Validation Log 2026-11-08 08:18:59.660410 mwtab Python Library Version: 2.1.1 Source: https://www.metabolomicsworkbench.org/rest/study/analysis_id/AN009120/mwtab/txt Study ID: ST005316 Analysis ID: AN009120 File format: txt Status: Contains Validation Issues Number of Issues: 16 Number of Warnings: 12 Number of Value Errors: 12 Number of Consistency Errors: 2 Number of Format Errors: 0 Issue Log: Error: The value, "0.12mL/min", for the subsection, "FLOW_RATE", in the "CHROMATOGRAPHY" section should be a number or range (ex. "5-6") followed by a space with a unit (ex. "5 V") from the following list: ['mL/min', 'uL/min', 'μL/min']. Ignore this when more complicated descriptions are required. Error: The value, "40", for the subsection, "COLUMN_TEMPERATURE", in the "CHROMATOGRAPHY" section should be a number or range (ex. "5-6") followed by a space with a unit (ex. "5 V") from the following list: ['°C', 'C']. Ignore this when more complicated descriptions are required. Error: The following metabolites in the, MS_METABOLITE_DATA table were not found in the METABOLITES table: "1_5-anhydroglucitol" "1alpha_25-Dihydroxyvitamin D3" "24_25-Epoxycholesterol" "2^-O-methyladenosine" "3_4-dihydroxyphenylalanine" "5^-Methylthioadenosine" "Inosine 5^-monophosphate" "NG_NG-Dimethyl-L-arginine" "Quinolin-2_8-diol" Error: The following metabolites in the METABOLITES table were not found in the MS_METABOLITE_DATA table: "1,5-anhydroglucitol" "1alpha,25-Dihydroxyvitamin D3" "24,25-Epoxycholesterol" "2'-O-methyladenosine" "3,4-dihydroxyphenylalanine" "5'-Methylthioadenosine" "Inosine 5'-monophosphate" "NG,NG-Dimethyl-L-arginine" "Quinolin-2,8-diol" Warning: The "refmet_name" column at position 2 in the METABOLITES table, matches a standard column name, "name". If this match was not in error, the column should be renamed to the standard name or a name that doesn't resemble the standard name. Warning: The "ri" column at position 8 in the METABOLITES table, matches a standard column name, "retention_index". If this match was not in error, the column should be renamed to the standard name or a name that doesn't resemble the standard name. Warning: The "ri_type" column at position 9 in the METABOLITES table, matches a standard column name, "retention_index_type". If this match was not in error, the column should be renamed to the standard name or a name that doesn't resemble the standard name. Warning: The column pair, "ri" and "ri_type", in the METABOLITES table should have data in the same rows, but at least one row has data in one column and nothing in the other. Warning: The standard column, "other_id", was found in the METABOLITES table as "other_id". If this column contains database IDs for standard databases such as KEGG, PubChem, HMDB, etc., it is recommended to make individual columns for these and not lump them together into a less descriptive "other_id" column. Warning: The "pubchem_id" column at position 3 in the METABOLITES table has all null values. Warning: The "inchi_key" column at position 4 in the METABOLITES table has all null values. Warning: The "kegg_id" column at position 5 in the METABOLITES table has all null values. Warning: The "other_id" column at position 6 in the METABOLITES table has all null values. Warning: The "other_id_type" column at position 7 in the METABOLITES table has all null values. Warning: The "ri_type" column at position 9 in the METABOLITES table has all null values. Warning: The "moverz_quant" column at position 10 in the METABOLITES table has all null values.