ 675 [M+H]+ 676 [M+H]+ 677 [M+H]+ 678 [M+H]+ 679 [M+H]+ 680 [M+H]+ 681 [M+H]+ 682 [M+H]+ 683 [M+H]+ 684 [M+H]+ 685 [M+H]+ 686 [M+H]+ 687 [M+H]+ 688 [M+H]+ 689 [M+H]+ 690 [M+H]+ 691 [M+H]+ 692 [M+H]+ 693 [M+H]+ 694 [M+H]+ 695 [M+H]+ 696 [M+H]+ 697 [M+H]+ 698 [M+H]+ 699 [M+H]+ 700 [M+H]+ 701 [M+H]+ 702 [M+H]+ 703 [M+H]+ 704 [M+H]+ 705 [M+H]+ 706 [M+H]+ 707 [M+H]+ 708 [M+H]+ 709 [M+H]+ 710 [M+H]+ 711 [M+H]+ 712 [M+H]+ 713 [M+H]+ 714 [M+H]+ 715 [M+H]+ 716 [M+H]+ 717 [M+H]+ 718 [M+H]+ 719 [M+H]+ 720 [M+H]+ 721 [M+H]+ 722 [M+H]+ 723 [M+H]+ 724 [M+H]+ 725 [M+H]+ 726 [M+H]+ 727 [M+H]+ 728 [M+H]+ 729 [M+H]+ 730 [M+H]+ 731 [M+H]+ 732 [M+H]+ 733 [M+H]+ 734 [M+H]+ 735 [M+H]+ 736 [M+H]+ 737 [M+H]+ 738 [M+H]+ 739 [M+H]+ 740 [M+H]+ 741 [M+H]+ 742 [M+H]+ 743 [M+H]+ 744 [M+H]+ 745 [M+H]+ 746 [M+H]+ 747 [M+H]+ 748 [M+H]+ 749 [M+H]+ 750 [M+H]+ 751 [M+H]+ 752 [M+H]+ 753 [M+H]+ 754 [M+H]+ 755 [M+H]+ 756 [M+H]+ 757 [M+H]+ 758 [M+H]+ 759 [M+H]+ 760 [M+H]+ 761 [M+H]+ 762 [M+H]+ 763 [M+H]+ 764 [M+H]+ 765 [M+H]+ 766 [M+H]+ 767 [M+H]+ 768 [M+H]+ 769 [M+H]+ 770 [M+H]+ 771 [M+H]+ 772 [M+H]+ 773 [M+H]+ 774 [M+H]+ 775 [M+H]+ 776 [M+H]+ 777 [M+H]+ 778 [M+H]+ 779 [M+H]+ 780 [M+H]+ 781 [M+H]+ 782 [M+H]+ 783 [M+H]+ 784 [M+H]+ 785 [M+H]+ 786 [M+H]+ 787 [M+H]+ 788 [M+H]+ 789 [M+H]+ 790 [M+H]+ 791 [M+H]+ 792 [M+H]+ 793 [M+H]+ 794 [M+H]+ 795 [M+H]+ 796 [M+H]+ 797 [M+H]+ 798 [M+H]+ 799 [M+H]+ 800 [M+H]+ 801 [M+H]+ 802 [M+H]+ 803 [M+H]+ 804 [M+H]+ 805 [M+H]+ 806 [M+H]+ 807 [M+H]+ 808 [M+H]+ 809 [M+H]+ 810 [M+H]+ 811 [M+H]+ 812 [M+H]+ 813 [M+H]+ 814 [M+H]+ 815 [M+H]+ 816 [M+H]+ 817 [M+H]+ 818 [M+H]+ 819 [M+H]+ 820 [M+H]+ 821 [M+H]+ 822 [M+H]+ 823 [M+H]+ 824 [M+H]+ 825 [M+H]+ 826 [M+H]+ 827 [M+H]+ 828 [M+H]+ 829 [M+H]+ 830 [M+H]+ 831 [M+H]+ 832 [M+H]+ 833 [M+H]+ 834 [M+H]+ 835 [M+H]+ 836 [M+H]+ 837 [M+H]+ 838 [M+H]+ 839 [M+H]+ 840 [M+H]+ 841 [M+H]+ 842 [M+H]+ 843 [M+H]+ 844 [M+H]+ 845 [M+H]+ 846 [M+H]+ 847 [M+H]+ 848 [M+H]+ 849 [M+H]+ 850 [M+H]+ 851 [M+H]+ 852 [M+H]+ 853 [M+H]+ 854 [M+H]+ 855 [M+H]+ 856 [M+H]+ 857 [M+H]+ 858 [M+H]+ 859 [M+H]+ 860 [M+H]+ 861 [M+H]+ 862 [M+H]+ 863 [M+H]+ 864 [M+H]+ 865 [M+H]+ 866 [M+H]+ 867 [M+H]+ 868 [M+H]+ 869 [M+H]+ 870 [M+H]+ 871 [M+H]+ 872 [M+H]+ 873 [M+H]+ 874 [M+H]+ 875 [M+H]+ 876 [M+H]+ 877 [M+H]+ 878 [M+H]+ 879 [M+H]+ 880 [M+H]+ 881 [M+H]+ 882 [M+H]+ 883 [M+H]+ 884 [M+H]+ 885 [M+H]+ 886 [M+H]+ 887 [M+H]+ 888 [M+H]+ 889 [M+H]+ 890 [M+H]+ 891 [M+H]+ 892 [M+H]+ 893 [M+H]+ 894 [M+H]+ 895 [M+H]+ 896 [M+H]+ 897 [M+H]+ 898 [M+H]+ 899 [M+H]+ 900 [M+H]+ 901 [M+H]+ 902 [M+H]+ 903 [M+H]+ 904 [M+H]+ 905 [M+H]+ 906 [M+H]+ 907 [M+Na]+ 908 [M+Na]+ 909 [M+Na]+ 910 [M+Na]+ 911 [M+Na]+ 912 [M+Na]+ 913 [M+Na]+ 914 [M+Na]+ 915 [M+Na]+ 916 [M+NH4]+ Warning: The "Ionization model" column at position 2 in the ["MS_METABOLITE_DATA"]["Metabolites"] table may have incorrect values. 90% or more of the values are the same, but 10% or less are different.