Validation Log
2026-03-15 08:19:32.172049
mwtab Python Library Version: 2.0.0
Source:        https://www.metabolomicsworkbench.org/rest/study/analysis_id/AN007865/mwtab/txt
Study ID:      ST004658
Analysis ID:   AN007865
File format:   txt
Status: Contains Validation Issues
Number of Issues: 24

Number of Warnings: 22

Number of Value Errors: 24

Number of Consistency Errors: 0

Number of Format Errors: 0

Issue Log:
Error: The value, "30", for the subsection, "COLUMN_TEMPERATURE", in the "CHROMATOGRAPHY" section should be a number or range (ex. "5-6") followed by a space with a unit (ex. "5 V") from the following list: ['°C', 'C']. Ignore this when more complicated descriptions are required.
Error: An empty value or a null value was detected for the subsection, "SOLVENT_A", in the "CHROMATOGRAPHY" section. A legitimate value should be provided for this required subsection.
Warning: SUBJECT_SAMPLE_FACTORS entry #1 has the following duplicate keys in its Additional sample data:
	"RAW_FILE_NAME(Raw_file_name)"
	"RAW_FILE_NAME(Raw_file_name)"
	"RAW_FILE_NAME(Raw_file_name)"
Warning: SUBJECT_SAMPLE_FACTORS entry #2 has the following duplicate keys in its Additional sample data:
	"RAW_FILE_NAME(Raw_file_name)"
	"RAW_FILE_NAME(Raw_file_name)"
	"RAW_FILE_NAME(Raw_file_name)"
Warning: SUBJECT_SAMPLE_FACTORS entry #3 has the following duplicate keys in its Additional sample data:
	"RAW_FILE_NAME(Raw_file_name)"
	"RAW_FILE_NAME(Raw_file_name)"
	"RAW_FILE_NAME(Raw_file_name)"
Warning: SUBJECT_SAMPLE_FACTORS entry #4 has the following duplicate keys in its Additional sample data:
	"RAW_FILE_NAME(Raw_file_name)"
	"RAW_FILE_NAME(Raw_file_name)"
	"RAW_FILE_NAME(Raw_file_name)"
Warning: SUBJECT_SAMPLE_FACTORS entry #5 has the following duplicate keys in its Additional sample data:
	"RAW_FILE_NAME(Raw_file_name)"
	"RAW_FILE_NAME(Raw_file_name)"
	"RAW_FILE_NAME(Raw_file_name)"
Warning: SUBJECT_SAMPLE_FACTORS entry #6 has the following duplicate keys in its Additional sample data:
	"RAW_FILE_NAME(Raw_file_name)"
	"RAW_FILE_NAME(Raw_file_name)"
	"RAW_FILE_NAME(Raw_file_name)"
Warning: SUBJECT_SAMPLE_FACTORS entry #7 has the following duplicate keys in its Additional sample data:
	"RAW_FILE_NAME(Raw_file_name)"
	"RAW_FILE_NAME(Raw_file_name)"
	"RAW_FILE_NAME(Raw_file_name)"
Warning: SUBJECT_SAMPLE_FACTORS entry #8 has the following duplicate keys in its Additional sample data:
	"RAW_FILE_NAME(Raw_file_name)"
	"RAW_FILE_NAME(Raw_file_name)"
	"RAW_FILE_NAME(Raw_file_name)"
Warning: SUBJECT_SAMPLE_FACTORS entry #9 has the following duplicate keys in its Additional sample data:
	"RAW_FILE_NAME(Raw_file_name)"
	"RAW_FILE_NAME(Raw_file_name)"
	"RAW_FILE_NAME(Raw_file_name)"
Warning: SUBJECT_SAMPLE_FACTORS entry #10 has the following duplicate keys in its Additional sample data:
	"RAW_FILE_NAME(Raw_file_name)"
	"RAW_FILE_NAME(Raw_file_name)"
	"RAW_FILE_NAME(Raw_file_name)"
Warning: SUBJECT_SAMPLE_FACTORS entry #11 has the following duplicate keys in its Additional sample data:
	"RAW_FILE_NAME(Raw_file_name)"
	"RAW_FILE_NAME(Raw_file_name)"
	"RAW_FILE_NAME(Raw_file_name)"
Warning: SUBJECT_SAMPLE_FACTORS entry #12 has the following duplicate keys in its Additional sample data:
	"RAW_FILE_NAME(Raw_file_name)"
	"RAW_FILE_NAME(Raw_file_name)"
	"RAW_FILE_NAME(Raw_file_name)"
Warning: SUBJECT_SAMPLE_FACTORS entry #13 has the following duplicate keys in its Additional sample data:
	"RAW_FILE_NAME(Raw_file_name)"
	"RAW_FILE_NAME(Raw_file_name)"
	"RAW_FILE_NAME(Raw_file_name)"
Warning: SUBJECT_SAMPLE_FACTORS entry #14 has the following duplicate keys in its Additional sample data:
	"RAW_FILE_NAME(Raw_file_name)"
	"RAW_FILE_NAME(Raw_file_name)"
	"RAW_FILE_NAME(Raw_file_name)"
Warning: SUBJECT_SAMPLE_FACTORS entry #15 has the following duplicate keys in its Additional sample data:
	"RAW_FILE_NAME(Raw_file_name)"
	"RAW_FILE_NAME(Raw_file_name)"
	"RAW_FILE_NAME(Raw_file_name)"
Warning: SUBJECT_SAMPLE_FACTORS entry #16 has the following duplicate keys in its Additional sample data:
	"RAW_FILE_NAME(Raw_file_name)"
	"RAW_FILE_NAME(Raw_file_name)"
	"RAW_FILE_NAME(Raw_file_name)"
Warning: SUBJECT_SAMPLE_FACTORS entry #17 has the following duplicate keys in its Additional sample data:
	"RAW_FILE_NAME(Raw_file_name)"
	"RAW_FILE_NAME(Raw_file_name)"
	"RAW_FILE_NAME(Raw_file_name)"
Warning: SUBJECT_SAMPLE_FACTORS entry #18 has the following duplicate keys in its Additional sample data:
	"RAW_FILE_NAME(Raw_file_name)"
	"RAW_FILE_NAME(Raw_file_name)"
	"RAW_FILE_NAME(Raw_file_name)"
Warning: SUBJECT_SAMPLE_FACTORS entry #19 has the following duplicate keys in its Additional sample data:
	"RAW_FILE_NAME(Raw_file_name)"
	"RAW_FILE_NAME(Raw_file_name)"
	"RAW_FILE_NAME(Raw_file_name)"
Warning: SUBJECT_SAMPLE_FACTORS entry #20 has the following duplicate keys in its Additional sample data:
	"RAW_FILE_NAME(Raw_file_name)"
	"RAW_FILE_NAME(Raw_file_name)"
	"RAW_FILE_NAME(Raw_file_name)"
Warning: The "PubChem_CID" column at position 4 in the METABOLITES table, matches a standard column name, "pubchem_id". If this match was not in error, the column should be renamed to the standard name or a name that doesn't resemble the standard name.
Warning: The "RT (min)" column at position 3 in the METABOLITES table, matches a standard column name, "retention_time". If this match was not in error, the column should be renamed to the standard name or a name that doesn't resemble the standard name.