Nuclear Reactions m58610 Nuclear Reactions By the end of this section, you will be able to: Describe and compare three types of nuclear radiation Use nuclear symbols to describe changes that occur during nuclear reactions Describe processes involved in the decay series of heavy elements 2c788aab-6757-47a1-9210-eea272d9eaa2 Early experiments revealed three types of nuclear “rays” or radiation: alpha (α) rays, beta (β) rays, and gamma (γ) rays. These three types of radiation are differentiated by their ability to penetrate matter. Alpha radiation is barely able to pass through a thin sheet of paper. Beta radiation can penetrate aluminum to a depth of about 3 mm, and gamma radiation can penetrate lead to a depth of 2 or more centimeters ().
A comparison of the penetration depths of alpha (α), beta (β), and gamma (γ) radiation through various materials.
The electrical properties of these three types of radiation are investigated by passing them through a uniform magnetic field, as shown in . According to the magnetic force equation F→=qv→×B→, positively charged particles are deflected upward, negatively charged particles are deflected downward, and particles with no charge pass through the magnetic field undeflected. Eventually, α rays were identified with helium nuclei (4He),β rays with electrons and positrons (positively charged electrons or antielectrons), and γ rays with high-energy photons. We discuss alpha, beta, and gamma radiation in detail in the remainder of this section.
The effect of a magnetic field on alpha (α), beta (β), and gamma (γ) radiation. This figure is a schematic only. The relative paths of the particles depend on their masses and initial kinetic energies.
Alpha Decay Heavy unstable nuclei emit α radiation. In α-particle decay (or alpha decay), the nucleus loses two protons and two neutrons, so the atomic number decreases by two, whereas its mass number decreases by four. Before the decay, the nucleus is called the parent nucleus. The nucleus or nuclei produced in the decay are referred to as the daughter nucleus or daughter nuclei. We represent an α decay symbolically by where ZAX is the parent nucleus, Z−2A−4X is the daughter nucleus, and 24He is the α particle. In α decay, a nucleus of atomic number Z decays into a nucleus of atomic number Z−2 and atomic mass A−4. Interestingly, the dream of the ancient alchemists to turn other metals into gold is scientifically feasible through the alpha-decay process. The efforts of the alchemists failed because they relied on chemical interactions rather than nuclear interactions. Watch alpha particles escape from a polonium nucleus, causing radioactive alpha decay. See how random decay times relate to the half-life. To try a simulation of alpha decay, visit alpha particles An example of alpha decay is uranium-238: The atomic number has dropped from 92 to 90. The chemical element with Z=90 is thorium. Hence, Uranium-238 has decayed to Thorium-234 by the emission of an α particle, written Subsequently, 90234Th decays by β emission with a half-life of 24 days. The energy released in this alpha decay takes the form of kinetic energies of the thorium and helium nuclei, although the kinetic energy of thorium is smaller than helium due to its heavier mass and smaller velocity. Plutonium Alpha Decay Find the energy emitted in the α decay of 239Pu. Strategy The energy emitted in the α decay of 239Pu can be found using the equation E=(Δm)c2. We must first find Δm, the difference in mass between the parent nucleus and the products of the decay. Solution The decay equation is Thus, the pertinent masses are those of 239Pu, 235U, and the α particle or 4He, all of which are known. The initial mass was m(239Pu)=239.052157u. The final mass is the sum Thus, Now we can find E by entering Δm into the equation: We know 1u=931.5MeV/c2, so we have Significance The energy released in this α decay is in the MeV range, many times greater than chemical reaction energies. Most of this energy becomes kinetic energy of the α particle (or 4He nucleus), which moves away at high speed. The energy carried away by the recoil of the 235U nucleus is much smaller due to its relatively large mass. The 235U nucleus can be left in an excited state to later emit photons (γ rays).
Beta Decay In most β particle decays (or beta decay), either an electron (β−) or positron (β+) is emitted by a nucleus. A positron has the same mass as the electron, but its charge is +e. For this reason, a positron is sometimes called an antielectron. How does β decay occur? A possible explanation is the electron (positron) is confined to the nucleus prior to the decay and somehow escapes. To obtain a rough estimate of the escape energy, consider a simplified model of an electron trapped in a box (or in the terminology of quantum mechanics, a one-dimensional square well) that has the width of a typical nucleus (10−14m). According to the Heisenberg uncertainty principle in Quantum Mechanics, the uncertainty of the momentum of the electron is: Taking this momentum value (an underestimate) to be the “true value,” the kinetic energy of the electron on escape is approximately Experimentally, the electrons emitted in β− decay are found to have kinetic energies of the order of only a few MeV. We therefore conclude that the electron is somehow produced in the decay rather than escaping the nucleus. Particle production (annihilation) is described by theories that combine quantum mechanics and relativity, a subject of a more advanced course in physics. Nuclear beta decay involves the conversion of one nucleon into another. For example, a neutron can decay to a proton by the emission of an electron (β−) and a nearly massless particle called an antineutrino (ν–): The notation −10e is used to designate the electron. Its mass number is 0 because it is not a nucleon, and its atomic number is −1 to signify that it has a charge of −e. The proton is represented by 11p because its mass number and atomic number are 1. When this occurs within an atomic nucleus, we have the following equation for beta decay: Enrico Fermi proposed a theory of beta decay in 1934, but his work was initially rejected. Other physicists' experiments to prove it were unsuccessful, casting further doubt on the theory. Chinese-born physicist Chien-Shiung Wu, who had developed a number of processes critical to the Manhattan Project and related research, identified a number of flaws in the earlier experimental methods and materials. She designed a new method, verified Fermi's theory, and later went on to establish the core principles of beta decay. As discussed in another chapter, this process occurs due to the weak nuclear force. Watch beta decay occur for a collection of nuclei or for an individual nucleus. As an example, the isotope 90234Th is unstable and decays by β− emission with a half-life of 24 days. Its decay can be represented as Since the chemical element with atomic number 91 is protactinium (Pa), we can write the β− decay of thorium as The reverse process is also possible: A proton can decay to a neutron by the emission of a positron (β+) and a nearly massless particle called a neutrino (v). This reaction is written as 11p→01n++10e+v. The positron +10e is emitted with the neutrino v, and the neutron remains in the nucleus. (Like β− decay, the positron does not precede the decay but is produced in the decay.) For an isolated proton, this process is impossible because the neutron is heavier than the proton. However, this process is possible within the nucleus because the proton can receive energy from other nucleons for the transition. As an example, the isotope of aluminum 1326Al decays by β+ emission with a half-life of 7.40×105y. The decay is written as The atomic number 12 corresponds to magnesium. Hence, As a nuclear reaction, positron emission can be written as The neutrino was not detected in the early experiments on β decay. However, the laws of energy and momentum seemed to require such a particle. Later, neutrinos were detected through their interactions with nuclei. Bismuth Alpha and Beta Decay The 83211Bi nucleus undergoes both α and β− decay. For each case, what is the daughter nucleus? Strategy We can use the processes described by and , as well as the Periodic Table, to identify the resulting elements. Solution The atomic number and the mass number for the α particle are 2 and 4, respectively. Thus, when a bismuth-211 nucleus emits an α particle, the daughter nucleus has an atomic number of 81 and a mass number of 207. The element with an atomic number of 81 is thallium, so the decay is given by In β− decay, the atomic number increases by 1, while the mass number stays the same. The element with an atomic number of 84 is polonium, so the decay is given by In radioactive beta decay, does the atomic mass number, A, increase or decrease? Neither; it stays the same.
Gamma Decay A nucleus in an excited state can decay to a lower-level state by the emission of a “gamma-ray” photon, and this is known as gamma decay. This is analogous to de-excitation of an atomic electron. Gamma decay is represented symbolically by where the asterisk (*) on the nucleus indicates an excited state. In γ decay, neither the atomic number nor the mass number changes, so the type of nucleus does not change.
Radioactive Decay Series Nuclei with Z>82 are unstable and decay naturally. Many of these nuclei have very short lifetimes, so they are not found in nature. Notable exceptions include 90232Th (or Th-232) with a half-life of 1.39×1010 years, and 92238U (or U-238) with a half-life of 7.04×108 years. When a heavy nucleus decays to a lighter one, the lighter daughter nucleus can become the parent nucleus for the next decay, and so on. This process can produce a long series of nuclear decays called a decay series. The series ends with a stable nucleus. To illustrate the concept of a decay series, consider the decay of Th-232 series (). The neutron number, N, is plotted on the vertical y-axis, and the atomic number, Z, is plotted on the horizontal x-axis, so Th-232 is found at the coordinates (N,Z)=(142,90). Th-232 decays by α emission with a half-life of 1.39×1010 years. Alpha decay decreases the atomic number by 2 and the mass number by 4, so we have The neutron number for Radium-228 is 140, so it is found in the diagram at the coordinates (N,Z)=(140,88). Radium-228 is also unstable and decays by β− emission with a half-life of 5.76 years to Actinum-228. The atomic number increases by 1, the mass number remains the same, and the neutron number decreases by 1. Notice that in the graph, α emission appears as a line sloping downward to the left, with both N and Z decreasing by 2. Beta emission, on the other hand, appears as a line sloping downward to the right with N decreasing by 1, and Z increasing by 1. After several additional alpha and beta decays, the series ends with the stable nucleus Pb-208. The relative frequency of different types of radioactive decays (alpha, beta, and gamma) depends on many factors, including the strength of the forces involved and the number of ways a given reaction can occur without violating the conservation of energy and momentum. How often a radioactive decay occurs often depends on a sensitive balance of the strong and electromagnetic forces. These forces are discussed in Particle Physics and Cosmology.
In the thorium 90232Th decay series, alpha (α) decays reduce the atomic number, as indicated by the red arrows. Beta (β−) decays increase the atomic number, as indicated by the blue arrows. The series ends at the stable nucleus Pb-208.
As another example, consider the U-238 decay series shown in . After numerous alpha and beta decays, the series ends with the stable nucleus Pb-206. An example of a decay whose parent nucleus no longer exists naturally is shown in . It starts with Neptunium-237, which decays to Bismuth-209, long thought to be stable, but which decays with a half-life of 2.01 × 1019 years (much longer than the age of the universe) to the stable nucleus Thallium-205. Neptunium is called a transuranic element because it lies beyond uranium in the periodic table. Uranium has the highest atomic number (Z=92) of any element found in nature. Elements with Z>92 can be produced only in the laboratory. They most probably also existed in nature at the time of the formation of Earth, but because of their relatively short lifetimes, they have completely decayed. There is nothing fundamentally different between naturally occurring and artificial elements.
In the Uranium-238 decay series, alpha (α) decays reduce the atomic number, as indicated by the red arrows. Beta (β−) decays increase the atomic number, as indicated by the blue arrows. The series ends at the stable nucleus Pb-206.
Notice that for Bi (21), the decay may proceed through either alpha or beta decay.
In the Neptunium-237 decay series, alpha (α) decays reduce the atomic number, as indicated by the red arrows. Beta (β−) decays increase the atomic number, as indicated by the blue arrows. The series ends at the stable nucleus Bi-209.
Radioactivity in the Earth According to geologists, if there were no heat source, Earth should have cooled to its present temperature in no more than 1 × 109 years. Yet, Earth is more than 4 × 109 years old. Why is Earth cooling so slowly? The answer is nuclear radioactivity, that is, high-energy particles produced in radioactive decays heat Earth from the inside ().
Earth is heated by nuclear reactions (alpha, beta, and gamma decays). Without these reactions, Earth’s core and mantle would be much cooler than it is now.
Candidate nuclei for this heating model are 238U and40K, which possess half-lives similar to or longer than the age of Earth. The energy produced by these decays (per second per cubic meter) is small, but the energy cannot escape easily, so Earth’s core is very hot. Thermal energy in Earth’s core is transferred to Earth’s surface and away from it through the processes of convection, conduction, and radiation.
Summary The three types of nuclear radiation are alpha (α) rays, beta (β) rays, and gamma (γ) rays. We represent α decay symbolically by ZAX→Z−2A−4X+24He. There are two types of β decay: either an electron (β−) or a positron (β+) is emitted by a nucleus. γ decay is represented symbolically by ZAX*→ZAX+γ. When a heavy nucleus decays to a lighter one, the lighter daughter nucleus can become the parent nucleus for the next decay, and so on, producing a decay series.
Conceptual Questions What is the key difference and the key similarity between beta (β−) decay and alpha decay? What is the difference between γ rays and characteristic X-rays and visible light? Gamma (γ) rays are produced by nuclear interactions and X-rays and light are produced by atomic interactions. Gamma rays are typically shorter wavelength than X-rays, and X-rays are shorter wavelength than light. What characteristics of radioactivity show it to be nuclear in origin and not atomic? Consider . If the magnetic field is replaced by an electric field pointed in toward the page, in which directions will the α-, β+-, and γ rays bend? Assume a rectangular coordinate system with an xy-plane that corresponds to the plane of the paper. α bends into the page (trajectory parabolic in the xz-plane); β+ bends into the page (trajectory parabolic in the xz-plane); and γ is unbent. Why is Earth’s core molten?
Problems 249Cf undergoes alpha decay. (a) Write the reaction equation. (b) Find the energy released in the decay. (a) Calculate the energy released in the α decay of 238U. (b) What fraction of the mass of a single 238U is destroyed in the decay? The mass of 234Th is 234.043593 u. (c) Although the fractional mass loss is large for a single nucleus, it is difficult to observe for an entire macroscopic sample of uranium. Why is this? a. 4.273 MeV; b. 1.927×10−5; c. Since 238U is a slowly decaying substance, only a very small number of nuclei decay on human timescales; therefore, although those nuclei that decay lose a noticeable fraction of their mass, the change in the total mass of the sample is not detectable for a macroscopic sample. The β− particles emitted in the decay of 3H (tritium) interact with matter to create light in a glow-in-the-dark exit sign. At the time of manufacture, such a sign contains 15.0 Ci of 3H. (a) What is the mass of the tritium? (b) What is its activity 5.00 y after manufacture? (a) Write the complete β− decay equation for 90Sr, a major waste product of nuclear reactors. (b) Find the energy released in the decay. a. 3890Sr52→3990Y51+β−1+ve–; b. 0.546 MeV Write a nuclear β− decay reaction that produces the 90Y nucleus. (Hint: The parent nuclide is a major waste product of reactors and has chemistry similar to calcium, so that it is concentrated in bones if ingested.) Write the complete decay equation in the complete ZAXN notation for the beta (β−) decay of 3H (tritium), a manufactured isotope of hydrogen used in some digital watch displays, and manufactured primarily for use in hydrogen bombs. 13H2→23He1+β−+ve– If a 1.50-cm-thick piece of lead can absorb 90.0% of the rays from a radioactive source, how many centimeters of lead are needed to absorb all but 0.100% of the rays? An electron can interact with a nucleus through the beta-decay process: ZAX+e−→Y+ve. (a) Write the complete reaction equation for electron capture by 7Be. (b) Calculate the energy released. a. 47Be3+e−→37Li4+ve; b. 0.862 MeV (a) Write the complete reaction equation for electron capture by 15O. (b) Calculate the energy released. A rare decay mode has been observed in which 222Ra emits a 14C nucleus. (a) The decay equation is 222Ra→AX+14C. Identify the nuclide AX. (b) Find the energy emitted in the decay. The mass of 222Ra is 222.015353 u. a. X=82208Pb126; b. 33.05 MeV
alpha decay radioactive nuclear decay associated with the emission of an alpha particle alpha (α) rays one of the types of rays emitted from the nucleus of an atom as alpha particles antielectrons another term for positrons antineutrino antiparticle of an electron’s neutrino in β− decay beta decay radioactive nuclear decay associated with the emission of a beta particle beta (β) rays one of the types of rays emitted from the nucleus of an atom as beta particles daughter nucleus nucleus produced by the decay of a parent nucleus decay series series of nuclear decays ending in a stable nucleus gamma decay radioactive nuclear decay associated with the emission of gamma radiation gamma (γ) rays one of the types of rays emitted from the nucleus of an atom as gamma particles neutrino subatomic elementary particle which has no net electric charge parent nucleus original nucleus before decay positron electron with positive charge transuranic element element that lies beyond uranium in the periodic table