Validation Log 2026-04-12 09:09:57.072910 mwtab Python Library Version: 2.0.0 Source: https://www.metabolomicsworkbench.org/rest/study/analysis_id/AN007409/mwtab/txt Study ID: ST004429 Analysis ID: AN007409 File format: txt Status: Contains Validation Issues Number of Issues: 25 Number of Warnings: 22 Number of Value Errors: 22 Number of Consistency Errors: 2 Number of Format Errors: 0 Issue Log: Error: The value, "55°C", for the subsection, "COLUMN_TEMPERATURE", in the "CHROMATOGRAPHY" section should be a number or range (ex. "5-6") followed by a space with a unit (ex. "5 V") from the following list: ['°C', 'C']. Ignore this when more complicated descriptions are required. Error: The following metabolites in the, MS_METABOLITE_DATA table were not found in the METABOLITES table: "5_15-diHETE EicoPAF" "5S_6R-diHETE" Error: The following metabolites in the METABOLITES table were not found in the MS_METABOLITE_DATA table: "5,15-diHETE EicoPAF" "5S,6R-diHETE" Warning: The "ri" column at position 7 in the METABOLITES table, matches a standard column name, "retention_index". If this match was not in error, the column should be renamed to the standard name or a name that doesn't resemble the standard name. Warning: The "ri_type" column at position 8 in the METABOLITES table, matches a standard column name, "retention_index_type". If this match was not in error, the column should be renamed to the standard name or a name that doesn't resemble the standard name. Warning: The standard column, "other_id", was found in the METABOLITES table as "other_id". If this column contains database IDs for standard databases such as KEGG, PubChem, HMDB, etc., it is recommended to make individual columns for these and not lump them together into a less descriptive "other_id" column. Warning: The "Sample002" column at position 15 in the MS_METABOLITE_DATA table has all null values. Warning: The "Sample071" column at position 22 in the MS_METABOLITE_DATA table has all null values. Warning: The "Sample042" column at position 25 in the MS_METABOLITE_DATA table has all null values. Warning: The "Sample077" column at position 31 in the MS_METABOLITE_DATA table has all null values. Warning: The "Sample078" column at position 35 in the MS_METABOLITE_DATA table has all null values. Warning: The "Sample076" column at position 43 in the MS_METABOLITE_DATA table has all null values. Warning: The "Sample039" column at position 46 in the MS_METABOLITE_DATA table has all null values. Warning: The "Sample060" column at position 66 in the MS_METABOLITE_DATA table has all null values. Warning: The "Sample087" column at position 79 in the MS_METABOLITE_DATA table has all null values. Warning: The "Sample022" column at position 97 in the MS_METABOLITE_DATA table has all null values. Warning: The "Sample080" column at position 108 in the MS_METABOLITE_DATA table has all null values. Warning: The "pubchem_id" column at position 2 in the METABOLITES table has all null values. Warning: The "inchi_key" column at position 3 in the METABOLITES table has all null values. Warning: The "kegg_id" column at position 4 in the METABOLITES table has all null values. Warning: The "other_id" column at position 5 in the METABOLITES table has all null values. Warning: The "other_id_type" column at position 6 in the METABOLITES table has all null values. Warning: The "ri" column at position 7 in the METABOLITES table has all null values. Warning: The "ri_type" column at position 8 in the METABOLITES table has all null values. Warning: The "moverz_quant" column at position 9 in the METABOLITES table has all null values.