---------------------------------------------------------------------------------------------------- S E R I E S D A T A R E C O R D ---------------------------------------------------------------------------------------------------- System Type IGA Systems System Owner EPFL System Reference G200773 System Serial Number HALIGA241 Sample Number 0328 Experiment Type Sequence Experiment No 001 Title ZIF 8 prisma Comment Source Batch ID Experiment Title Isotherm N2 20C S A M P L E S E T U P Sample Wet Weight 9.2627 mg Sample Dry Weight 8.9674 mg Sample Dry Mass 8.9674 mg Sample Weight Loss 3.29 %d.b. Balance Trim (V) 0.0024 cc Balance Trim (T) Cabinet Counterweight (M) 0.3062 g Counterweight (ρ) 7.886 g/cc Counterweight (T) Air Sample Container (M) 0.0895 g Sample Container (ρ) 7.886 g/cc Sample Container (T) Sample Tungsten (M) 0.0568 g Tungsten (ρ) 19.03976 g/cc Tungsten (T) Sample Chain Excess (M) 0.0719 g Chain Excess (ρ) 11.09856 g/cc Chain Excess (T) Air Interaction Type Adsorption Classification Not Specified Sample Geometry Not Specified Sample Dimension Not Specified Presorbed Not Specified Sample Molar Mass Not Specified Sample Skeletal Density Not Specified Absolute Adsorption Basis None Adsorbate Density Not Specified Micropore Volume Not Specified Dilation Not Specified A P P L I C A T I O N S E T U P Application Code 201510 Mode Vacuum Source Gas Cylinder Gas Source NITROGEN at supply pressure 20 barg Vessel CF-SW High Pressure Reactor Conflat SS316L Pressure Sensor(s) 20 bar Thermostat Water Bath NITROGEN EOS calculation NIST REFPROP v9.1 NITROGEN SVP calculation NIST REFPROP v9.1 Source Data C:\HIsorp\G200773\Sample_0328\Sequence\Sequence001\Data.txt Operations Log C:\HIsorp\G200773\Sample_0328\Sequence\Sequence001\Operations Log.txt Method Log C:\HIsorp\G200773\Sample_0328\Sequence\Sequence001\Method Log.txt File created 14:01:09 on 20 January 2020 by WR200774 Issue Level Recalculation Not Issued Series Type Isothermal Series Data Delimiter Space Scan 1 Course Sorption Reference State Device Sample Scan Title Scan Commenced 17:02:35 on 15 January 2020 by WR200774 Pressure Gas p/p0 Total Excess Excess BET Sample %Wt Density Weight Adsorption Adsorption (mbar) (g/cc) (mg) (%) (mmol/g) (g/ml(stp)) (°C) (% d.b.) ----------------------------------------------------------------------------------------------------- -.7 0.000000 0.00 8.9674 0.0000 0.0000 0.0000 27.03 0.000 19.9 0.000023 0.00 8.9716 0.0420 0.0150 0.0000 20.02 0.047 39.8 0.000046 0.00 8.9722 0.0431 0.0154 0.0000 20.00 0.053 60.2 0.000069 0.00 8.9729 0.0461 0.0165 0.0000 20.01 0.061 80.0 0.000092 0.00 8.9738 0.0511 0.0182 0.0000 19.98 0.071 100.1 0.000115 0.00 8.9747 0.0558 0.0199 0.0000 20.02 0.081 149.5 0.000172 0.00 8.9767 0.0655 0.0234 0.0001 20.00 0.103 199.5 0.000229 0.00 8.9788 0.0770 0.0275 0.0001 19.98 0.128 249.3 0.000287 0.00 8.9815 0.0935 0.0334 0.0001 19.96 0.157 299.9 0.000345 0.00 8.9839 0.1077 0.0385 0.0001 19.97 0.184 349.9 0.000402 0.00 8.9863 0.1215 0.0434 0.0001 20.00 0.210 399.9 0.000460 0.00 8.9886 0.1348 0.0481 0.0001 20.01 0.236 448.6 0.000516 0.00 8.9907 0.1462 0.0522 0.0001 20.02 0.260 497.1 0.000571 0.00 8.9929 0.1589 0.0567 0.0001 20.01 0.285 599.8 0.000689 0.00 8.9975 0.1837 0.0656 0.0001 19.99 0.336 699.9 0.000805 0.00 9.0019 0.2070 0.0739 0.0001 19.98 0.385 747.2 0.000859 0.00 9.0043 0.2216 0.0791 0.0001 19.98 0.411 797.4 0.000917 0.00 9.0065 0.2337 0.0834 0.0001 19.96 0.437 895.7 0.001030 0.00 9.0112 0.2602 0.0929 0.0001 19.97 0.488 994.0 0.001142 0.00 9.0166 0.2955 0.1055 0.0001 19.99 0.548 1190.9 0.001369 0.00 9.0263 0.3547 0.1266 0.0001 20.00 0.657 1383.0 0.001589 0.00 9.0362 0.4164 0.1486 0.0001 20.00 0.767 1581.7 0.001818 0.00 9.0445 0.4592 0.1639 0.0001 19.99 0.860 1781.3 0.002047 0.00 9.0525 0.4983 0.1779 0.0001 19.99 0.950 1876.4 0.002157 0.00 9.0578 0.5319 0.1899 0.0001 19.97 1.008 1969.7 0.002264 0.00 9.0627 0.5626 0.2008 0.0001 19.95 1.062 2199.5 0.002528 0.00 9.0682 0.5644 0.2015 0.0001 19.99 1.124 2399.9 0.002759 0.00 9.0765 0.6055 0.2161 0.0001 19.97 1.217 2599.5 0.002988 0.00 9.0860 0.6624 0.2365 0.0001 19.98 1.323 2765.4 0.003179 0.01 9.0971 0.7450 0.2659 0.0001 19.97 1.447 ----------------------------------------------------------------------------------------------------- Scan Ends 02:36:36 on 16 January 2020 by WR200774 Reference State 19.99°C ---------------------------------------------------------------------------------------------------- S E R I E S D A T A R E C O R D ---------------------------------------------------------------------------------------------------- System Type IGA Systems System Owner EPFL System Reference G200773 System Serial Number HALIGA241 Sample Number 0328 Experiment Type Sequence Experiment No 002 Title ZIF 8 prisma Comment Source Batch ID Experiment Title Isotherm N2 40C S A M P L E S E T U P Sample Wet Weight 9.2627 mg Sample Dry Weight 8.9698 mg Sample Dry Mass 8.9698 mg Sample Weight Loss 3.27 %d.b. Balance Trim (V) 0.0024 cc Balance Trim (T) Cabinet Counterweight (M) 0.3062 g Counterweight (ρ) 7.886 g/cc Counterweight (T) Air Sample Container (M) 0.0895 g Sample Container (ρ) 7.886 g/cc Sample Container (T) Sample Tungsten (M) 0.0568 g Tungsten (ρ) 19.03976 g/cc Tungsten (T) Sample Chain Excess (M) 0.0719 g Chain Excess (ρ) 11.09856 g/cc Chain Excess (T) Air Interaction Type Adsorption Classification Not Specified Sample Geometry Not Specified Sample Dimension Not Specified Presorbed Not Specified Sample Molar Mass Not Specified Sample Skeletal Density Not Specified Absolute Adsorption Basis None Adsorbate Density Not Specified Micropore Volume Not Specified Dilation Not Specified A P P L I C A T I O N S E T U P Application Code 201510 Mode Vacuum Source Gas Cylinder Gas Source NITROGEN at supply pressure 20 barg Vessel CF-SW High Pressure Reactor Conflat SS316L Pressure Sensor(s) 20 bar Thermostat Water Bath NITROGEN EOS calculation NIST REFPROP v9.1 NITROGEN SVP calculation NIST REFPROP v9.1 Source Data C:\HIsorp\G200773\Sample_0328\Sequence\Sequence002\Data.txt Operations Log C:\HIsorp\G200773\Sample_0328\Sequence\Sequence002\Operations Log.txt Method Log C:\HIsorp\G200773\Sample_0328\Sequence\Sequence002\Method Log.txt File created 14:01:12 on 20 January 2020 by WR200774 Issue Level Recalculation Not Issued Series Type Isothermal Series Data Delimiter Space Scan 1 Course Sorption Reference State Device Sample Scan Title Scan Commenced 09:49:34 on 16 January 2020 by WR200774 Pressure Gas p/p0 Total Excess Excess BET Sample %Wt Density Weight Adsorption Adsorption (mbar) (g/cc) (mg) (%) (mmol/g) (g/ml(stp)) (°C) (% d.b.) ----------------------------------------------------------------------------------------------------- -.9 0.000000 0.00 8.9698 0.0004 0.0002 0.0000 22.33 0.000 20.0 0.000022 0.00 8.9732 0.0326 0.0116 0.0000 39.99 0.038 39.9 0.000043 0.00 8.9740 0.0364 0.0130 0.0000 39.98 0.047 59.8 0.000064 0.00 8.9747 0.0387 0.0138 0.0000 40.03 0.055 79.8 0.000086 0.00 8.9755 0.0423 0.0151 0.0000 39.98 0.063 99.8 0.000107 0.00 8.9765 0.0486 0.0173 0.0000 40.04 0.075 149.9 0.000161 0.00 8.9789 0.0616 0.0220 0.0001 39.99 0.101 199.8 0.000215 0.00 8.9810 0.0718 0.0256 0.0001 39.97 0.125 249.8 0.000269 0.00 8.9837 0.0888 0.0317 0.0001 39.96 0.155 299.9 0.000323 0.00 8.9862 0.1037 0.0370 0.0001 40.01 0.183 349.8 0.000376 0.00 8.9884 0.1148 0.0410 0.0001 40.01 0.207 397.4 0.000428 0.00 8.9906 0.1264 0.0451 0.0001 39.99 0.231 446.9 0.000481 0.00 8.9928 0.1385 0.0495 0.0001 39.95 0.257 495.6 0.000533 0.00 8.9955 0.1548 0.0553 0.0001 39.94 0.286 595.7 0.000641 0.00 9.0013 0.1932 0.0690 0.0001 39.94 0.351 694.0 0.000747 0.00 9.0062 0.2224 0.0794 0.0001 39.99 0.406 743.0 0.000799 0.00 9.0082 0.2317 0.0827 0.0001 39.99 0.428 792.6 0.000853 0.00 9.0103 0.2417 0.0863 0.0001 39.97 0.451 891.8 0.000960 0.00 9.0155 0.2734 0.0976 0.0001 39.92 0.509 999.9 0.001076 0.00 9.0211 0.3072 0.1096 0.0001 39.89 0.572 1199.8 0.001291 0.00 9.0320 0.3761 0.1343 0.0001 39.94 0.693 1399.8 0.001506 0.00 9.0404 0.4177 0.1491 0.0001 39.98 0.787 1599.8 0.001721 0.00 9.0482 0.4518 0.1613 0.0001 40.00 0.874 1799.8 0.001937 0.00 9.0573 0.4998 0.1784 0.0001 39.93 0.976 1899.8 0.002044 0.00 9.0597 0.4988 0.1781 0.0001 39.94 1.002 1999.8 0.002152 0.00 9.0654 0.5355 0.1911 0.0001 39.98 1.065 2199.9 0.002367 0.00 9.0760 0.6025 0.2151 0.0001 39.97 1.184 2399.5 0.002581 0.00 9.0826 0.6240 0.2227 0.0001 40.04 1.257 2599.5 0.002797 0.00 9.0898 0.6513 0.2325 0.0001 39.97 1.338 2799.4 0.003013 0.00 9.0953 0.6581 0.2349 0.0001 39.88 1.399 ----------------------------------------------------------------------------------------------------- Scan Ends 19:27:07 on 16 January 2020 by WR200774 Reference State 39.97°C ---------------------------------------------------------------------------------------------------- S E R I E S D A T A R E C O R D ---------------------------------------------------------------------------------------------------- System Type IGA Systems System Owner EPFL System Reference G200773 System Serial Number HALIGA241 Sample Number 0328 Experiment Type Sequence Experiment No 003 Title ZIF 8 prisma Comment Source Batch ID Experiment Title Isotherm N2 60C S A M P L E S E T U P Sample Wet Weight 9.2627 mg Sample Dry Weight 8.9714 mg Sample Dry Mass 8.9714 mg Sample Weight Loss 3.25 %d.b. Balance Trim (V) 0.0024 cc Balance Trim (T) Cabinet Counterweight (M) 0.3062 g Counterweight (ρ) 7.886 g/cc Counterweight (T) Air Sample Container (M) 0.0895 g Sample Container (ρ) 7.886 g/cc Sample Container (T) Sample Tungsten (M) 0.0568 g Tungsten (ρ) 19.03976 g/cc Tungsten (T) Sample Chain Excess (M) 0.0719 g Chain Excess (ρ) 11.09856 g/cc Chain Excess (T) Air Interaction Type Adsorption Classification Not Specified Sample Geometry Not Specified Sample Dimension Not Specified Presorbed Not Specified Sample Molar Mass Not Specified Sample Skeletal Density Not Specified Absolute Adsorption Basis None Adsorbate Density Not Specified Micropore Volume Not Specified Dilation Not Specified A P P L I C A T I O N S E T U P Application Code 201510 Mode Vacuum Source Gas Cylinder Gas Source NITROGEN at supply pressure 20 barg Vessel CF-SW High Pressure Reactor Conflat SS316L Pressure Sensor(s) 20 bar Thermostat Water Bath NITROGEN EOS calculation NIST REFPROP v9.1 NITROGEN SVP calculation NIST REFPROP v9.1 Source Data C:\HIsorp\G200773\Sample_0328\Sequence\Sequence003\Data.txt Operations Log C:\HIsorp\G200773\Sample_0328\Sequence\Sequence003\Operations Log.txt Method Log C:\HIsorp\G200773\Sample_0328\Sequence\Sequence003\Method Log.txt File created 14:01:16 on 20 January 2020 by WR200774 Issue Level Recalculation Not Issued Series Type Isothermal Series Data Delimiter Space Scan 1 Course Sorption Reference State Device Sample Scan Title Scan Commenced 10:54:11 on 17 January 2020 by WR200774 Pressure Gas p/p0 Total Excess Excess BET Sample %Wt Density Weight Adsorption Adsorption (mbar) (g/cc) (mg) (%) (mmol/g) (g/ml(stp)) (°C) (% d.b.) ----------------------------------------------------------------------------------------------------- -.8 0.000000 0.00 8.9714 0.0002 0.0001 0.0000 32.95 0.000 19.8 0.000020 0.00 8.9752 0.0366 0.0131 0.0000 59.99 0.042 39.9 0.000040 0.00 8.9759 0.0388 0.0139 0.0000 60.03 0.050 60.0 0.000061 0.00 8.9763 0.0385 0.0137 0.0000 59.96 0.055 79.7 0.000081 0.00 8.9773 0.0442 0.0158 0.0000 60.04 0.066 99.8 0.000101 0.00 8.9780 0.0465 0.0166 0.0000 59.98 0.074 149.2 0.000151 0.00 8.9803 0.0588 0.0210 0.0001 59.97 0.100 199.2 0.000202 0.00 8.9832 0.0772 0.0275 0.0001 59.99 0.131 248.8 0.000252 0.00 8.9858 0.0933 0.0333 0.0001 60.00 0.161 297.9 0.000301 0.00 8.9880 0.1042 0.0372 0.0001 60.01 0.185 347.4 0.000351 0.00 8.9905 0.1186 0.0423 0.0001 59.99 0.213 396.6 0.000401 0.00 8.9929 0.1316 0.0470 0.0001 59.95 0.239 446.8 0.000452 0.00 8.9955 0.1473 0.0526 0.0001 59.91 0.269 495.9 0.000502 0.00 8.9974 0.1548 0.0553 0.0001 59.83 0.290 594.4 0.000602 0.00 9.0029 0.1887 0.0674 0.0001 59.66 0.351 692.6 0.000701 0.00 9.0098 0.2399 0.0856 0.0001 59.55 0.429 742.1 0.000752 0.00 9.0129 0.2608 0.0931 0.0001 59.54 0.463 799.9 0.000810 0.00 9.0156 0.2751 0.0982 0.0001 59.53 0.492 899.9 0.000912 0.00 9.0205 0.3032 0.1082 0.0001 59.48 0.548 999.8 0.001013 0.00 9.0234 0.3078 0.1099 0.0001 59.43 0.580 1200.0 0.001216 0.00 9.0331 0.3608 0.1288 0.0001 59.25 0.688 1399.8 0.001419 0.00 9.0375 0.3559 0.1271 0.0001 59.10 0.737 1599.8 0.001622 0.00 9.0454 0.3894 0.1390 0.0001 59.16 0.825 1799.7 0.001825 0.00 9.0564 0.4582 0.1636 0.0001 59.15 0.947 1899.7 0.001927 0.00 9.0628 0.5034 0.1797 0.0001 59.09 1.019 1999.8 0.002028 0.00 9.0647 0.4974 0.1775 0.0001 59.12 1.040 2199.8 0.002231 0.00 9.0807 0.6203 0.2214 0.0001 59.00 1.218 2399.7 0.002436 0.00 9.0860 0.6240 0.2227 0.0001 58.81 1.277 2599.8 0.002641 0.00 9.0955 0.6755 0.2411 0.0001 58.55 1.383 2799.7 0.002844 0.00 9.1074 0.7556 0.2697 0.0001 58.55 1.516 ----------------------------------------------------------------------------------------------------- Scan Ends 20:28:54 on 17 January 2020 by WR200774 Reference State 59.54°C ---------------------------------------------------------------------------------------------------- S E R I E S D A T A R E C O R D ---------------------------------------------------------------------------------------------------- System Type IGA Systems System Owner EPFL System Reference G200773 System Serial Number HALIGA241 Sample Number 0328 Experiment Type Sequence Experiment No 004 Title ZIF 8 prisma Comment Source Batch ID Experiment Title Isotherm_n2_70deg S A M P L E S E T U P Sample Wet Weight 9.2627 mg Sample Dry Weight 8.9727 mg Sample Dry Mass 8.9727 mg Sample Weight Loss 3.23 %d.b. Balance Trim (V) 0.0024 cc Balance Trim (T) Cabinet Counterweight (M) 0.3062 g Counterweight (ρ) 7.886 g/cc Counterweight (T) Air Sample Container (M) 0.0895 g Sample Container (ρ) 7.886 g/cc Sample Container (T) Sample Tungsten (M) 0.0568 g Tungsten (ρ) 19.03976 g/cc Tungsten (T) Sample Chain Excess (M) 0.0719 g Chain Excess (ρ) 11.09856 g/cc Chain Excess (T) Air Interaction Type Adsorption Classification Not Specified Sample Geometry Not Specified Sample Dimension Not Specified Presorbed Not Specified Sample Molar Mass Not Specified Sample Skeletal Density Not Specified Absolute Adsorption Basis None Adsorbate Density Not Specified Micropore Volume Not Specified Dilation Not Specified A P P L I C A T I O N S E T U P Application Code 201510 Mode Vacuum Source Gas Cylinder Gas Source NITROGEN at supply pressure 20 barg Vessel CF-SW High Pressure Reactor Conflat SS316L Pressure Sensor(s) 20 bar Thermostat Water Bath NITROGEN EOS calculation NIST REFPROP v9.1 NITROGEN SVP calculation NIST REFPROP v9.1 Source Data C:\HIsorp\G200773\Sample_0328\Sequence\Sequence004\Data.txt Operations Log C:\HIsorp\G200773\Sample_0328\Sequence\Sequence004\Operations Log.txt Method Log C:\HIsorp\G200773\Sample_0328\Sequence\Sequence004\Method Log.txt File created 14:01:19 on 20 January 2020 by WR200774 Issue Level Recalculation Not Issued Series Type Isothermal Series Data Delimiter Space Scan 1 Course Sorption Reference State Device Sample Scan Title Scan Commenced 14:09:47 on 18 January 2020 by WR200774 Pressure Gas p/p0 Total Excess Excess BET Sample %Wt Density Weight Adsorption Adsorption (mbar) (g/cc) (mg) (%) (mmol/g) (g/ml(stp)) (°C) (% d.b.) ----------------------------------------------------------------------------------------------------- -.8 0.000000 0.00 8.9727 0.0000 0.0000 0.0000 42.44 0.000 19.9 0.000020 0.00 8.9762 0.0332 0.0119 0.0000 69.54 0.039 40.0 0.000039 0.00 8.9769 0.0358 0.0128 0.0000 69.55 0.047 59.9 0.000059 0.00 8.9778 0.0408 0.0146 0.0000 69.53 0.057 79.8 0.000079 0.00 8.9790 0.0480 0.0171 0.0000 69.49 0.070 99.6 0.000098 0.00 8.9798 0.0522 0.0186 0.0000 69.57 0.080 149.2 0.000147 0.00 8.9818 0.0606 0.0216 0.0000 69.50 0.102 198.9 0.000196 0.00 8.9842 0.0728 0.0260 0.0001 69.45 0.128 248.7 0.000245 0.00 8.9873 0.0944 0.0337 0.0001 69.46 0.163 296.9 0.000292 0.00 8.9893 0.1036 0.0370 0.0001 69.45 0.185 347.3 0.000342 0.00 8.9926 0.1261 0.0450 0.0001 69.44 0.222 396.6 0.000390 0.00 8.9950 0.1396 0.0498 0.0001 69.40 0.249 445.3 0.000438 0.00 8.9973 0.1521 0.0543 0.0001 69.34 0.275 499.8 0.000492 0.00 8.9998 0.1646 0.0587 0.0001 69.24 0.302 599.8 0.000591 0.00 9.0048 0.1924 0.0687 0.0001 69.04 0.358 699.9 0.000690 0.00 9.0108 0.2310 0.0825 0.0001 68.83 0.424 749.9 0.000739 0.00 9.0148 0.2626 0.0937 0.0001 68.77 0.469 799.8 0.000788 0.00 9.0177 0.2815 0.1005 0.0001 68.77 0.501 899.8 0.000887 0.00 9.0233 0.3167 0.1131 0.0001 68.71 0.564 999.8 0.000986 0.00 9.0281 0.3427 0.1223 0.0001 68.66 0.617 1199.9 0.001183 0.00 9.0335 0.3478 0.1241 0.0001 68.51 0.678 1399.9 0.001381 0.00 9.0385 0.3483 0.1243 0.0001 68.36 0.733 1599.8 0.001578 0.00 9.0481 0.3991 0.1425 0.0001 68.37 0.840 1799.8 0.001776 0.00 9.0597 0.4740 0.1692 0.0001 68.23 0.970 1899.7 0.001875 0.00 9.0607 0.4579 0.1635 0.0001 68.20 0.980 1999.9 0.001974 0.00 9.0705 0.5407 0.1930 0.0001 68.15 1.090 2199.7 0.002172 0.00 9.0775 0.5649 0.2016 0.0001 68.13 1.168 2399.9 0.002370 0.00 9.0899 0.6472 0.2310 0.0001 68.07 1.306 2599.8 0.002569 0.00 9.0928 0.6244 0.2229 0.0001 67.77 1.339 2799.7 0.002768 0.00 9.1036 0.6884 0.2457 0.0001 67.64 1.458 ----------------------------------------------------------------------------------------------------- Scan Ends 23:50:08 on 18 January 2020 by WR200774 Reference State 68.87°C