Validation Log 2025-12-15 03:29:23.056193 mwtab Python Library Version: 2.0.0 Source: https://www.metabolomicsworkbench.org/rest/study/analysis_id/AN007185/mwtab/txt Study ID: ST004315 Analysis ID: AN007185 File format: txt Status: Contains Validation Issues Number of Issues: 16 Number of Warnings: 7 Number of Value Errors: 16 Number of Consistency Errors: 0 Number of Format Errors: 0 Issue Log: Error: An empty value or a null value was detected for the subsection, "GENOTYPE_STRAIN", in the "SUBJECT" section. Either a legitimate value should be provided for this subsection, or it should be removed altogether. Error: The value, "4w-28w", for the subsection, "AGE_OR_AGE_RANGE", in the "SUBJECT" section should be a number or range (ex. "5-6") followed by a space with a unit (ex. "5 V") from the following list: ['weeks', 'days', 'months', 'years']. Ignore this when more complicated descriptions are required. Error: An empty value or a null value was detected for the subsection, "INSTRUMENT_NAME", in the "CHROMATOGRAPHY" section. A legitimate value should be provided for this required subsection. Error: An empty value or a null value was detected for the subsection, "COLUMN_NAME", in the "CHROMATOGRAPHY" section. A legitimate value should be provided for this required subsection. Error: An empty value or a null value was detected for the subsection, "FLOW_GRADIENT", in the "CHROMATOGRAPHY" section. A legitimate value should be provided for this required subsection. Error: The value, "none", for the subsection, "FLOW_RATE", in the "CHROMATOGRAPHY" section should be a number or range (ex. "5-6") followed by a space with a unit (ex. "5 V") from the following list: ['mL/min', 'uL/min', 'μL/min']. Ignore this when more complicated descriptions are required. Error: The value, "none", for the subsection, "COLUMN_TEMPERATURE", in the "CHROMATOGRAPHY" section should be a number or range (ex. "5-6") followed by a space with a unit (ex. "5 V") from the following list: ['°C', 'C']. Ignore this when more complicated descriptions are required. Error: An empty value or a null value was detected for the subsection, "SOLVENT_A", in the "CHROMATOGRAPHY" section. A legitimate value should be provided for this required subsection. Error: An empty value or a null value was detected for the subsection, "SOLVENT_B", in the "CHROMATOGRAPHY" section. A legitimate value should be provided for this required subsection. Warning: The "neutral_mass" column at position 3 in the METABOLITES table, matches a standard column name, "mass". If this match was not in error, the column should be renamed to the standard name or a name that doesn't resemble the standard name. Warning: The "formula" column at position 2 in the METABOLITES table, matches a standard column name, "formula", and some of the values in the column do not match the expected type or format for that column. The non-matching values are: 7 C10H17NO6/C12H23NO5 8 C11H19NO6/C11H19NO6 12 C13H21NO6/C15H27NO5 13 C13H23NO6/C15H29NO5 20 C15H27NO6/C17H33NO5 23 C17H31NO6/C19H37NO5 27 C19H33NO6/C21H39NO5 28 C19H35NO6/C21H41NO5 32 C21H37NO6/C23H43NO5 33 C21H39NO6/C23H45NO5 37 C23H39NO6/C25H45NO5 38 C23H41NO6/C25H47NO5 39 C23H43NO6/C25H49NO5 42 C25H45NO6/C27H51NO5 43 C25H47NO6/C27H53NO5 Warning: The "Pubchem CID" column at position 5 in the METABOLITES table, matches a standard column name, "pubchem_id". If this match was not in error, the column should be renamed to the standard name or a name that doesn't resemble the standard name. Warning: The "Pubchem CID" column at position 5 in the METABOLITES table, matches a standard column name, "pubchem_id", and some of the values in the column do not match the expected type or format for that column. The non-matching values are: 7 22833583/NA 13 71296139/NA 20 71752223/NA 28 145720503/NA 33 145720507/NA 43 145720513/NA Warning: The "KEGG ID" column at position 4 in the METABOLITES table, matches a standard column name, "kegg_id". If this match was not in error, the column should be renamed to the standard name or a name that doesn't resemble the standard name. Warning: The "HMDB ID" column at position 6 in the METABOLITES table, matches a standard column name, "hmdb_id". If this match was not in error, the column should be renamed to the standard name or a name that doesn't resemble the standard name. Warning: The "HMDB ID" column at position 6 in the METABOLITES table, matches a standard column name, "hmdb_id", and some of the values in the column do not match the expected type or format for that column. The non-matching values are: 7 HMDB0002095/NA 13 HMDB0061677/NA 28 HMDB0013327/NA