Validation Log
2026-07-05 07:45:24.050640
mwtab Python Library Version: 2.1.1
Source:        https://www.metabolomicsworkbench.org/rest/study/analysis_id/AN007183/mwtab/txt
Study ID:      ST004314
Analysis ID:   AN007183
File format:   txt
Status: Contains Validation Issues
Number of Issues: 15

Number of Warnings: 10

Number of Value Errors: 12

Number of Consistency Errors: 2

Number of Format Errors: 0

Issue Log:
Error: The value, "Not applicable", for the subsection, "GENDER", in the "SUBJECT" section should be one of "Male", "Female", "Male, Female", "Hermaphrodite", or "N/A". Ignore this when more complicated descriptions are required.
Error: The value, "0.4 ml/min", for the subsection, "FLOW_RATE", in the "CHROMATOGRAPHY" section should be a number or range (ex. "5-6") followed by a space with a unit (ex. "5 V") from the following list: ['mL/min', 'uL/min', 'μL/min']. Ignore this when more complicated descriptions are required.
Error: The value, "40", for the subsection, "COLUMN_TEMPERATURE", in the "CHROMATOGRAPHY" section should be a number or range (ex. "5-6") followed by a space with a unit (ex. "5 V") from the following list: ['°C', 'C']. Ignore this when more complicated descriptions are required.
Error: The following metabolites in the, MS_METABOLITE_DATA table were not found in the METABOLITES table:
	"10-Formyl-7_8-dihydrofolic acid"
	"(10S_13R)-10_13-dimethyl-17-(6-methylhept-5-en-2-yl)-1_2_4_5_6_7_11_12_14_15_16_17-dodecahydrocyclopenta[a]phenanthren-3-one"
	"12_13-dihydroxyfumitremorgin C"
	"1_2-bis(Heptanoylthio)glycerophosphocholine"
	"1_2-Dihexanoyl-sn-glycero-3-phosphocholine"
	"1_2-Dioleoyl-sn-glycero-3-phosphoethanolamine"
	"1_2-Dipalmitoleoyl-sn-glycero-3-phosphocholine"
	"1_3-Dimethyluric Acid"
	"14_15-Leukotriene E4"
	"1_4-Dihydro-1-Methyl-4-Oxo-3-Pyridinecarboxamide"
	"1_5-Diaminopentane"
	"1-Fluorocyclohexadiene-cis_cis-1_2-diol"
	"1H-Indole-3-acetonitrile_ alpha-hydroxy-"
	"1-Phenyl-1_2-propanedione"
	"1-Phenyl-1_3-eicosanedione"
	"(1R_6S)-6-amino-5-oxocyclohexyl-2-ene-1-carboxylic-acid-ester"
	"2-[2-[19-Acetamido-6-(3_4-dicarboxybutanoyloxy)-16_18-dihydroxy-5_9-dimethylicosan-7-yl]oxy-2-oxoethyl]butanedioic acid"
	"2_3-Dimethoxyphenol"
	"2_4-diacetamino-2_4_6-triphenoxy-D-mannopyranose"
	"2_4-Dihydroxypteridine"
	"2_4-Dihydroxypyridine"
	"2_5-Dimethyl-2_3-dihydrofuran-3-one"
	"2_6-Diamino-5-hydroxyhexanoic acid"
	"2_6-Dimethylpyridine"
	"2_6-di-tert-butyl-1_4-benzoquinone"
	"2^-Deoxyadenosine"
	"2^-Deoxyadenosine-5^-Monophosphate"
	"2^-Deoxycytidine-5^-Diphosphate"
	"2^-Deoxycytidine-5^-Monophosphate"
	"2^-Deoxyinosine"
	"(2E_4E)-6-(2-aminophenyl)-2-hydroxy-6-oxohexa-2_4-dienoic acid"
	"2^-O-methyladenosine"
	"2^-O-Methylguanosine"
	"(2S)-2-[[(2R_3R)-3-azaniumyl-2-hydroxy-4-phenylbutanoyl]amino]-4-methylpentanoate"
	"(2S_3S)-3-methylphenylalanine"
	"(2S_3S)-butane-2_3-diol"
	"[(2S_6S_10S_12R_13S_14S_15S_16S_17R_18R_19S_22S_23S_25R)-16_17-diacetyloxy-10_12_14_23-tetrahydroxy-6_10_19-trimethyl-13-[(2R)-2-methylbutanoyl]oxy-24-oxa-4-azaheptacyclo[12.12.0.02_11.04_9.015_25.018_23.019_25]hexacosan-22-yl] (2S_3R)-2_3-dihydroxy-2-methylbutanoate"
	"(2Z_4E)-5-(1-hydroxy-2_6_6-trimethyl-4-oxocyclohex-2-en-1-yl)-3-methylpenta-2_4-dienal"
	"3_3^-Dimethoxybenzidine"
	"3_4-Dihydroxy-9_10-secoandrosta-1_3_5(10)-triene-9_17-dione"
	"3_4^-Dihydroxyflavonoid"
	"3-(4-oxo-4_5-dihydro-1H-imidazol-5-yl)propanoic acid"
	"3_6_9_12_15_18_21-Heptaoxatricosane-21_23-diol"
	"3_7-Dimethyluric Acid"
	"3_8-Dihydroxy-1-methylanthraquinone-2-carboxylic acid"
	"3alpha-3-Hydroxytirucalla-7_24-dien-21-oic acid"
	"3^-O-Methyladenosine"
	"3-Oxolanosta-7_24Z-dien-26-oic acid"
	"(3S_4S_10S_13R)-4_10_13-trimethyl-17-[(2R)-6-methylhept-5-en-2-yl]-2_3_4_5_6_7_11_12_14_15_16_17-dodecahydro-1H-cyclopenta[a]phenanthren-3-ol"
	"4-(3-Azidopropyl)cyclohexane-1_3-dione"
	"(4R_7S_7aR_12bS)-3-methyl-2_4_4a_7_7a_13-hexahydro-1H-4_12-methanobenzofuro[3_2-e]isoquinoline-7_9-diol"
	"(4R_7S_7aR_12bS)-9-methoxy-1_2_3_4_4a_7_7a_13-octahydro-4_12-methanobenzofuro[3_2-e]isoquinolin-7-ol"
	"5_10-Methylene-THF"
	"5^-Deoxy-5^-fluoroadenosine"
	"5^-Deoxy-5^-(Methylthio) Adenosine"
	"7_3^_4^-Trihydroxyflavone"
	"7-nitro-10-octyl-3-phenyl-pyrimido[4_5-b]quinoline-2_4(3H_10H)-dione"
	"(8R_10S_13S)-13-methyl-3_17-dioxo-2_6_7_8_9_11_12_14_15_16-decahydro-1H-cyclopenta[a]phenanthrene-10-carbaldehyde"
	"acetic acid [(1R_4bR_5R_8R_10S_10aS_12aS)-1-(3-furanyl)-8_10-dihydroxy-4b_7_7_10a_12a-pentamethyl-3-oxo-1_5_6_6a_8_9_10_10b_11_12-decahydronaphtho[2_1-f][2]benzopyran-5-yl] ester"
	"Adenosine 5^-Diphosphate（ADP）"
	"alpha-D-Glucopyranoside_-beta-D-fructofuranosyl"
	"alphaS-Amino-2-[[4S-amino-4-carboxybutyl]amino]-4H-imidazo[4_5-b]pyridine-4-hexanoic acid"
	"Cytidine 5^-diphosphate"
	"Cytidine 5^-Diphosphocholine"
	"(E)-3-[(5S_6R)-5_6-dihydroxycyclohexa-1_3-dienyl]acrylic acid"
	"Genistein-4^-glucuronide"
	"Guanosine 3^_5^-Cyclic Monophosphate"
	"Guanosine-5^-monophosphate"
	"Inosine 5^-monophosphate"
	"Inositol 1_3_4-trisphosphate"
	"L-Tyrosine_ 24"
	"N-[1-[4-[(2_4-dimethoxyphenyl)methyl]-5-(2-phenylethyl)-1_2_4-triazol-3-yl]-2-(1H-indol-3-yl)ethyl]pyridine-2-carboxamide"
	"N1_N8-diacetylspermidine"
	"N-[2-(Dimethylamino)ethyl]-N-methyl-4-[({4-[4-morpholin-4-yl-7-(2_2_2-trifluoroethyl)-7H-pyrrolo[2_3-d]pyrimidin-2-yl]phenyl}carbamoyl)amino]benzamide"
	"N4-(4-phenoxyphenethyl)quinazoline-4_6-diamine"
	"N6-methyl-2^-deoxyadenosine"
	"N-benzyl-1-methyl-1H-pyrazolo[3_4-d]pyrimidin-4-amine"
	"N^-Methyl-2-pyridone-5-carboxamide"
	"N_N-Dimethylarginine"
	"N_N^_N^^-Triacetyl-chitotriose"
	"trans-2-Butene-1_4-dicarboxylic Acid"
Error: The following metabolites in the METABOLITES table were not found in the MS_METABOLITE_DATA table:
	"10-Formyl-7,8-dihydrofolic acid"
	"(10S,13R)-10,13-dimethyl-17-(6-methylhept-5-en-2-yl)-1,2,4,5,6,7,11,12,14,15,16,17-dodecahydrocyclopenta[a]phenanthren-3-one"
	"12,13-dihydroxyfumitremorgin C"
	"1,2-bis(Heptanoylthio)glycerophosphocholine"
	"1,2-Dihexanoyl-sn-glycero-3-phosphocholine"
	"1,2-Dioleoyl-sn-glycero-3-phosphoethanolamine"
	"1,2-Dipalmitoleoyl-sn-glycero-3-phosphocholine"
	"1,3-Dimethyluric Acid"
	"14,15-Leukotriene E4"
	"1,4-Dihydro-1-Methyl-4-Oxo-3-Pyridinecarboxamide"
	"1,5-Diaminopentane"
	"1-Fluorocyclohexadiene-cis,cis-1,2-diol"
	"1H-Indole-3-acetonitrile, alpha-hydroxy-"
	"1-Phenyl-1,2-propanedione"
	"1-Phenyl-1,3-eicosanedione"
	"(1R,6S)-6-amino-5-oxocyclohexyl-2-ene-1-carboxylic-acid-ester"
	"2-[2-[19-Acetamido-6-(3,4-dicarboxybutanoyloxy)-16,18-dihydroxy-5,9-dimethylicosan-7-yl]oxy-2-oxoethyl]butanedioic acid"
	"2,3-Dimethoxyphenol"
	"2,4-diacetamino-2,4,6-triphenoxy-D-mannopyranose"
	"2,4-Dihydroxypteridine"
	"2,4-Dihydroxypyridine"
	"2,5-Dimethyl-2,3-dihydrofuran-3-one"
	"2,6-Diamino-5-hydroxyhexanoic acid"
	"2,6-Dimethylpyridine"
	"2,6-di-tert-butyl-1,4-benzoquinone"
	"2'-Deoxyadenosine"
	"2'-Deoxyadenosine-5'-Monophosphate"
	"2'-Deoxycytidine-5'-Diphosphate"
	"2'-Deoxycytidine-5'-Monophosphate"
	"2'-Deoxyinosine"
	"(2E,4E)-6-(2-aminophenyl)-2-hydroxy-6-oxohexa-2,4-dienoic acid"
	"2'-O-methyladenosine"
	"2'-O-Methylguanosine"
	"(2S)-2-[[(2R,3R)-3-azaniumyl-2-hydroxy-4-phenylbutanoyl]amino]-4-methylpentanoate"
	"(2S,3S)-3-methylphenylalanine"
	"(2S,3S)-butane-2,3-diol"
	"[(2S,6S,10S,12R,13S,14S,15S,16S,17R,18R,19S,22S,23S,25R)-16,17-diacetyloxy-10,12,14,23-tetrahydroxy-6,10,19-trimethyl-13-[(2R)-2-methylbutanoyl]oxy-24-oxa-4-azaheptacyclo[12.12.0.02,11.04,9.015,25.018,23.019,25]hexacosan-22-yl] (2S,3R)-2,3-dihydroxy-2-methylbutanoate"
	"(2Z,4E)-5-(1-hydroxy-2,6,6-trimethyl-4-oxocyclohex-2-en-1-yl)-3-methylpenta-2,4-dienal"
	"3,3'-Dimethoxybenzidine"
	"3,4-Dihydroxy-9,10-secoandrosta-1,3,5(10)-triene-9,17-dione"
	"3,4'-Dihydroxyflavonoid"
	"3-(4-oxo-4,5-dihydro-1H-imidazol-5-yl)propanoic acid"
	"3,6,9,12,15,18,21-Heptaoxatricosane-21,23-diol"
	"3,7-Dimethyluric Acid"
	"3,8-Dihydroxy-1-methylanthraquinone-2-carboxylic acid"
	"3alpha-3-Hydroxytirucalla-7,24-dien-21-oic acid"
	"3'-O-Methyladenosine"
	"3-Oxolanosta-7,24Z-dien-26-oic acid"
	"(3S,4S,10S,13R)-4,10,13-trimethyl-17-[(2R)-6-methylhept-5-en-2-yl]-2,3,4,5,6,7,11,12,14,15,16,17-dodecahydro-1H-cyclopenta[a]phenanthren-3-ol"
	"4-(3-Azidopropyl)cyclohexane-1,3-dione"
	"(4R,7S,7aR,12bS)-3-methyl-2,4,4a,7,7a,13-hexahydro-1H-4,12-methanobenzofuro[3,2-e]isoquinoline-7,9-diol"
	"(4R,7S,7aR,12bS)-9-methoxy-1,2,3,4,4a,7,7a,13-octahydro-4,12-methanobenzofuro[3,2-e]isoquinolin-7-ol"
	"5,10-Methylene-THF"
	"5'-Deoxy-5'-fluoroadenosine"
	"5'-Deoxy-5'-(Methylthio) Adenosine"
	"7,3',4'-Trihydroxyflavone"
	"7-nitro-10-octyl-3-phenyl-pyrimido[4,5-b]quinoline-2,4(3H,10H)-dione"
	"(8R,10S,13S)-13-methyl-3,17-dioxo-2,6,7,8,9,11,12,14,15,16-decahydro-1H-cyclopenta[a]phenanthrene-10-carbaldehyde"
	"acetic acid [(1R,4bR,5R,8R,10S,10aS,12aS)-1-(3-furanyl)-8,10-dihydroxy-4b,7,7,10a,12a-pentamethyl-3-oxo-1,5,6,6a,8,9,10,10b,11,12-decahydronaphtho[2,1-f][2]benzopyran-5-yl] ester"
	"Adenosine 5'-Diphosphate（ADP）"
	"alpha-D-Glucopyranoside,-beta-D-fructofuranosyl"
	"alphaS-Amino-2-[[4S-amino-4-carboxybutyl]amino]-4H-imidazo[4,5-b]pyridine-4-hexanoic acid"
	"Cytidine 5'-diphosphate"
	"Cytidine 5'-Diphosphocholine"
	"(E)-3-[(5S,6R)-5,6-dihydroxycyclohexa-1,3-dienyl]acrylic acid"
	"Genistein-4'-glucuronide"
	"Guanosine 3',5'-Cyclic Monophosphate"
	"Guanosine-5'-monophosphate"
	"Inosine 5'-monophosphate"
	"Inositol 1,3,4-trisphosphate"
	"L-Tyrosine, 24"
	"N-[1-[4-[(2,4-dimethoxyphenyl)methyl]-5-(2-phenylethyl)-1,2,4-triazol-3-yl]-2-(1H-indol-3-yl)ethyl]pyridine-2-carboxamide"
	"N1,N8-diacetylspermidine"
	"N-[2-(Dimethylamino)ethyl]-N-methyl-4-[({4-[4-morpholin-4-yl-7-(2,2,2-trifluoroethyl)-7H-pyrrolo[2,3-d]pyrimidin-2-yl]phenyl}carbamoyl)amino]benzamide"
	"N4-(4-phenoxyphenethyl)quinazoline-4,6-diamine"
	"N6-methyl-2'-deoxyadenosine"
	"N-benzyl-1-methyl-1H-pyrazolo[3,4-d]pyrimidin-4-amine"
	"N'-Methyl-2-pyridone-5-carboxamide"
	"N,N-Dimethylarginine"
	"N,N',N''-Triacetyl-chitotriose"
	"trans-2-Butene-1,4-dicarboxylic Acid"
Warning: The "ri" column at position 7 in the METABOLITES table, matches a standard column name, "retention_index". If this match was not in error, the column should be renamed to the standard name or a name that doesn't resemble the standard name.
Warning: The "ri_type" column at position 8 in the METABOLITES table, matches a standard column name, "retention_index_type". If this match was not in error, the column should be renamed to the standard name or a name that doesn't resemble the standard name.
Warning: The standard column, "other_id", was found in the METABOLITES table as "other_id". If this column contains database IDs for standard databases such as KEGG, PubChem, HMDB, etc., it is recommended to make individual columns for these and not lump them together into a less descriptive "other_id" column.
Warning: The "inchi_key" column at position 3 in the METABOLITES table has all null values.
Warning: The "kegg_id" column at position 4 in the METABOLITES table has all null values.
Warning: The "other_id" column at position 5 in the METABOLITES table has all null values.
Warning: The "other_id_type" column at position 6 in the METABOLITES table has all null values.
Warning: The "ri" column at position 7 in the METABOLITES table has all null values.
Warning: The "ri_type" column at position 8 in the METABOLITES table has all null values.
Warning: The "moverz_quant" column at position 9 in the METABOLITES table has all null values.