Validation Log 2026-01-11 07:50:22.330039 mwtab Python Library Version: 2.0.0 Source: https://www.metabolomicsworkbench.org/rest/study/analysis_id/AN007436/mwtab/txt Study ID: ST004440 Analysis ID: AN007436 File format: txt Status: Contains Validation Issues Number of Issues: 21 Number of Warnings: 20 Number of Value Errors: 21 Number of Consistency Errors: 0 Number of Format Errors: 0 Issue Log: Error: The value, "45°C", for the subsection, "COLUMN_TEMPERATURE", in the "CHROMATOGRAPHY" section should be a number or range (ex. "5-6") followed by a space with a unit (ex. "5 V") from the following list: ['°C', 'C']. Ignore this when more complicated descriptions are required. Warning: SUBJECT_SAMPLE_FACTORS entry #1 has the following duplicate keys in its Additional sample data: "Injection order" Warning: SUBJECT_SAMPLE_FACTORS entry #2 has the following duplicate keys in its Additional sample data: "Injection order" Warning: SUBJECT_SAMPLE_FACTORS entry #3 has the following duplicate keys in its Additional sample data: "Injection order" Warning: SUBJECT_SAMPLE_FACTORS entry #4 has the following duplicate keys in its Additional sample data: "Injection order" Warning: SUBJECT_SAMPLE_FACTORS entry #5 has the following duplicate keys in its Additional sample data: "Injection order" Warning: SUBJECT_SAMPLE_FACTORS entry #6 has the following duplicate keys in its Additional sample data: "Injection order" Warning: SUBJECT_SAMPLE_FACTORS entry #7 has the following duplicate keys in its Additional sample data: "Injection order" Warning: SUBJECT_SAMPLE_FACTORS entry #8 has the following duplicate keys in its Additional sample data: "Injection order" Warning: SUBJECT_SAMPLE_FACTORS entry #9 has the following duplicate keys in its Additional sample data: "Injection order" Warning: SUBJECT_SAMPLE_FACTORS entry #10 has the following duplicate keys in its Additional sample data: "Injection order" Warning: SUBJECT_SAMPLE_FACTORS entry #11 has the following duplicate keys in its Additional sample data: "Injection order" Warning: SUBJECT_SAMPLE_FACTORS entry #12 has the following duplicate keys in its Additional sample data: "Injection order" Warning: SUBJECT_SAMPLE_FACTORS entry #13 has the following duplicate keys in its Additional sample data: "Injection order" Warning: SUBJECT_SAMPLE_FACTORS entry #14 has the following duplicate keys in its Additional sample data: "Injection order" Warning: SUBJECT_SAMPLE_FACTORS entry #15 has the following duplicate keys in its Additional sample data: "Injection order" Warning: SUBJECT_SAMPLE_FACTORS entry #16 has the following duplicate keys in its Additional sample data: "Injection order" Warning: The "m/z" column at position 3 in the METABOLITES table, matches a standard column name, "moverz_quant". If this match was not in error, the column should be renamed to the standard name or a name that doesn't resemble the standard name. Warning: The "KEGG" column at position 2 in the METABOLITES table, matches a standard column name, "kegg_id". If this match was not in error, the column should be renamed to the standard name or a name that doesn't resemble the standard name. Warning: The "KEGG" column at position 2 in the METABOLITES table, matches a standard column name, "kegg_id", and some of the values in the column do not match the expected type or format for that column. The non-matching values are: 91 HMDB13127 93 ac107 94 HMDB00756 95 ac109 96 HMDB05066 97 HMDB13329 99 HMDB06317 100 HMDB00848 101 HMDB06351 102 HMDB01064 103 ac124 Warning: The "RT" column at position 4 in the METABOLITES table, matches a standard column name, "retention_time". If this match was not in error, the column should be renamed to the standard name or a name that doesn't resemble the standard name.