Validation Log
2026-01-11 07:49:35.711438
mwtab Python Library Version: 2.0.0
Source:        https://www.metabolomicsworkbench.org/rest/study/analysis_id/AN007399/mwtab/txt
Study ID:      ST004422
Analysis ID:   AN007399
File format:   txt
Status: Contains Validation Issues
Number of Issues: 10

Number of Warnings: 8

Number of Value Errors: 10

Number of Consistency Errors: 0

Number of Format Errors: 0

Issue Log:
Error: An empty value or a null value was detected for the "Sample ID" in entry 1 of the "SUBJECT_SAMPLE_FACTORS" section. A legitimate value should be provided for this required subsection.
Error: The value, "35°C", for the subsection, "COLUMN_TEMPERATURE", in the "CHROMATOGRAPHY" section should be a number or range (ex. "5-6") followed by a space with a unit (ex. "5 V") from the following list: ['°C', 'C']. Ignore this when more complicated descriptions are required.
Warning: The "Calc. MW" column at position 8 in the METABOLITES table, matches a standard column name, "mass". If this match was not in error, the column should be renamed to the standard name or a name that doesn't resemble the standard name.
Warning: The "Formula" column at position 2 in the METABOLITES table, matches a standard column name, "formula", and some of the values in the column do not match the expected type or format for that column. The non-matching values are:
11          C10 H13 N O3
13            C9 H7 N O2
14     C22 H25 Cl F N3 O
29            C8 H9 N O3
33           C7 H5 N O S
34            C7 H5 N S2
35             C2 H6 O S
38           C10 H11 N O
44             C6 H7 N O
45       C8 H10 F N O2 S
46            C7 H7 N O2
48           C12 H19 N O
50             C9 H7 N O
53           C6 H9 N O S
59             C7 H9 N O
60          C15 H17 N O3
63          C18 H23 N O4
67          C18 H33 N O4
74           C9 H13 N O2
75           C8 H13 N O2
76          C14 H21 N O4
80            C6 H11 N O
83            C5 H13 N O
88            C5 H9 N O2
89            C5 H7 N O3
90           C10 H21 N O
95            C3 H7 N O3
96           C9 H19 N O4
97           C9 H15 N O3
98          C10 H17 N O3
99          C16 H25 N O4
105          C16 H33 N O
106          C11 H17 N O
114        C5 H11 N O2 S
117          C6 H13 N O2
118          C6 H13 N O2
119          C9 H11 N O2
120          C5 H11 N O2
124         C15 H25 N O3
128          C8 H15 N O3
129         C10 H13 N O2
130         C17 H27 N O4
131           C6 H5 N O3
133            C5 H9 N O
134           C7 H13 N O
137    C15 H10 Cl F N2 O
138         C16 H17 N O3
139         C10 H15 N O3
146          C18 H35 N O
153          C6 H11 N O2
155           C5 H9 N O2
158          C8 H11 N O3
164        C45 H73 N O15
165          C27 H43 N O
166          C18 H37 N O
173          C11 H9 N O2
174           C5 H9 N O3
178           C8 H15 N O
179           C8 H13 N O
182           C8 H17 N O
184         C13 H19 N O3
186    C18 H13 Cl F N3 O
Warning: The "Annot. Source: ChemSpider Search" column at position 6 in the METABOLITES table, matches a standard column name, "chemspider_id". If this match was not in error, the column should be renamed to the standard name or a name that doesn't resemble the standard name.
Warning: The "# ChemSpider Results" column at position 11 in the METABOLITES table, matches a standard column name, "chemspider_id". If this match was not in error, the column should be renamed to the standard name or a name that doesn't resemble the standard name.
Warning: The "Annot. Source: ChemSpider Search" column at position 6 in the METABOLITES table, matches a standard column name, "chemspider_id", and some of the values in the column do not match the expected type or format for that column. The non-matching values are:
0           Full match
1        Partial match
2           Full match
3        Partial match
4           No results
5             No match
6        Partial match
7           No results
8        Partial match
9        Partial match
10       Partial match
11       Partial match
12          No results
13       Partial match
14          No results
15          Full match
16     Not the top hit
17          Full match
18          No results
19       Partial match
20          Full match
21     Not the top hit
22          No results
23          No results
24          Full match
25       Partial match
26       Partial match
27       Partial match
28          No results
29          Full match
30          Full match
31          Full match
32          Full match
33       Partial match
34          Full match
35     Not the top hit
36       Partial match
37          Full match
38          Full match
39          Full match
40       Partial match
41          Full match
42     Not the top hit
43     Not the top hit
44       Partial match
45          No results
46     Not the top hit
47       Partial match
48       Partial match
49     Not the top hit
50       Partial match
51     Not the top hit
52       Partial match
53          Full match
54          Full match
55       Partial match
56       Partial match
57     Not the top hit
58     Not the top hit
59       Partial match
60       Partial match
61     Not the top hit
62       Partial match
63       Partial match
64       Partial match
65       Partial match
66     Not the top hit
67          Full match
68          Full match
69          Full match
70       Partial match
71          Full match
72          Full match
73          Full match
74       Partial match
75          Full match
76       Partial match
77          No results
78       Partial match
79          Full match
80          Full match
81     Not the top hit
82          No results
83          No results
84     Not the top hit
85          Full match
86          Full match
87     Not the top hit
88          Full match
89          Full match
90       Partial match
91       Partial match
92          No results
93          Full match
94       Partial match
95          Full match
96          Full match
97       Partial match
98          Full match
99          Full match
100         Full match
101         Full match
102         Full match
103         Full match
104         Full match
105         Full match
106      Partial match
107      Partial match
108      Partial match
109         Full match
110         Full match
111      Partial match
112      Partial match
113         Full match
114         Full match
115         Full match
116         Full match
117    Not the top hit
118    Not the top hit
119         Full match
120         Full match
121         Full match
122         No results
123    Not the top hit
124         Full match
125      Partial match
126      Partial match
127      Partial match
128         Full match
129      Partial match
130         Full match
131      Partial match
132      Partial match
133         Full match
134      Partial match
135         No results
136      Partial match
137         Full match
138         Full match
139      Partial match
140      Partial match
141      Partial match
142      Partial match
143      Partial match
144         No results
145    Not the top hit
146      Partial match
147         Full match
148         No results
149         Full match
150         Full match
151         Full match
152         Full match
153         Full match
154         Full match
155         Full match
156      Partial match
157    Not the top hit
158         Full match
159      Partial match
160      Partial match
161      Partial match
162         Full match
163         Full match
164         Full match
165         Full match
166      Partial match
167         Full match
168      Partial match
169         Full match
170         Full match
171         Full match
172         Full match
173         Full match
174         Full match
175         Full match
176         No results
177         Full match
178         Full match
179      Partial match
180         Full match
181         Full match
182         Full match
183    Not the top hit
184      Partial match
185         Full match
186         Full match
187         Full match
188      Partial match
189      Partial match
Warning: The "mzCloud Best Match Confidence" column at position 14 in the METABOLITES table, matches a standard column name, "mzcloud_id". If this match was not in error, the column should be renamed to the standard name or a name that doesn't resemble the standard name.
Warning: The "mzCloud Best Match Confidence" column at position 14 in the METABOLITES table, matches a standard column name, "mzcloud_id", and some of the values in the column do not match the expected type or format for that column. The non-matching values are:
0      83.2
1      88.1
2      83.1
3      73.1
4      48.8
5      75.9
6      68.4
7      43.3
8       9.9
9      47.5
10     75.3
12      8.4
13     66.1
15     79.6
17     82.9
18      8.4
19     66.3
20     97.8
21     91.1
22     52.3
23     49.3
24     53.7
25     44.7
26      9.2
28     43.1
29      9.1
30     49.2
31     90.1
33     54.8
35      9.9
36     42.7
37      9.8
38     49.4
39     76.9
40     62.9
41      8.1
42     81.3
43     53.5
44      8.5
45     53.1
46     71.1
49      8.8
50     55.1
51     80.9
52     66.4
53     69.6
55     65.3
56     54.1
57     55.6
58     75.6
59     49.1
60     71.6
61     45.1
62      8.9
63     46.6
64     74.7
65     68.8
66     75.7
67     43.9
68     74.8
69     65.6
71      9.9
72      9.8
73     80.9
75      8.8
76     46.5
77     62.1
79     81.4
80     60.6
81     43.3
82      9.3
83      9.8
84     70.4
85     55.1
86     82.8
87     76.6
88      9.9
89      8.9
91      9.6
92      8.5
93      9.9
95     50.1
96     52.7
97     52.5
98     49.5
99     65.9
100    98.4
101    97.2
103    58.5
104    68.4
105    90.9
106    75.8
107    80.5
108     9.9
109     8.5
110     8.4
111    47.9
112    65.7
113    67.4
114    80.2
115    63.9
116    78.9
117     9.9
119    90.8
120     9.9
121    74.5
122    46.3
123    52.4
125    86.4
126     8.9
127    64.2
128    86.2
129    83.2
131    55.1
132     9.8
133    42.7
135    61.7
136    96.8
137     9.6
138     8.7
139    73.5
140    70.2
141    66.2
142    70.6
143    66.9
144    62.1
145    77.7
146    98.4
147     8.5
148    98.9
149    95.4
150    97.3
151    96.9
152     9.5
154     8.3
155     8.2
156     9.1
157    71.2
158    43.8
159    46.5
160    81.7
161    75.7
162    65.7
163    71.8
164    80.9
165     9.9
166    88.2
167    81.7
168     9.3
169    74.4
170    54.7
171    80.9
172    46.9
173    67.6
174     8.8
175    51.9
176    46.5
177    85.1
178     9.7
179    52.1
180    79.9
181    52.4
183    65.3
184    47.3
185    94.5
186    48.3
187    48.6
188    71.7
189    47.4
Warning: The "RT [min]" column at position 9 in the METABOLITES table, matches a standard column name, "retention_time". If this match was not in error, the column should be renamed to the standard name or a name that doesn't resemble the standard name.