Validation Log 2026-09-06 14:25:09.165199 mwtab Python Library Version: 2.1.1 Source: https://www.metabolomicsworkbench.org/rest/study/analysis_id/AN008588/mwtab/json Study ID: ST005051 Analysis ID: AN008588 File format: json Status: Contains Validation Issues Number of Issues: 19 Number of Warnings: 14 Number of Value Errors: 16 Number of Consistency Errors: 2 Number of Format Errors: 0 Issue Log: Error: The value, "400 μL/min", in ["CHROMATOGRAPHY"]["FLOW_RATE"] should be a number or range (ex. "5-6") followed by a space with a unit (ex. "5 V") from the following list: ['mL/min', 'uL/min', 'μL/min']. Ignore this when more complicated descriptions are required. Error: The value, "40℃", in ["CHROMATOGRAPHY"]["COLUMN_TEMPERATURE"] should be a number or range (ex. "5-6") followed by a space with a unit (ex. "5 V") from the following list: ['°C', 'C']. Ignore this when more complicated descriptions are required. Error: The following metabolites in the, ["MS_METABOLITE_DATA"]["Data"] table were not found in the ["MS_METABOLITE_DATA"]["Metabolites"] table: "(10E_12Z)-(9S)-9-Hydroperoxyoctadeca-10_12-dienoic acid" "12_13-DHOME" "1_2_4-Trimethylbenzene" "(13E)-11a-Hydroxy-9_15-dioxoprost-13-enoic acid" "1H-Indole-2_3-dione" "2_4-Dimethylphenol" "2_5-Dihydroxybenzaldehyde" "2^_6^-Dihydroxy 4^-methoxydihydrochalcone" "2-Deoxyribose 5^-phosphate" "2^-Hydroxydihydrodaidzein" "2^-O-Methyladenosine" "(2S_3R_4E)-2-Amino-4-heptadecene-1_3-diol" "3-(3_4-Dihydroxy-5-methoxy)-2-propenoic acid" "3_4_5-Trimethoxycinnamyl alcohol" "3_4-Dihydrocoumarin" "3_4-Dihydroxybenzaldehyde" "3_4-Dihydroxyphenylacetaldehyde" "3_4-Dihydroxyphenylglycol" "3_8^-Biapigenin" "3_9-Dihydroxypterocarpan" "3alpha_6beta-Ditigloyloxytropan-7beta-ol" "4^_5_6_7-Tetramethoxyflavone" "4^_7-Isoflavandiol" "4^-Prenyloxyresveratrol" "5_6-DHET" "5_6-Dihydroxyindole" "5^-Deoxyadenosine" "5^-S-Methyl-5^-thioadenosine" "5-Tricosyl-1_3-benzenediol" "6_7_4^-Trihydroxyisoflavone" "7beta-(3-Ethyl-cis-crotonoyloxy)-1alpha-(2-methylbutyryloxy)-3_14-dehydro-Z-notonipetranone" "8_9-DiHETrE" "9_10-DHOME" "Adenosine 5^-monophosphate" "N1-(alpha-D-ribosyl)-5_6-dimethyl-benzimidazole" "N^-Formylkynurenine" "NG_NG-Dimethylarginine dihydrochloride" "N_N^-diacetylchitobiose" "N_N-Dimethyl-1_4-phenylenediamine" "N_N-Dimethylglycine" "Pseudouridine 5^-phosphate" "S-(5^-Adenosy)-L-homocysteine" Error: The following metabolites in the ["MS_METABOLITE_DATA"]["Metabolites"] table were not found in the ["MS_METABOLITE_DATA"]["Data"] table: "(10E,12Z)-(9S)-9-Hydroperoxyoctadeca-10,12-dienoic acid" "12,13-DHOME" "1,2,4-Trimethylbenzene" "(13E)-11a-Hydroxy-9,15-dioxoprost-13-enoic acid" "1H-Indole-2,3-dione" "2,4-Dimethylphenol" "2,5-Dihydroxybenzaldehyde" "2',6'-Dihydroxy 4'-methoxydihydrochalcone" "2-Deoxyribose 5'-phosphate" "2'-Hydroxydihydrodaidzein" "2'-O-Methyladenosine" "(2S,3R,4E)-2-Amino-4-heptadecene-1,3-diol" "3-(3,4-Dihydroxy-5-methoxy)-2-propenoic acid" "3,4,5-Trimethoxycinnamyl alcohol" "3,4-Dihydrocoumarin" "3,4-Dihydroxybenzaldehyde" "3,4-Dihydroxyphenylacetaldehyde" "3,4-Dihydroxyphenylglycol" "3,8'-Biapigenin" "3,9-Dihydroxypterocarpan" "3alpha,6beta-Ditigloyloxytropan-7beta-ol" "4',5,6,7-Tetramethoxyflavone" "4',7-Isoflavandiol" "4'-Prenyloxyresveratrol" "5,6-DHET" "5,6-Dihydroxyindole" "5'-Deoxyadenosine" "5'-S-Methyl-5'-thioadenosine" "5-Tricosyl-1,3-benzenediol" "6,7,4'-Trihydroxyisoflavone" "7beta-(3-Ethyl-cis-crotonoyloxy)-1alpha-(2-methylbutyryloxy)-3,14-dehydro-Z-notonipetranone" "8,9-DiHETrE" "9,10-DHOME" "Adenosine 5'-monophosphate" "N1-(alpha-D-ribosyl)-5,6-dimethyl-benzimidazole" "N'-Formylkynurenine" "NG,NG-Dimethylarginine dihydrochloride" "N,N'-diacetylchitobiose" "N,N-Dimethyl-1,4-phenylenediamine" "N,N-Dimethylglycine" "Pseudouridine 5'-phosphate" "S-(5'-Adenosy)-L-homocysteine" Warning: The "refmet_name" column at position 2 in the ["MS_METABOLITE_DATA"]["Metabolites"] table, matches a standard column name, "name". If this match was not in error, the column should be renamed to the standard name or a name that doesn't resemble the standard name. Warning: The "ri" column at position 8 in the ["MS_METABOLITE_DATA"]["Metabolites"] table, matches a standard column name, "retention_index". If this match was not in error, the column should be renamed to the standard name or a name that doesn't resemble the standard name. Warning: The "ri_type" column at position 9 in the ["MS_METABOLITE_DATA"]["Metabolites"] table, matches a standard column name, "retention_index_type". If this match was not in error, the column should be renamed to the standard name or a name that doesn't resemble the standard name. Warning: The standard column, "other_id", was found in the METABOLITES table as "other_id". If this column contains database IDs for standard databases such as KEGG, PubChem, HMDB, etc., it is recommended to make individual columns for these and not lump them together into a less descriptive "other_id" column. Error: Column(s) with no name were found in the ["MS_METABOLITE_DATA"]["Metabolites"] table. Warning: The "refmet_name" column at position 2 in the ["MS_METABOLITE_DATA"]["Metabolites"] table has all null values. Warning: The "pubchem_id" column at position 3 in the ["MS_METABOLITE_DATA"]["Metabolites"] table has all null values. Warning: The "inchi_key" column at position 4 in the ["MS_METABOLITE_DATA"]["Metabolites"] table has all null values. Warning: The "kegg_id" column at position 5 in the ["MS_METABOLITE_DATA"]["Metabolites"] table has all null values. Warning: The "other_id" column at position 6 in the ["MS_METABOLITE_DATA"]["Metabolites"] table has all null values. Warning: The "other_id_type" column at position 7 in the ["MS_METABOLITE_DATA"]["Metabolites"] table has all null values. Warning: The "ri" column at position 8 in the ["MS_METABOLITE_DATA"]["Metabolites"] table has all null values. Warning: The "ri_type" column at position 9 in the ["MS_METABOLITE_DATA"]["Metabolites"] table has all null values. Warning: The "moverz_quant" column at position 10 in the ["MS_METABOLITE_DATA"]["Metabolites"] table has all null values. Warning: The "" column at position 11 in the ["MS_METABOLITE_DATA"]["Metabolites"] table has all null values.