Validation Log 2025-12-15 03:28:50.888635 mwtab Python Library Version: 2.0.0 Source: https://www.metabolomicsworkbench.org/rest/study/analysis_id/AN007164/mwtab/json Study ID: ST004301 Analysis ID: AN007164 File format: json Status: Contains Validation Issues Number of Issues: 9 Number of Warnings: 8 Number of Value Errors: 9 Number of Consistency Errors: 0 Number of Format Errors: 0 Issue Log: Error: The value, "40", in ["CHROMATOGRAPHY"]["COLUMN_TEMPERATURE"] should be a number or range (ex. "5-6") followed by a space with a unit (ex. "5 V") from the following list: ['°C', 'C']. Ignore this when more complicated descriptions are required. Warning: The "Molecular weight (Da)" column at position 8 in the ["MS_METABOLITE_DATA"]["Metabolites"] table, matches a standard column name, "mass". If this match was not in error, the column should be renamed to the standard name or a name that doesn't resemble the standard name. Warning: The "Class I" column at position 3 in the ["MS_METABOLITE_DATA"]["Metabolites"] table, matches a standard column name, "class". If this match was not in error, the column should be renamed to the standard name or a name that doesn't resemble the standard name. Warning: The "Class II" column at position 4 in the ["MS_METABOLITE_DATA"]["Metabolites"] table, matches a standard column name, "class". If this match was not in error, the column should be renamed to the standard name or a name that doesn't resemble the standard name. Warning: The "kegg_map" column at position 11 in the ["MS_METABOLITE_DATA"]["Metabolites"] table, matches a standard column name, "kegg_id". If this match was not in error, the column should be renamed to the standard name or a name that doesn't resemble the standard name. Warning: The "CAS" column at position 5 in the ["MS_METABOLITE_DATA"]["Metabolites"] table, matches a standard column name, "cas_number". If this match was not in error, the column should be renamed to the standard name or a name that doesn't resemble the standard name. Warning: The "Ionization model" column at position 2 in the ["MS_METABOLITE_DATA"]["Metabolites"] table, matches a standard column name, "ionization_mode". If this match was not in error, the column should be renamed to the standard name or a name that doesn't resemble the standard name. Warning: The "Ionization model" column at position 2 in the ["MS_METABOLITE_DATA"]["Metabolites"] table, matches a standard column name, "ionization_mode", and some of the values in the column do not match the expected type or format for that column. The non-matching values are: 0 [M-H]- 1 [M-H]- 2 [M-H]- 3 [M-H]- 4 [M-H]- 5 [M-H]- 6 [M-H]- 7 [M-H]- 8 [M-H]- 9 [M-H]- 10 [M-H]- 11 [M-H]- 12 [M-H]- 13 [M-H]- 14 [M-H]- 15 [M-H]- 16 [M-H]- 17 [M-H]- 18 [M-H]- 19 [M-H]- 20 [M-H]- 21 [M-H]- 22 [M-H]- 23 [M-H]- 24 [M-H]- 25 [M-H]- 26 [M-H]- 27 [M-H]- 28 [M-H]- 29 [M-H]- 30 [M-H]- 31 [M-H]- 32 [M-H]- 33 [M-H]- 34 [M-H]- 35 [M-H]- 36 [M-H]- 37 [M-H]- 38 [M-H]- 39 [M-H]- 40 [M-H]- 41 [M-H]- 42 [M-H]- 43 [M-H]- 44 [M-H]- 45 [M-H]- 46 [M-H]- 47 [M-H]- 48 [M-H]- 49 [M-H]- 50 [M-H]- 51 [M-H]- 52 [M-H]- 53 [M-H]- 54 [M-H]- 55 [M-H]- 56 [M-H]- 57 [M-H]- 58 [M-H]- 59 [M-H]- 60 [M-H]- 61 [M-H]- 62 [M-H]- 63 [M-H]- 64 [M-H]- 65 [M-H]- 66 [M-H]- 67 [M-H]- 68 [M-H]- 69 [M-H]- 70 [M-H]- 71 [M-H]- 72 [M-H]- 73 [M-H]- 74 [M-H]- 75 [M-H]- 76 [M-H]- 77 [M-H]- 78 [M-H]- 79 [M-H]- 80 [M-H]- 81 [M-H]- 82 [M-H]- 83 [M-H]- 84 [M-H]- 85 [M-H]- 86 [M-H]- 87 [M-H]- 88 [M-H]- 89 [M-H]- 90 [M-H]- 91 [M-H]- 92 [M-H]- 93 [M-H]- 94 [M-H]- 95 [M-H]- 96 [M-H]- 97 [M-H]- 98 [M-H]- 99 [M-H]- 100 [M-H]- 101 [M-H]- 102 [M-H]- 103 [M-H]- 104 [M-H]- 105 [M-H]- 106 [M-H]- 107 [M-H]- 108 [M-H]- 109 [M-H]- 110 [M-H]- 111 [M-H]- 112 [M-H]- 113 [M-H]- 114 [M-H]- 115 [M-H]- 116 [M-H]- 117 [M-H]- 118 [M-H]- 119 [M-H]- 120 [M-H]- 121 [M-H]- 122 [M-H]- 123 [M-H]- 124 [M-H]- 125 [M-H]- 126 [M-H]- 127 [M-H]- 128 [M-H]- 129 [M-H]- 130 [M-H]- 131 [M-H]- 132 [M-H]- 133 [M-H]- 134 [M-H]- 135 [M-H]- 136 [M-H]- 137 [M-H]- 138 [M-H]- 139 [M-H]- 140 [M-H]- 141 [M-H]- 142 [M-H]- 143 [M-H]- 144 [M-H]- 145 [M-H]- 146 [M-H]- 147 [M-H]- 148 [M-H]- 149 [M-H]- 150 [M-H]- 151 [M-H]- 152 [M-H]- 153 [M-H]- 154 [M-H]- 155 [M-H]- 156 [M-H]- 157 [M-H]- 158 [M-H]- 159 [M-H]- 160 [M-H]- 161 [M-H]- 162 [M-H]- 163 [M-H]- 164 [M-H]- 165 [M-H]- 166 [M-H]- 167 [M-H]- 168 [M-H]- 169 [M-H]- 170 [M-H]- 171 [M-H]- 172 [M-H]- 173 [M-H]- 174 [M-H]- 175 [M-H]- 176 [M-H]- 177 [M-H]- 178 [M-H]- 179 [M-H]- 180 [M-H]- 181 [M-H]- 182 [M-H]- 183 [M-H]- 184 [M-H]- 185 [M-H]- 186 [M-H]- 187 [M-H]- 188 [M-H]- 189 [M-H]- 190 [M-H]- 191 [M-H]- 192 [M-H]- 193 [M-H]- 194 [M-H]- 195 [M-H]- 196 [M-H]- 197 [M-H]- 198 [M-H]- 199 [M-H]- 200 [M-H]- 201 [M-H]- 202 [M-H]- 203 [M-H]- 204 [M-H]- 205 [M-H]- 206 [M-H]- 207 [M-H]- 208 [M-H]- 209 [M-H]- 210 [M-H]- 211 [M-H]- 212 [M-H]- 213 [M-H]- 214 [M-H]- 215 [M-H]- 216 [M-H]- 217 [M-H]- 218 [M-H]- 219 [M-H]- 220 [M-H]- 221 [M-H]- 222 [M-H]- 223 [M-H]- 224 [M-H]- 225 [M-H]- 226 [M-H]- 227 [M-H]- 228 [M-H]- 229 [M-H]- 230 [M-H]- 231 [M-H]- 232 [M-H]- 233 [M-H]- 234 [M-H]- 235 [M-H]- 236 [M-H]- 237 [M-H]- 238 [M-H]- 239 [M-H]- 240 [M-H]- 241 [M-H]- 242 [M-H]- 243 [M-H]- 244 [M-H]- 245 [M-H]- 246 [M-H]- 247 [M-H]- 248 [M-H]- 249 [M-H]- 250 [M-H]- 251 [M-H]- 252 [M-H]- 253 [M-H]- 254 [M-H]- 255 [M-H]- 256 [M-H]- 257 [M-H]- 258 [M-H]- 259 [M-H]- 260 [M-H]- 261 [M-H]- 262 [M-H]- 263 [M-H]- 264 [M-H]- 265 [M-H]- 266 [M-H]- 267 [M-H]- 268 [M-H]- 269 [M-H]- 270 [M-H]- 271 [M-H]- 272 [M-H]- 273 [M-H]- 274 [M-H]- 275 [M-H]- 276 [M-H]- 277 [M-H]- 278 [M-H]- 279 [M-H]- 280 [M-H]- 281 [M-H]- 282 [M-H]- 283 [M-H]- 284 [M-H]- 285 [M-H]- 286 [M-H]- 287 [M-H]- 288 [M-H]- 289 [M-H]- 290 [M-H]- 291 [M-H]- 292 [M-H]- 293 [M-H]- 294 [M-H]- 295 [M-H]- 296 [M-H]- 297 [M-H]- 298 [M-H]- 299 [M-H]- 300 [M-H]- 301 [M-H]- 302 [M-H]- 303 [M-H]- 304 [M-H]- 305 [M-H]- 306 [M-H]- 307 [M-H]- 308 [M-H]- 309 [M-H]- 310 [M-H]- 311 [M-H]- 312 [M-H]- 313 [M-H]- 314 [M-H]- 315 [M-H]- 316 [M-H]- 317 [M-H]- 318 [M-H]- 319 [M-H]- 320 [M-H]- 321 [M-H]- 322 [M-H]- 323 [M-H]- 324 [M-H]- 325 [M-H]- 326 [M-H]- 327 [M-H]- 328 [M-H]- 329 [M-H]- 330 [M-H]- 331 [M-H]- 332 [M-H]- 333 [M-H]- 334 [M-H]- 335 [M-H]- 336 [M-H]- 337 [M-H]- 338 [M-H]- 339 [M-H]- 340 [M-H]- 341 [M-H]- 342 [M-H]- 343 [M-H]- 344 [M-H]- 345 [M-H]- 346 [M-H]- 347 [M-H]- 348 [M-H]- 349 [M-H]- 350 [M-H]- 351 [M-H]- 352 [M-H]- 353 [M-H]- 354 [M-H]- 355 [M-H]- 356 [M-H]- 357 [M-H]- 358 [M-H]- 359 [M-H]- 360 [M-H]- 361 [M-H]- 362 [M-H]- 363 [M-H]- 364 [M-H]- 365 [M-H]- 366 [M-H]- 367 [M-H]- 368 [M-H]- 369 [M-H]- 370 [M-H]- 371 [M-H]- 372 [M-H]- 373 [M-H]- 374 [M-H]- 375 [M-H]- 376 [M-H]- 377 [M-H]- 378 [M-H]- 379 [M-H]- 380 [M-H]- 381 [M-H]- 382 [M-H]- 383 [M-H]- 384 [M-H]- 385 [M-H]- 386 [M-H]- 387 [M-H]- 388 [M-H]- 389 [M-H]- 390 [M-H]- 391 [M-H]- 392 [M-H]- 393 [M-H]- 394 [M-H]- 395 [M-H]- 396 [M-H]- 397 [M-H]- 398 [M-H]- 399 [M-H]- 400 [M-H]- 401 [M-H]- 402 [M-H]- 403 [M-H]- 404 [M-H]- 405 [M-H]- 406 [M-H]- 407 [M-H]- 408 [M-H]- 409 [M-H]- 410 [M-H]- 411 [M-H]- 412 [M-H]- 413 [M-H]- 414 [M-H]- 415 [M-H]- 416 [M-H]- 417 [M-H]- 418 [M-H]- 419 [M-H]- 420 [M-H]- 421 [M-H]- 422 [M-H]- 423 [M-H]- 424 [M-H]- 425 [M-H]- 426 [M-H]- 427 [M-H]- 428 [M-H]- 429 [M-H]- 430 [M-H]- 431 [M-H]- 432 [M-H]- 433 [M-H]- 434 [M-H]- 435 [M-H]- 436 [M-H]- 437 [M-H]- 438 [M-H]- 439 [M-H]- 440 [M-H]- 441 [M-H]- 442 [M-H]- 443 [M-H]- 444 [M-H]- 445 [M-H]- 446 [M-H]- 447 [M-H]- 448 [M-H]- 449 [M-H]- 450 [M-H]- 451 [M-H]- 452 [M-H]- 453 [M-H]- 454 [M-H]- 455 [M-H]- 456 [M-H]- 457 [M-H]- 458 [M-H]- 459 [M-H]- 460 [M-H]- 461 [M-H]- 462 [M-H]- 463 [M-H]- 464 [M-H]- 465 [M-H]- 466 [M-H]- 467 [M-H]- 468 [M-H]- 469 [M-H]- 470 [M-H]- 471 [M-H]- 472 [M-H]- 473 [M-H]- 474 [M-H]- 475 [M-H]- 476 [M-H]- 477 [M-H]- 478 [M-H]- 479 [M-H]- 480 [M-H]- 481 [M-H]- 482 [M-H]- 483 [M-H]- 484 [M-H]- 485 [M-H]- 486 [M-H]- 487 [M-H]- 488 [M-H]- 489 [M-H]- 490 [M-H]- 491 [M-H]- 492 [M-H]- 493 [M-H]- 494 [M-H]- 495 [M-H]- 496 [M-H]- 497 [M-H]- 498 [M-H]- 499 [M-H]- 500 [M-H]- 501 [M-H]- 502 [M-H]- 503 [M-H]- 504 [M-H]- 505 [M-H]- 506 [M-H]- 507 [M-H]- 508 [M-H]- 509 [M-H]- 510 [M-H]- 511 [M-H]- 512 [M-H]- 513 [M-H]- 514 [M-H]- 515 [M-H]- 516 [M-H]- 517 [M-H]- 518 [M-H]- 519 [M-H]- 520 [M-H]- 521 [M-H]- 522 [M-H]- 523 [M-H]- 524 [M-H]- 525 [M-H]- 526 [M-H]- 527 [M-H]- 528 [M-H]- 529 [M-H]- 530 [M-H]- 531 [M-H]- 532 [M-H]- 533 [M-H]- 534 [M-H]- 535 [M-H]- 536 [M-H]- 537 [M-H]- 538 [M-H]- 539 [M-H]- 540 [M-H]- 541 [M-H]- 542 [M-H]- 543 [M-H]- 544 [M-H]- 545 [M-H]- 546 [M-H]- 547 [M-H]- 548 [M-H]- 549 [M-H]- 550 [M-H]- 551 [M-H]- 552 [M-H]- 553 [M-H]- 554 [M-H]- 555 [M-H]- 556 [M-H]- 557 [M-H]- 558 [M-H]- 559 [M-H]- 560 [M-H]- 561 [M-H]- 562 [M-H]- 563 [M-H]- 564 [M-H]- 565 [M-H]- 566 [M-H]- 567 [M-H]- 568 [M-H]- 569 [M-H]- 570 [M-H]- 571 [M-H]- 572 [M-H]- 573 [M-H]- 574 [M-H]- 575 [M-H]- 576 [M-H]- 577 [M-H]- 578 [M-H]- 579 [M-H]- 580 [M-H]- 581 [M-H]- 582 [M-H]- 583 [M-H]- 584 [M-H]- 585 [M-H]- 586 [M-H]- 587 [M-H]- 588 [M-H]- 589 [M-H]- 590 [M-H]- 591 [M-H]- 592 [M-H]- 593 [M-H]- 594 [M-H]- 595 [M-H]- 596 [M-H]- 597 [M-H]- 598 [M-H]- 599 [M-H]- 600 [M-H]- 601 [M-H]- 602 [M-H]- 603 [M-H]- 604 [M-H]- 605 [M-H]- 606 [M-H]- 607 [M-H]- 608 [M-H]- 609 [M-H]- 610 [M-H]- 611 [M-H]- 612 [M-H]- 613 [M-H]- 614 [M-H]- 615 [M-H]- 616 [M-H]- 617 [M-H]- 618 [M-H]- 619 [M-H]- 620 [M-H]- 621 [M-H]- 622 [M-H]- 623 [M-H]- 624 [M-H]- 625 [M-H]- 626 [M-H]- 627 [M-H]- 628 [M-H]- 629 [M-H]- 630 [M-H]- 631 [M-H]- 632 [M-H]- 633 [M-H]- 634 [M-H]- 635 [M-H]- 636 [M-H]- 637 [M-H]- 638 [M-H]- 639 [M-H]- 640 [M-H]- 641 [M-H]- 642 [M-H]- 643 [M-H]- 644 [M-H]- 645 [M-H]- 646 [M-H]- 647 [M-H]- 648 [M-H]- 649 [M-H]- 650 [M-H]- 651 [M-H]- 652 [M-H]- 653 [M-H]- 654 [M-H]- 655 [M-H]- 656 [M-H]- 657 [M-H]- 658 [M-H]- 659 [M-H]- 660 [M-H]- 661 [M-H]- 662 [M-H]- 663 [M-H]- 664 [M-H]- 665 [M-H]- 666 [M-H]- 667 [M-H]- 668 [M-H]- 669 [M-H]- 670 [M-H]- 671 [M-H]- 672 [M-H]- 673 [M-H]- 674 [M-H]- 675 [M-H]- 676 [M-H]- 677 [M-H]- 678 [M-H]- 679 [M-H]- 680 [M-H]- 681 [M-H]- 682 [M-H]- 683 [M-H]- 684 [M-H]- 685 [M-H]- 686 [M-H]- 687 [M-H]- 688 [M-H]- 689 [M-H]- 690 [M-H]- 691 [M-H]- 692 [M-H]- 693 [M-H]- 694 [M-H]- 695 [M-H]- 696 [M-H]- 697 [M-H]- 698 [M-H]- 699 [M-H]- 700 [M-H]- 701 [M-H]- 702 [M-H]- 703 [M-H]- 704 [M-H]- 705 [M-H]- 706 [M-H]- 707 [M-H]- 708 [M-H]- 709 [M-H]- 710 [M-H]- 711 [M-H]- 712 [M-H]- 713 [M-H]- 714 [M-H]- 715 [M-H]- 716 [M-H]- 717 [M-H]- 718 [M-H]- 719 [M-H]- 720 [M-H]- 721 [M-H]- 722 [M-H]- 723 [M-H]- 724 [M-H]- 725 [M-H]- 726 [M-H]- 727 [M-H]- 728 [M-H]- 729 [M-H]- 730 [M-H]- 731 [M-H]- 732 [M-H]- 733 [M-H]- 734 [M-H]- 735 [M-H]- 736 [M-H]- 737 [M-H]- 738 [M-H]- 739 [M-H]- 740 [M-H]- 741 [M-H]- 742 [M-H]- 743 [M-H]- 744 [M-H]- 745 [M-H]- 746 [M-H]- 747 [M-H]- 748 [M-H]- 749 [M-H]- 750 [M-H]- 751 [M-H]- 752 [M-H]- 753 [M-H]- 754 [M-H]- 755 [M-H]- 756 [M-H]- 757 [M-H]- 758 [M-H]- 759 [M-H]- 760 [M-H]- 761 [M-H]- 762 [M-H]- 763 [M-H]- 764 [M-H]- 765 [M-H]- 766 [M-H]- 767 [M-H]- 768 [M-H]- 769 [M-H]- 770 [M-H]- 771 [M-H]- 772 [M-H]- 773 [M-H]- 774 [M-H]- 775 [M-H]- 776 [M-H]- 777 [M-H]- 778 [M-H]- 779 [M-H]- 780 [M-H]- 781 [M-H]- 782 [M-H]- 783 [M-H]- 784 [M-H]- 785 [M-H]- 786 [M-H]- 787 [M-H]- 788 [M-H]- 789 [M-H]- 790 [M-H]- 791 [M-H]- 792 [M-H]- 793 [M-H]- 794 [M-H]- 795 [M-H]- 796 [M-H]- 797 [M-H]- 798 [M-H]- 799 [M-H]- 800 [M-H]- 801 [M-H]- 802 [M-H]- 803 [M-H]- 804 [M-H]- 805 [M-H]- 806 [M-H]- 807 [M-H]- 808 [M-H]- 809 [M-H]- 810 [M-H]- 811 [M-H]- 812 [M-H]- 813 [M-H]- 814 [M-H]- 815 [M-H]- 816 [M-H]- 817 [M-H]- 818 [M-H]- 819 [M-H]- 820 [M-H]- 821 [M-H]- 822 [M-H]- 823 [M-H]- 824 [M-H]- 825 [M-H]- 826 [M-H]- 827 [M-H]- 828 [M-H]- 829 [M-H]- 830 [M-H]- 831 [M-H]- 832 [M-H]- 833 [M-H]- 834 [M-H]- 835 [M-H]- 836 [M-H]- 837 [M-H]- 838 [M-H]- 839 [M-H]- 840 [M-H]- 841 [M-H]- 842 [M-H]- 843 [M-H]- 844 [M-H]- 845 [M-H]- 846 [M-H]- 847 [M-H]- 848 [M-H]- 849 [M-H]- 850 [M-H]- 851 [M-H]- 852 [M-H]- 853 [M-H]- 854 [M-H]- 855 [M-H]- 856 [M-H]- 857 [M-H]- 858 [M-H]- 859 [M-H]- 860 [M-H]- 861 [M-H]- 862 [M-H]- 863 [M-H]- 864 [M-H]- 865 [M-H]- 866 [M-H]- 867 [M-H]- 868 [M-H]- 869 [M-H]- 870 [M-H]- 871 [M-H]- 872 [M-H]- 873 [M-H]- 874 [M-H]- 875 [M-H]- 876 [M-H]- 877 [M-H]- 878 [M-H]- 879 [M-H]- 880 [M-H]- 881 [M-H]- 882 [M-H]- 883 [M-H]- 884 [M-H]- 885 [M-H]- 886 [M-H]- 887 [M-H]- 888 [M-H]- 889 [M-H]- 890 [M-H]- 891 [M-H]- 892 [M-H]- 893 [M-H]- 894 [M-H]- 895 [M-H]- 896 [M-H]- 897 [M-H]- 898 [M-H]- 899 [M-H]- 900 [M-H]- 901 [M-H]- 902 [M-H]- 903 [M-H]- 904 [M-H]- 905 [M-H]- 906 [M-H]- 907 [M-H]- 908 [M-H]- 909 [M-H]- 910 [M-H]- 911 [M-H]- 912 [M-H]- 913 [M-H]- 914 [M-H]- 915 [M-H]- 916 [M-H]- 917 [M-H]- 918 [M-H]- 919 [M-H]- 920 [M-H]- 921 [M-H]- 922 [M-H]- 923 [M-H]- 924 [M-H]- 925 [M-H]- 926 [M-H]- 927 [M-H]- 928 [M-H]- 929 [M-H]- 930 [M-H]- 931 [M-H]- 932 [M-H]- 933 [M-H]- 934 [M-H]- 935 [M-H]- 936 [M-H]- 937 [M-H]- 938 [M-H]- 939 [M-H]- 940 [M-H]- 941 [M-H]- 942 [M-H]- 943 [M-H]- 944 [M-H]- 945 [M-H]- 946 [M-H]- 947 [M-H]- 948 [M-H]- 949 [M-H]- 950 [M-H]- 951 [M-H]- 952 [M-H]- 953 [M-H]- 954 [M-H]- 955 [M-H]- 956 [M-H]- 957 [M-H]- 958 [M-H]- 959 [M-H]- 960 [M-H]- 961 [M-H]- 962 [M-H]- 963 [M-H]- 964 [M-H]- 965 [M-H]- 966 [M-H]- 967 [M-H]- 968 [M-H]- 969 [M-H]- 970 [M-H]- 971 [M-H]- 972 [M-H]- 973 [M-H]- 974 [M-H]- 975 [M-H]- 976 [M-H]- 977 [M-H]- 978 [M-H]- 979 [M-H]- 980 [M-H]- 981 [M-H]- 982 [M-H]- 983 [M-H]- 984 [M-H]- 985 [M-H]- 986 [M-H]- 987 [M-H]- 988 [M-H]- 989 [M-H]- 990 [M-H]- 991 [M-H]- 992 [M-H]- 993 [M-Na]- 994 [M+CH3COO]- 995 [M+CH3COO]- 996 [M+CH3COO]- 997 [M+CH3COO]- 998 [M+CH3COOH-H]- 999 [M+CH3COOH-H]- 1000 [M+CH3COOH-H]- 1001 [M+CH3COOH-H]- 1002 [M+CH3COOH-H]- 1003 [M+CH3COOH-H]- 1004 [M+CH3COOH-H]- Warning: The "Ionization model" column at position 2 in the ["MS_METABOLITE_DATA"]["Metabolites"] table may have incorrect values. 90% or more of the values are the same, but 10% or less are different.