Validation Log 2026-02-22 08:05:34.711108 mwtab Python Library Version: 2.0.0 Source: https://www.metabolomicsworkbench.org/rest/study/analysis_id/AN007630/mwtab/json Study ID: ST004541 Analysis ID: AN007630 File format: json Status: Contains Validation Issues Number of Issues: 14 Number of Warnings: 8 Number of Value Errors: 12 Number of Consistency Errors: 1 Number of Format Errors: 0 Issue Log: Error: An empty value or a null value was detected in ["CHROMATOGRAPHY"]["FLOW_GRADIENT"]. A legitimate value should be provided for this required key. Error: The value in ["CHROMATOGRAPHY"]["COLUMN_TEMPERATURE"] should be a number or range (ex. "5-6") followed by a space with a unit (ex. "5 V") from the following list: ['°C', 'C']. Ignore this when more complicated descriptions are required. Error: An empty value or a null value was detected in ["CHROMATOGRAPHY"]["SOLVENT_A"]. A legitimate value should be provided for this required key. Error: An empty value or a null value was detected in ["CHROMATOGRAPHY"]["SOLVENT_B"]. A legitimate value should be provided for this required key. Error: SUBJECT_SAMPLE_FACTORS section missing sample ID(s). The following IDs were found in the ["MS_METABOLITE_DATA"]["Data"] section but not in the SUBJECT_SAMPLE_FACTORS: "" Warning: The "Quantitated m/z" column at position 5 in the ["MS_METABOLITE_DATA"]["Metabolites"] table, matches a standard column name, "moverz_quant". If this match was not in error, the column should be renamed to the standard name or a name that doesn't resemble the standard name. Warning: The "PubChem CID" column at position 3 in the ["MS_METABOLITE_DATA"]["Metabolites"] table, matches a standard column name, "pubchem_id". If this match was not in error, the column should be renamed to the standard name or a name that doesn't resemble the standard name. Warning: The "PubChem CID" column at position 3 in the ["MS_METABOLITE_DATA"]["Metabolites"] table, matches a standard column name, "pubchem_id", and some of the values in the column do not match the expected type or format for that column. The non-matching values are: 23 C00189 24 C00140 25 C00258 26 C00116 27 C00160 Warning: The "KEGG ID" column at position 2 in the ["MS_METABOLITE_DATA"]["Metabolites"] table, matches a standard column name, "kegg_id". If this match was not in error, the column should be renamed to the standard name or a name that doesn't resemble the standard name. Warning: The "KEGG ID" column at position 2 in the ["MS_METABOLITE_DATA"]["Metabolites"] table, matches a standard column name, "kegg_id", and some of the values in the column do not match the expected type or format for that column. The non-matching values are: 1 7036277 22 8222 23 700 24 174 25 752 26 753 27 757 Warning: The "Retention index" column at position 4 in the ["MS_METABOLITE_DATA"]["Metabolites"] table, matches a standard column name, "retention_index". If this match was not in error, the column should be renamed to the standard name or a name that doesn't resemble the standard name. Warning: The column "Retention index" was found in the ["MS_METABOLITE_DATA"]["Metabolites"] table, but this column implies that another column, "retention_index_type", should also exist, and that column was not found. Error: Column(s) with no name were found in the ["MS_METABOLITE_DATA"]["Data"] table. Warning: The "" column at position 26 in the ["MS_METABOLITE_DATA"]["Data"] table has all null values.