Validation Log 2025-12-15 03:21:45.300454 mwtab Python Library Version: 2.0.0 Source: https://www.metabolomicsworkbench.org/rest/study/analysis_id/AN007232/mwtab/txt Study ID: ST004186 Analysis ID: AN007232 File format: txt Status: Contains Validation Issues Number of Issues: 100 Number of Warnings: 97 Number of Value Errors: 99 Number of Consistency Errors: 0 Number of Format Errors: 1 Issue Log: Error: An empty value or a null value was detected for the subsection, "MS_COMMENTS", in the "MS" section. Either a legitimate value should be provided for this subsection, or it should be removed altogether. Error: The value, "50", for the subsection, "COLUMN_TEMPERATURE", in the "CHROMATOGRAPHY" section should be a number or range (ex. "5-6") followed by a space with a unit (ex. "5 V") from the following list: ['°C', 'C']. Ignore this when more complicated descriptions are required. Error: Unknown or invalid section, "FACTORS". Warning: SUBJECT_SAMPLE_FACTORS entry #1 has the following duplicate keys in its Additional sample data: "RAW_FILE_NAME" Warning: SUBJECT_SAMPLE_FACTORS entry #2 has the following duplicate keys in its Additional sample data: "RAW_FILE_NAME" Warning: SUBJECT_SAMPLE_FACTORS entry #3 has the following duplicate keys in its Additional sample data: "RAW_FILE_NAME" Warning: SUBJECT_SAMPLE_FACTORS entry #4 has the following duplicate keys in its Additional sample data: "RAW_FILE_NAME" Warning: SUBJECT_SAMPLE_FACTORS entry #5 has the following duplicate keys in its Additional sample data: "RAW_FILE_NAME" Warning: SUBJECT_SAMPLE_FACTORS entry #6 has the following duplicate keys in its Additional sample data: "RAW_FILE_NAME" Warning: SUBJECT_SAMPLE_FACTORS entry #7 has the following duplicate keys in its Additional sample data: "RAW_FILE_NAME" Warning: SUBJECT_SAMPLE_FACTORS entry #8 has the following duplicate keys in its Additional sample data: "RAW_FILE_NAME" Warning: SUBJECT_SAMPLE_FACTORS entry #9 has the following duplicate keys in its Additional sample data: "RAW_FILE_NAME" Warning: SUBJECT_SAMPLE_FACTORS entry #10 has the following duplicate keys in its Additional sample data: "RAW_FILE_NAME" Warning: SUBJECT_SAMPLE_FACTORS entry #11 has the following duplicate keys in its Additional sample data: "RAW_FILE_NAME" Warning: SUBJECT_SAMPLE_FACTORS entry #12 has the following duplicate keys in its Additional sample data: "RAW_FILE_NAME" Warning: SUBJECT_SAMPLE_FACTORS entry #13 has the following duplicate keys in its Additional sample data: "RAW_FILE_NAME" Warning: SUBJECT_SAMPLE_FACTORS entry #14 has the following duplicate keys in its Additional sample data: "RAW_FILE_NAME" Warning: SUBJECT_SAMPLE_FACTORS entry #15 has the following duplicate keys in its Additional sample data: "RAW_FILE_NAME" Warning: SUBJECT_SAMPLE_FACTORS entry #16 has the following duplicate keys in its Additional sample data: "RAW_FILE_NAME" Warning: SUBJECT_SAMPLE_FACTORS entry #17 has the following duplicate keys in its Additional sample data: "RAW_FILE_NAME" Warning: SUBJECT_SAMPLE_FACTORS entry #18 has the following duplicate keys in its Additional sample data: "RAW_FILE_NAME" Warning: SUBJECT_SAMPLE_FACTORS entry #19 has the following duplicate keys in its Additional sample data: "RAW_FILE_NAME" Warning: SUBJECT_SAMPLE_FACTORS entry #20 has the following duplicate keys in its Additional sample data: "RAW_FILE_NAME" Warning: SUBJECT_SAMPLE_FACTORS entry #21 has the following duplicate keys in its Additional sample data: "RAW_FILE_NAME" Warning: SUBJECT_SAMPLE_FACTORS entry #22 has the following duplicate keys in its Additional sample data: "RAW_FILE_NAME" Warning: SUBJECT_SAMPLE_FACTORS entry #23 has the following duplicate keys in its Additional sample data: "RAW_FILE_NAME" Warning: SUBJECT_SAMPLE_FACTORS entry #24 has the following duplicate keys in its Additional sample data: "RAW_FILE_NAME" Warning: SUBJECT_SAMPLE_FACTORS entry #25 has the following duplicate keys in its Additional sample data: "RAW_FILE_NAME" Warning: SUBJECT_SAMPLE_FACTORS entry #26 has the following duplicate keys in its Additional sample data: "RAW_FILE_NAME" Warning: SUBJECT_SAMPLE_FACTORS entry #27 has the following duplicate keys in its Additional sample data: "RAW_FILE_NAME" Warning: SUBJECT_SAMPLE_FACTORS entry #28 has the following duplicate keys in its Additional sample data: "RAW_FILE_NAME" Warning: SUBJECT_SAMPLE_FACTORS entry #29 has the following duplicate keys in its Additional sample data: "RAW_FILE_NAME" Warning: SUBJECT_SAMPLE_FACTORS entry #30 has the following duplicate keys in its Additional sample data: "RAW_FILE_NAME" Warning: SUBJECT_SAMPLE_FACTORS entry #31 has the following duplicate keys in its Additional sample data: "RAW_FILE_NAME" Warning: SUBJECT_SAMPLE_FACTORS entry #32 has the following duplicate keys in its Additional sample data: "RAW_FILE_NAME" Warning: SUBJECT_SAMPLE_FACTORS entry #33 has the following duplicate keys in its Additional sample data: "RAW_FILE_NAME" Warning: SUBJECT_SAMPLE_FACTORS entry #34 has the following duplicate keys in its Additional sample data: "RAW_FILE_NAME" Warning: SUBJECT_SAMPLE_FACTORS entry #35 has the following duplicate keys in its Additional sample data: "RAW_FILE_NAME" Warning: SUBJECT_SAMPLE_FACTORS entry #36 has the following duplicate keys in its Additional sample data: "RAW_FILE_NAME" Warning: SUBJECT_SAMPLE_FACTORS entry #37 has the following duplicate keys in its Additional sample data: "RAW_FILE_NAME" Warning: SUBJECT_SAMPLE_FACTORS entry #38 has the following duplicate keys in its Additional sample data: "RAW_FILE_NAME" Warning: SUBJECT_SAMPLE_FACTORS entry #39 has the following duplicate keys in its Additional sample data: "RAW_FILE_NAME" Warning: SUBJECT_SAMPLE_FACTORS entry #40 has the following duplicate keys in its Additional sample data: "RAW_FILE_NAME" Warning: SUBJECT_SAMPLE_FACTORS entry #41 has the following duplicate keys in its Additional sample data: "RAW_FILE_NAME" Warning: SUBJECT_SAMPLE_FACTORS entry #42 has the following duplicate keys in its Additional sample data: "RAW_FILE_NAME" Warning: SUBJECT_SAMPLE_FACTORS entry #43 has the following duplicate keys in its Additional sample data: "RAW_FILE_NAME" Warning: SUBJECT_SAMPLE_FACTORS entry #44 has the following duplicate keys in its Additional sample data: "RAW_FILE_NAME" Warning: SUBJECT_SAMPLE_FACTORS entry #45 has the following duplicate keys in its Additional sample data: "RAW_FILE_NAME" Warning: SUBJECT_SAMPLE_FACTORS entry #46 has the following duplicate keys in its Additional sample data: "RAW_FILE_NAME" Warning: SUBJECT_SAMPLE_FACTORS entry #47 has the following duplicate keys in its Additional sample data: "RAW_FILE_NAME" Warning: SUBJECT_SAMPLE_FACTORS entry #48 has the following duplicate keys in its Additional sample data: "RAW_FILE_NAME" Warning: SUBJECT_SAMPLE_FACTORS entry #49 has the following duplicate keys in its Additional sample data: "RAW_FILE_NAME" Warning: SUBJECT_SAMPLE_FACTORS entry #50 has the following duplicate keys in its Additional sample data: "RAW_FILE_NAME" Warning: SUBJECT_SAMPLE_FACTORS entry #51 has the following duplicate keys in its Additional sample data: "RAW_FILE_NAME" Warning: SUBJECT_SAMPLE_FACTORS entry #52 has the following duplicate keys in its Additional sample data: "RAW_FILE_NAME" Warning: SUBJECT_SAMPLE_FACTORS entry #53 has the following duplicate keys in its Additional sample data: "RAW_FILE_NAME" Warning: SUBJECT_SAMPLE_FACTORS entry #54 has the following duplicate keys in its Additional sample data: "RAW_FILE_NAME" Warning: SUBJECT_SAMPLE_FACTORS entry #55 has the following duplicate keys in its Additional sample data: "RAW_FILE_NAME" Warning: SUBJECT_SAMPLE_FACTORS entry #56 has the following duplicate keys in its Additional sample data: "RAW_FILE_NAME" Warning: SUBJECT_SAMPLE_FACTORS entry #57 has the following duplicate keys in its Additional sample data: "RAW_FILE_NAME" Warning: SUBJECT_SAMPLE_FACTORS entry #58 has the following duplicate keys in its Additional sample data: "RAW_FILE_NAME" Warning: SUBJECT_SAMPLE_FACTORS entry #59 has the following duplicate keys in its Additional sample data: "RAW_FILE_NAME" Warning: SUBJECT_SAMPLE_FACTORS entry #60 has the following duplicate keys in its Additional sample data: "RAW_FILE_NAME" Warning: SUBJECT_SAMPLE_FACTORS entry #61 has the following duplicate keys in its Additional sample data: "RAW_FILE_NAME" Warning: SUBJECT_SAMPLE_FACTORS entry #62 has the following duplicate keys in its Additional sample data: "RAW_FILE_NAME" Warning: SUBJECT_SAMPLE_FACTORS entry #63 has the following duplicate keys in its Additional sample data: "RAW_FILE_NAME" Warning: SUBJECT_SAMPLE_FACTORS entry #64 has the following duplicate keys in its Additional sample data: "RAW_FILE_NAME" Warning: SUBJECT_SAMPLE_FACTORS entry #65 has the following duplicate keys in its Additional sample data: "RAW_FILE_NAME" Warning: SUBJECT_SAMPLE_FACTORS entry #66 has the following duplicate keys in its Additional sample data: "RAW_FILE_NAME" Warning: SUBJECT_SAMPLE_FACTORS entry #67 has the following duplicate keys in its Additional sample data: "RAW_FILE_NAME" Warning: SUBJECT_SAMPLE_FACTORS entry #68 has the following duplicate keys in its Additional sample data: "RAW_FILE_NAME" Warning: SUBJECT_SAMPLE_FACTORS entry #69 has the following duplicate keys in its Additional sample data: "RAW_FILE_NAME" Warning: SUBJECT_SAMPLE_FACTORS entry #70 has the following duplicate keys in its Additional sample data: "RAW_FILE_NAME" Warning: SUBJECT_SAMPLE_FACTORS entry #71 has the following duplicate keys in its Additional sample data: "RAW_FILE_NAME" Warning: SUBJECT_SAMPLE_FACTORS entry #72 has the following duplicate keys in its Additional sample data: "RAW_FILE_NAME" Warning: SUBJECT_SAMPLE_FACTORS entry #73 has the following duplicate keys in its Additional sample data: "RAW_FILE_NAME" Warning: SUBJECT_SAMPLE_FACTORS entry #74 has the following duplicate keys in its Additional sample data: "RAW_FILE_NAME" Warning: SUBJECT_SAMPLE_FACTORS entry #75 has the following duplicate keys in its Additional sample data: "RAW_FILE_NAME" Warning: SUBJECT_SAMPLE_FACTORS entry #76 has the following duplicate keys in its Additional sample data: "RAW_FILE_NAME" Warning: SUBJECT_SAMPLE_FACTORS entry #77 has the following duplicate keys in its Additional sample data: "RAW_FILE_NAME" Warning: SUBJECT_SAMPLE_FACTORS entry #78 has the following duplicate keys in its Additional sample data: "RAW_FILE_NAME" Warning: SUBJECT_SAMPLE_FACTORS entry #79 has the following duplicate keys in its Additional sample data: "RAW_FILE_NAME" Warning: SUBJECT_SAMPLE_FACTORS entry #80 has the following duplicate keys in its Additional sample data: "RAW_FILE_NAME" Warning: SUBJECT_SAMPLE_FACTORS entry #81 has the following duplicate keys in its Additional sample data: "RAW_FILE_NAME" Warning: SUBJECT_SAMPLE_FACTORS entry #82 has the following duplicate keys in its Additional sample data: "RAW_FILE_NAME" Warning: SUBJECT_SAMPLE_FACTORS entry #83 has the following duplicate keys in its Additional sample data: "RAW_FILE_NAME" Warning: SUBJECT_SAMPLE_FACTORS entry #84 has the following duplicate keys in its Additional sample data: "RAW_FILE_NAME" Warning: SUBJECT_SAMPLE_FACTORS entry #85 has the following duplicate keys in its Additional sample data: "RAW_FILE_NAME" Warning: SUBJECT_SAMPLE_FACTORS entry #86 has the following duplicate keys in its Additional sample data: "RAW_FILE_NAME" Warning: SUBJECT_SAMPLE_FACTORS entry #87 has the following duplicate keys in its Additional sample data: "RAW_FILE_NAME" Warning: SUBJECT_SAMPLE_FACTORS entry #88 has the following duplicate keys in its Additional sample data: "RAW_FILE_NAME" Warning: SUBJECT_SAMPLE_FACTORS entry #89 has the following duplicate keys in its Additional sample data: "RAW_FILE_NAME" Warning: SUBJECT_SAMPLE_FACTORS entry #90 has the following duplicate keys in its Additional sample data: "RAW_FILE_NAME" Warning: SUBJECT_SAMPLE_FACTORS entry #91 has the following duplicate keys in its Additional sample data: "RAW_FILE_NAME" Warning: SUBJECT_SAMPLE_FACTORS entry #92 has the following duplicate keys in its Additional sample data: "RAW_FILE_NAME" Warning: SUBJECT_SAMPLE_FACTORS entry #93 has the following duplicate keys in its Additional sample data: "RAW_FILE_NAME" Warning: SUBJECT_SAMPLE_FACTORS entry #94 has the following duplicate keys in its Additional sample data: "RAW_FILE_NAME" Warning: SUBJECT_SAMPLE_FACTORS entry #95 has the following duplicate keys in its Additional sample data: "RAW_FILE_NAME" Warning: The "HMDB" column at position 2 in the METABOLITES table, matches a standard column name, "hmdb_id". If this match was not in error, the column should be renamed to the standard name or a name that doesn't resemble the standard name. Warning: The "HMDB" column at position 2 in the METABOLITES table, matches a standard column name, "hmdb_id", and some of the values in the column do not match the expected type or format for that column. The non-matching values are: 1 HMDB0000008+HMDB0000011 7 HMDB0000407+HMDB0000754 41 HMDB0000867+HMDB0060256 58 HMDB0000122+HMDB0000211 61 HMDB0000765+HMDB0000247 98 CHEBI133226 114 IPT-NM089 115 IPT-NM027 123 CHEBI77168 129 IPT-NM025 130 IPT-NM081 134 IPT-NM022 148 IPT-NM096 163 IPT-NM100 165 IPT-NM023 166 IPT-NM097 175 IPT-NM091 176 IPT-NM090 190 IPT-NM085 207 IPT-NM094 221 IPT-NM098 255 IPT-NM026 260 IPT-NM021 279 IPT-NM037 285 IPT-NM035 288 IPT-NM043 290 IPT-NM034 294 IPT-NM036 295 IPT-NM030 296 IPT-NM042 298 IPT-NM045 299 IPT-NM033 300 IPT-NM028 301 IPT-NM032 302 IPT-NM029 303 IPT-NM031 307 HMDB0000161+HMDB0000271 332 IPT-NM011 333 IPT-NM014 334 IPT-NM018